Validation of QuEChERS-based method for determination of flusilazole residues in grape by high-performance liquid chromatography with photodiode array detector

A high-performance liquid chromatography with photodiode array detector analytical method was developed to determine the residue levels of flusilazole in grape and investigate the dissipation pattern and safety. The results showed that the mean recoveries were in the range of 86%–90%. Limits of detection and quantification were 0.008 and 0.02 mg/kg, respectively. The residue levels of flusilazole were best described by first-order rate kinetics and with half-lives ranging from 4.2 days (recommended dose) to 4.6 days (double the recommended dose). In conclusion, flusilazole at the recommended or even at double the recommended doses does not pose any apparent hazards to consumers.     

污染土壤淋洗修复技术研究进展

本文介绍了淋洗修复技术和淋洗装置在污染土壤修复技术中的应用,对有机物、重金属及放射性核素污染土壤淋洗修复技术的应用现状进行了总结和评价,还探讨了淋洗修复技术的发展方向及其应用前景。     

石油石化企业温室气体清单编制简析

文章通过简要阐述石油石化企业温室气体清单的编制全过程,确定石油石化企业温室气体排放种类、识别主要温室气体排放源、列举重点生产过程中温室气体排放量的核算方法,为石油石化企业实现温室气体减排和控制工作、为完成国务院规定的到2020年我国单位国内生产总值二氧化碳排放强度比2005年下降40%~45%的约束性指标,奠定数据理论基础。     

医疗废物焚烧处理核心技术的开发及应用

国内已建成的医疗废物焚烧设施目前普遍存在进料系统不稳定、玻璃结渣和高浓度HCl气体的排放的问题。这些技术难点已成为医疗废物焚烧处置行业发展的瓶颈。本文介绍了可解决上述问题的"可调节医疗废物恒流量进料技术"、"医废焚烧防玻璃结渣技术"和"含高浓度氯化氢医废尾气处理技术"三项医疗废物焚烧处理核心技术的主要特点及技术指标与应用实例。     

基于PCA-RBF神经网络的地铁车站火灾风险评估

为避免地铁车站火灾事故的发生,帮助地铁车站管理部门做好火灾风险评估工作,提出基于PCA-RBF神经网络的地铁车站火灾风险评估模型。采用主成分分析法(Principal Component Analysis,PCA)对风险评价指标体系进行降维处理,并将降维后的主成分作为RBF神经网络的输入变量;选择具有代表性的样本数据训练RBF神经网络,并用检验样本测试训练效果;最后,输入待测样本数据得出火灾风险评估结果。通过实例对比分析,验证了该评估模型在地铁车站火灾风险评估中的可行性与准确性,对类似项目火灾风险评估具有一定参考意义。     

Preparation, characterization and application of CuCrO2/ZnO photocatalysts for the reduction of Cr(VI)

The delafossite CuCrO₂ elaborated by sol-gel from 40 nm diameter colloid is optically active in the visible region. It is characterized physically and photoelectrochemically. The microstructure is fairly homogenous with a mean crystallite size of ca. 2 μm. The optical gap (1.30 eV), determined from the diffuse reflectance, is well suited to the sunlight spectrum. The Mott Schottky plot is characteristic of P-type conductivity with a flat band potential of -0.26 V_SCE. As application, the photoreduction of chromate is successfully achieved in air-equilibrated suspension CuCrO₂/ZnO (1/1). CuCrO₂ is photoactivated by visible light and the electrons in the conduction band (-1.34 V_SCE) are injected to ZnO. In the presence of salicylic acid, a conversion of Cr(VI) to Cr(III) of 57% is obtained under optimal conditions (pH 3 at 25℃, 5×10^-4 mol/L) because of the HCrO₄^- dark adsorption onto ZnO (4HCrO₄^- + 3C₇H₆O₃ + 18O₂ + 16H⁺ → 4Cr³⁺ + 21CO₂ + 19H₂O, ΔG⁰ = -557 kcal/mol). Prolonged illumination is accompanied by a deceleration in the photoactivity owing to the competitive water reduction, an issue of energetic concern. The hetero-system exhibits self sensitization for hydrogen production with an evolution rate of 149 μmol/(hr·g).     

降雨和土地利用对地表径流的影响-以北京北护城河周边区域为例

以北京北护城河周边区域为例,探讨了降雨和土地利用对地表径流的影响。选取了2011-2012 年4-11 月的15 场降雨,分别代表小雨、中雨、大雨、暴雨、大暴雨和特大暴雨这6 个雨量级。利用校准的雨洪管理模型（Storm Water Management Model, SWMM）分别模拟每次降雨事件下研究区7 个控制断面的地表径流深度。结果表明,地表径流深度随降雨量的增加显著线性增加。当降雨量在不同量级之间变化时,地表径流深度的变化幅度不尽相同。在不同的降雨事件中,降雨量和地表径流深度随时间的动态变化趋势可能有很大的差异,但地表径流深度在某一时刻的值的高低均决定于之前1~2 h 的降雨量,而地表径流深度的总体上升或下降趋势均决定于前期累积的降雨量。地表径流深度随渗透面积比例的增加显著下降,且变化曲线存在临界阈值（为15%~20%）。在暴雨、大暴雨和特大暴雨时,渗透面积比例对地表径流的影响更大。研究结果可为控制汛期城市地表径流量和洪峰流量、减少城市内涝提供土地利用和管理方面的理论依据和决策建议。     

ModelOps for enhanced decision-making and governance in emergency control rooms

Environment Systems and Decisions - For mission critical (MC) applications such as bushfire emergency management systems (EMS), understanding the current situation as a disaster unfolds is critical...     

含氮杂环化合物吲哚的缺氧降解性能研究

以好氧、厌氧作为对比，研究了含氮杂环化合物——吲哚的缺氧生物降解性能。主要研究在缺氧状态下吲哚的生物降解性能、适宜N／C比、氮源的变化情况以及吲哚的缺氧降解途径。结果表明，缺氧反硝化状态下吲哚具有较好的生物降解性能。     

蚯蚓土壤填料生态滤池处理生活污水

采用二级蚯蚓土壤填料生态滤池对生活污水进行处理,考察其对污水中各类污染物的去除效果。连续运行90d,试验结果表明:滤池运行稳定,对COD、TP、NH3-N、TN和SS的去除效果良好,平均去除率分别为78.7%、93.4%、74.9%、60.4%和87.5%,出水满足GB 1898—2002《城镇污水处理厂污染物排放标准》二级标准。滤池二级串联结构设计系统稳定,改善了出水水质。蚯蚓在试验初期对滤池环境可较好较快的适应,维持了滤池的稳定运行。土壤生态处理技术工艺简单,兼具经济实用和规模灵活的优点,适合推广。