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571.
J T Smith O V Voitsekhovitch L H?kanson J Hilton 《Journal of environmental radioactivity》2001,56(1-2):11-32
Following a radioactive fallout event, there are a number of possible intervention measures to reduce radioactive doses to the public via the surface water pathway. We have critically reviewed the options available to decision-makers in the event of radioactive contamination of surface waters. We believe that the most effective and viable measures to reduce radioactivity in drinking water are those which operate at the water treatment and distribution stage. Intervention measures to reduce concentrations of radioactivity in rivers and reservoirs are expected to be much less viable and efficient at reducing doses via the drinking water pathway. Bans on consumption of freshwater fish can be effective, but there are few viable measures to reduce radioactivity in fish prior to the preparation stage. Lake liming and biomanipulation have been found to be ineffective for radiocaesium, although the addition of potassium to lakewaters appears promising in some situations. Lake liming may be effective in reducing radiostrontium in fish, though this has not, to our knowledge, been tested. De-boning fish contaminated by strontium is probably the most effective food preparation measure, but salting and freezing can also reduce radiocaesium concentrations in fish. The provision of accurate information to the public is highlighted as a key element of countermeasure implementation. 相似文献
572.
H Vandenhove Y Thiry A Gommers F Goor J M Jossart E Holm T G?fvert J Roed A Grebenkov S Timofeyev T G?ufert 《Journal of environmental radioactivity》2001,56(1-2):157-184
When dealing with large-scale environmental contamination, as following the Chernobyl accident, changed land use such that the products of the land are radiologically acceptable and sustain an economic return from the land is a potentially sustainable remediation option. In this paper, willow short rotation coppice (SRC) is evaluated on radiological, technical and economic grounds for W. European and Belarus site conditions. Radiocaesium uptake was studied in a newly established and existing SRC. Only for light-texture soils with low soil potassium should cultivation be restricted to soils with contamination levels below 100-370 kBq m-2 given the TFs on these soils (5 x 10(-4) and 2 x 10(-3) m2 kg-1) and considering the Belarus exemption limit for firewood (740 Bq kg-1). In the case of high wood contamination levels (> 1000 Bq kg-1), power plant personnel working in the vicinity of ash conveyers should be subjected to radiation protection measures. For appropriate soil conditions, potential SRC yields are high. In Belarus, most soils are sandy with a low water retention, for which yield estimates are too low to make production profitable without irrigation. The economic viability should be thoroughly calculated for the prevailing conditions. In W. Europe, SRC production or conversion is not profitable without price incentives. For Belarus, the profitability of SRC on the production side largely depends on crop yield and price of the delivered bio-fuel. Large-scale heat conversion systems seem the most profitable and revenue may be considerable. Electricity routes are usually unprofitable. It could be concluded that energy production from SRC is potentially a radiologically and economically sustainable land use option for contaminated agricultural land. 相似文献
573.
Female and male reproductive interests often differ. In species in which matings are accompanied by a transfer of resources
valuable for both participants, such as nuptial prey gifts, conflicts may readily occur. Scorpionflies may use alternative
mating tactics. One is to offer a prey item (dead arthropod) to females in exchange for mating. This prey gift tactic includes
a conflict because a male must decide on whether to offer the gift rather than to fight the female and consume the gift. The
outcome may depend on the nutritional status of both males and females. Males may be more willing to give if they themselves
are satiated and the condition of the females may influence the payoff from the males’ investment. Similarly, females may
be more willing to accept food gifts if they are in poor nutritional condition. In this study of the scorpionfly Panorpa cognata, I experimentally manipulated the feeding history of both males and females. I observed the outcome of the direct interactions
that followed when males that were holding prey were approached by females. I found that well-fed males offered the food gift
sooner than males in poor nutritional condition that fed extensively on the food item before offering. Female condition had
no significant influence on whether prey items were offered by males or accepted by females. I also found that well-fed males
rarely searched for prey to pursue the prey gift tactic in courtship. Thus, the prey tactic does not seem to be the males’
first option. 相似文献
574.
M.?A.?de?FigueiredoEmail author D.?M.?Reiner H.?J.?Herzog 《Mitigation and Adaptation Strategies for Global Change》2005,10(4):647-657
This paper examines how legal standards of liability may apply to geologic carbon storage. The liability regime governing
geologic carbon storage will shape the technology's cost-effectiveness and overall attractiveness. We classify potential sources
of liability into operational, in situ, and climate liability. As a first step, we explore in situ liability in the United States. After summarizing legal standards of liability including negligence, breach of implied warranty,
strict liability, and product liability, we discuss how liability may be addressed at the level of the federal government,
state government, industry, and the firm. Finally, we address the implications of judicial treatment of liability for carbon
storage, including the apportionment of liability and the adequacy of current regulations. 相似文献
575.
Tamer?Karay?ld?r?mEmail author Jale?Yan?k Mithat?Yüksel Mehmet?Sa?lam Michael?Haussmann 《Journal of Polymers and the Environment》2005,13(4):365-374
Degradation of a model polymer mixture (PVC/PS/PE) and a waste polymer mixture in the presence of HCl fixators (Red Mud, precipitated CaCO3 and dolamite) was studied using thermal gravimetric analysis (TGA) and a cycled-spheres-reactor. The experiments in cycled-spheres reactor model were performed by stepwise pyrolysis. Liquid products and HCl from each step were collected separately. For the model polymer mixture, the precipitated CaCO3 showed the best effect on the fixation of evolved HCl and the reduction of chlorine content in the liquid products whereas RM yielded the best result for the waste polymer mixture. In addition, using HCl fixator also affected the degradation of both types of polymer mixture, leading to the formation of more gaseous and less residue. 相似文献
576.
采用自行研发的泥-水界面微孔曝气系统,开展了底泥表面曝气和覆盖对城市重污染河道底泥磷释放及形态分布规律的影响研究.结果表明,微孔曝气能够有效提高上覆水的溶解氧(DO)和沉积物的氧化还原电位(Eh),能够将泥-水界面Eh维持在-100 m V左右,DO提高到6 mg·L-1以上.与对照比较,原位覆盖处理的上覆水DO和Eh有一定提高,但仍明显低于微孔曝气处理.与对照相比较,微孔曝气处理均有效降低上覆水中总磷(TP)和溶解性正磷酸盐(PO3-4)的含量.试验结束时,微孔曝气(A)和微孔曝气+原位覆盖处理(A+C)上覆水中TP含量由初始的0.201 mg·L-1分别降至0.062 mg·L-1和0.050 mg·L-1;上覆水中PO3-4含量由0.086 mg·L-1和0.078 mg·L-1分别降至0.026 mg·L-1和0.023 mg·L-1.与对照相比,微孔曝气处理明显降低了底泥间隙水中TP的浓度,在整个培养期间,其TP含量平均下降38.8%(A)和47.9%(A+C).底泥原位覆盖处理对抑制泥-水界面磷释放能力要弱于微孔曝气处理,而且在试验后期(50 d),上覆水中TP和PO3-4的含量均有所反弹.不管有无覆盖,泥-水界面微孔曝气处理均显著改变了表层底泥磷形态分布特征,显著降低了底泥中铁铝结合态磷(Fe/Al-P)组分比例,而钙结合态磷(Ca-P)含量比例却出现明显增加.单一的表面覆盖处理对底泥磷形态分布特征没有显著影响(P0.05).研究表明,与单一的处理效果相比较,泥-水界面纳米微孔曝气处理,并结合底泥原位覆盖,更有利于抑制城市重污染河道泥-水界面中磷的释放风险. 相似文献
577.
Degradation of azo dyes in water by Electro-Fenton process 总被引:19,自引:0,他引:19
Elodie?Guivarch Stephane?Trevin Claude?Lahitte Mehmet?A.?OturanEmail author 《Environmental Chemistry Letters》2003,1(1):38-44
The degradation of the azo dyes azobenzene, p-methyl red and methyl orange in aqueous solution at room temperature has been studied by an advanced electrochemical oxidation
process (AEOPs) under potential-controlled electrolysis conditions, using a Pt anode and a carbon felt cathode. The electrochemical
production of Fenton's reagent (H2O2, Fe2+) allows a controlled in situ generation of hydroxyl radicals (·OH) by simultaneous reduction of dioxygen and ferrous ions on the carbon felt electrode. In turn, hydroxyl radicals react
with azo dyes, thus leading to their mineralization into CO2 and H2O. The chemical composition of the azo dyes and their degradation products during electrolysis were monitored by high performance
liquid chromatography (HPLC). The following degradation products were identified: hydroquinone, 1,4-benzoquinone, pyrocatechol,
4-nitrocatechol, 1,3,5-trihydroxynitrobenzene and p-nitrophenol. Degradation of the initial azo dyes was assessed by the measurement of the chemical oxygen demand (COD). Kinetic
analysis of these data showed a pseudo-first order degradation reaction for all azo dyes. A pathway of degradation of azo
dyes is proposed. Specifically, the degradation of dyes and intermediates proceeds by oxidation of azo bonds and aromatic
ring by hydroxyl radicals. The results display the efficiency of the Electro-Fenton process to degrade organic matter.
Electronic Publication 相似文献
578.
Demir M Makineci E Comez A Yilmaz E 《Journal of environmental biology / Academy of Environmental Biology, India》2010,31(4):477-482
In this study, long-term timber skidding effects on herbaceous understory forest floor and soil were investigated on a skid road in a stand of the eastern beech (Fagus orientalis Lipsky). For this purpose, herbaceous understory forest floor and soil samples were collected from the skid road and from an undisturbed area used as a control plot. The mass (kg ha(-1)) of herbaceous and forest floor samples was determined, and soil characteristics were examined at two depths (0-5 cm and 5-10 cm). We quantified sand, silt and clay content, as well as bulk density compaction, pH, and organic carbon content in soil samples. The quantities of N, K, P, Na, Ca, Mg, Fe, Mn, Zn and Cu were determined in all herbaceous cover forest floor and soil samples. The quantities of Na, Fe, Zn, Cu and Mn in herbaceous understory samples from the skid road were considerably higher than those in the undisturbed area, while the quantity of Mg was considerably lower. These differences could have been caused by decreased herbaceous cover in addition to variations in the properties of the forest floor and soil after skidding. A lower amount of forest floor on the skid road was the result of skidding and harvesting activities. Mg and Zn contents in forest floor samples were found to be considerably lower for the skid road than for the undisturbed area. No significant differences were found in soil chemical properties (quantities of N, P, K, Na, Ca, Mg, Fe, Zn, Cu and Mn) at the 0-5 cm soil depth. Important differences exist between soil quantities of Mg at a 5-10 cm depth on the skid road and in undisturbed areas. Both 0-5 cm and 5-10 cm soil depths, the average penetrometer resistance values for the skid road was higher than for the undisturbed area. This result shows that the compaction caused by skidding is maintained to depth of 10 cm. Skid road soil showed higher bulk density values than undisturbed areas because of compaction. 相似文献
579.
The Influence of Mycorrhiza on Uranium and Phosphorus Uptake by Barley Plants from a Field-contaminated Soil (7 pp) 总被引:3,自引:0,他引:3
Chen B Zhu YG Zhang X Jakobsen I 《Environmental science and pollution research international》2005,12(6):325-331
Background Recent studies indicated that arbuscular mycorrhizal fungi (AMF) play important roles in plant accumulation of uranium (U)
from contaminated environments, but the impacts of fertilization practices on functioning of the symbiotic associations, which
are crucial factors influencing plant nutrition and growth responses to mycorrhiza, have rarely been considered.
Materials and Methods In a greenhouse experiment, a bald root barley mutant (brb) together with the wild type (wt) were used to test the role of
root hairs and AMF in uranium (U) uptake by host plants from a U contaminated soil. Nil, 20 and 60 mg KH2PO4-P kg–1 soil were
included to investigate the influences of phosphorus (P) fertilization on plant growth and accumulation of U.
Results Dry matter yield of barley plants increased with increasing P additions and wt produced significantly higher dry weight than
brb. Mycorrhiza markedly improved dry matter yield of both genotypes grown at nil P, whereas only brb responded positively
to mycorrhiza at 20 mg P kg-1. At the highest P level, mycorrhiza resulted in growth depressions in both genotypes, except
for the roots of wt. In general, plant P concentrations increased markedly with increasing P additions and in response to
mycorrhiza.
Mycorrhiza and P additions had no significant effects on shoot U concentrations. However, root U concentrations in both genotypes
were significantly increased by mycorrhiza. On the other hand, shoot U contents increased with increasing P levels, while
20 mg P kg-1 stimulated, but 60 mg P kg-1 marginally affected the U accumulation in roots. Root length specific U uptake was
moderately enhanced both by root hairs and strongly enhanced by mycorrhiza. Moreover, non-inoculated plants generally had
higher shoot-root ratios of U content than the corresponding inoculated controls.
Conclusion Our study shows that AMF and root hairs improves not only P acquisition but also the root uptake of U, and mycorrhiza generally
decreases U translocation from plant root to shoot. Hence, mycorrhiza is of potential use in the phytostabilization of U contaminated
environments.
Perspectives The complex impacts of P on U accumulation by barley plants suggested that U behavior in mycorrhizosphere and translocation
along the soil-fungi-plant continuum as affected by fertilization practices deserve extensive studies for optimizing the function
of mycorrhizal associations for phytoremediation purposes. 相似文献
580.
Yu X Zhou P Zhou X Liu Y 《Environmental science and pollution research international》2005,12(4):221-226
Background Little is known about metabolism rates of environmental chemicals by vegetation. A good model compound to study the variation
of rates among plant species is cyanide. Vascular plants possess an enzyme system that detoxifies cyanide by converting it
to the amino acid asparagine. Knowledge of the kinetic parameters, the half-saturation constant (Km) and the maximum metabolic
capacity (vmax), is very useful for enzyme characterization and biochemical purposes. The goal of this study is to find the
enzyme kinetics (KM and vmax) during cyanide metabolism in the presence of Chinese vegetation, to provide quantitative data
for engineered phytoremediation, and to investigate the variation of metabolic rates of plants.
Methods Detached leaves (1.0 g fresh weight) from 12 species out of 9 families were kept in glass vessels with 100 mL of aqueous
solution spiked with potassium cyanide at 23°C for 28 h. Four different treatment concentrations of cyanide were used, ranging
from 0.44 to 7.69 mg CN/L. The disappearance of cyanide from the aqueous solution was analyzed spectrophotometrically. Realistic
values of the half-saturation constant (KM) and the maximum metabolic capacity (vmax) were estimated by a computer program
using non-linear regression treatments. As a comparison, Lineweaver-Burk plots were also used to estimate the kinetic parameters.
Results and Discussion The values obtained for KM and vmax varied with plant species. Using non-linear regression treatments, values of vmax and
KM were found in a range between 6.68 and 21.91 mg CN/kg/h and 0.90 to 3.15 mg CN/L, respectively. The highest vmax was by
Chinese elder (Sambucus chinensis), followed by upright hedge-parsley (Torilis japonica). The lowest vmax was demonstrated
by the hybrid willow (Salix matssudana x alba). However, the highest KM was found in the water lily (Nymphea teragona), followed
by the poplar (Populus deltoides Marsh). The lowest KM was demonstrated by corn (Zea mays L.). The values of vmax were normally
distributed with a mean of 13 mg CN/kg/h.
Conclusions Significant removal of cyanide from aqueous solution was observed in the presence of plant materials without phytotoxicity,
even at high doses of cyanide. This gives rise to the conclusion that the Chinese plant species used in this study are all
able to efficiently metabolize cyanide, although with different maximum metabolic capacities. A second conclusion is that
the variation of metabolism rates between species is small. All these plants had a similar KM, indicating the same enzyme
is active in all plants.
Recommendations and Outlook Detoxification of cyanide with trees seems to be a feasible option for cleaning soils and water contaminated with cyanide.
For phytoremediation projects, screening appropriate plant species adapted to local conditions should be seriously considered.
More chemicals should be investigated to find common principles of the metabolism of environmental chemicals by plants. 相似文献