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581.
Atmospheric BTEX concentrations in the vicinity of the crude oil refinery of the Baltic region 总被引:1,自引:0,他引:1
Baltrėnas P Baltrėnaitė E Serevičienė V Pereira P 《Environmental monitoring and assessment》2011,182(1-4):115-127
Among chemical industries, petroleum refineries have been identified as large emitters of a wide variety of pollutants. Benzene, toluene, ethylbenzene, and xylene (BTEX) form an important group of aromatic volatile organic compounds (VOCs) because of their role in the troposphere chemistry and the risk posed to human health. A very large crude oil refinery of the Baltic States (200,000 bbl/day) is situated in the northern, rural part of Lithuania, 10 km from the town of Ma?eikiai (Lithuania). The objectives of this study were: (1) to determine of atmospheric levels of BTEX in the region rural and urban parts at the vicinity of the crude oil refinery; and (2) to investigate the effect of meteorological parameters (wind speed, wind direction, temperature, pressure, humidity) on the concentrations measured. The averaged concentration of benzene varied from 2.12 ppbv in the rural areas to 2.75 ppbv in the urban areas where the traffic was determined to be a dominant source of BTEX emissions. Our study showed that concentration of benzene, as strictly regulated air pollutant by EU Directive 2008/50/EC, did not exceed the limit of 5 ppbv in the region in the vicinity of the crude oil refinery during the investigated period. No significant change in air quality in the vicinity of the oil refinery was discovered, however, an impact of the industry on the background air quality was detected. The T/B ratio (0.50-0.81) that was much lower than 2.0, identified other sources of pollution than traffic. 相似文献
582.
Dorte Vigs? 《Waste management & research》2004,22(6):477-487
This study compares the social costs and environmental benefits of collecting single use drink containers through the Danish deposit system with the social costs and benefits of treating the containers as part of the municipal waste-disposal system. It focuses on single use polyethylene terphthalate and glass bottles, and steel and aluminium cans. The social costs of handling these containers in the deposit system includes the costs of collection, sorting, and transportation, adjusted against the profit from selling the collected material for recycling. The social cost of incinerating these containers as municipal waste consists of the expenses for the collection, incineration of the containers and disposal of ashes. If there is any income from energy generation accompanying incineration, this is adjusted against costs. The main environmental effects related to both strategies are quantified, valuated and included in the assessment. The results of the analysis show that there are significant social costs compared to the benefits connected with the new deposit system. This is true for all four types of single use drink containers examined. All in all, Denmark bears a net social cost of 6.7 to 8.1 million Euros per year compared to a baseline of incineration with energy recovery. 相似文献
583.
Landfill processes were simulated in laboratory-scale bioreactors--lysimeters. The changes in leachate characteristics as well as the influence of advanced oxidation processes (AOPs) on the processes taking place in the sanitary landfill were investigated. Lysimeters were filled with material simulating municipal waste in the city of Lodz, Poland. Compost in the amount of 30% w/w and the methanogens inoculum were added in order to enhance development of a methanogenic phase. The leachate produced in lysimeters was recirculated. In order to investigate the influence of AOPs implementation on processes taking place in landfills two runs in lysimeters were performed, each lasting about 250 days. The leachate composition and biogas composition and production changes showed trends that confirmed that the bench-scale lysimeters appeared suitable to simulate processes taking place in the landfill. The application of AOPs to the leachate recirculated into the lysimeters did not bring about unequivocally positive effects. The ozonation of the leachate, implemented at the beginning of the methanogenic phase, caused slight acceleration (about 2 weeks) of the biodegradation, whereas employment of H2O2/UV led to the inhibition of anaerobic processes. 相似文献
584.
Ma?gorzata Grodzińska-Jurczak Hanna Zakowska Adam Read 《Waste management & research》2004,22(3):212-223
In recent years the issue of the municipal waste in Poland has become increasingly topical, with a considerable rise in the waste generation, much of which can be attributed to a boom in product packaging (mainly plastic). The annual production of plastics packaging has been constantly increasing over the last 20 to 30 years, and now exceeds 3.7 million tons. Due to a lack of processing technologies and poorly developed selective segregation system, packaging waste is still treated as a part of the municipal solid waste (MSW) stream, most of which is landfilled. As a result of Poland's access to the European Union, previous legal regulations governing municipal waste management have been harmonized with those binding on the member countries. One of the main changes, the most revolutionary one, is to make entrepreneurs liable for environmental risks resulting from the introduction of packaging to the market, and for its recycling. In practice, all entrepreneurs are to ensure recovery, and recycling, of used packaging from products introduced to the market at the required level. In recent year, the required recycling levels were fulfilled for all types of materials but mainly by large institutions using grouped and transport packaging waste for that matter. Household packaging gathered in the selective segregation system at the municipalities was practically left alone. This paper is an attempt to describe the system and assess the first year of functioning of the new, revamped system of packaging waste management in Poland. Recommendations are made relating to those features that need to be included in packaging waste management systems in order to maximize their sustainability and harmonization with the EU legal system. 相似文献
585.
586.
The expected impact of the “Peace Conduit” project (the Red Sea - Dead Sea pipeline) on the Dead Sea
Ittai?GavrieliEmail author Amos?Bein Aharon?Oren 《Mitigation and Adaptation Strategies for Global Change》2005,10(4):759-777
The Dead Sea is a severely disturbed ecosystem, greatly damaged by anthropogenic intervention in its water balance. During
the 20th century, the Dead Sea level dropped by more than 25 meters, and presently (2003) it is at about 416 meters below
mean sea level. This negative water balance is mainly due to the diversion of water from the catchment area of the lake by
Israel, Jordan and Syria. During the 2002 World Summit on Sustainable Development Israel and Jordan jointly announced their
interest in saving the Dead Sea by constructing the “Peace Conduit” that will pipe water from the Red Sea to the Dead Sea.
The inflow of seawater (or reject brine after desalinization) into the Dead Sea will have a major impact on its limnology,
geochemistry and biology. During the filling stage, relatively diluted surface water will form and the rate of evaporation
will therefore increase. Dilution of the surface water will most likely result in microbial blooming whose duration is not
known, while the lower water layer is likely to develop reducing conditions, including bacterial sulfate reduction and presence
of hydrogen sulfide (H2S). Mixing between the calcium-rich Dead Sea brine and the sulfate-rich seawater will result in gypsum precipitation (CaSO4⋅ 2H2O). Once the target level is reached, inflow will be outbalanced by evaporation and salinity of the surface water will increase
due to accumulation of seawater-salts. The water column will re-mix when the density of the surface water will equal that
of the lower water column. In spite of its large volume and high salinity relative to that of the inflowing water, over the
long run the composition of this unique lake will change. Before a decision is made on the planning and construction of the
Conduit, it is essential that the long term evolution and characteristics of the “renewed” Dead Sea be known and anticipated
changes examined. Once decided upon, the planning and construction of the Conduit should be conducted so as to minimize possible
negative impacts of seawater introduction on the Dead Sea. This can only be achieved through a thorough understanding of the
expected changes in the limnological physical/chemical characteristics of the Dead Sea and its unique brine. 相似文献
587.
Ernst Mayr: the doyen of twentieth century evolutionary biology 总被引:1,自引:0,他引:1
Hölldobler B 《Die Naturwissenschaften》2004,91(6):249-254
588.
589.
590.
Al/Si configurations in some natural and synthetic Rb-feldspars have been examined carefully by EMPA and XPS analyses. Our results indicate that a small amount of H2O and excess Si and Al are incorporated in hydrothermally synthesized Rb-feldspar. The quantities of excess Al are 0.056 atoms per formula unit and are negatively correlated with those of the Rb, suggesting the presence of excess Al occupying non-tetrahedral sites in feldspar structures. This leads to incorporation of Al(Al3Si)O8 endmember into Rb-feldspars, estimated as one appropriate endmember indication for unusual chemistry of feldspars. In addition, Si2p, Al2p and O1s XPS signals of Rb-feldspars shift drastically toward the higher energy side than those of any natural feldspars. These provide conclusive evidence not only for existence of perceptible excess Si and Al, but also for Al at both extra-framework and tetrahedral sites in feldspar structures. 相似文献