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631.
Fast transformation of roxarsone into toxic arsenic species with ferrous iron and tetrapolyphosphate
Chen Na Wan Yichao Ai Zhihui Jia Falong Zhang Lizhi 《Environmental Chemistry Letters》2019,17(2):1077-1084
Environmental Chemistry Letters - Organoarsenic compounds have been widely used as feed additives in livestock and poultry breeding. They are excreted in manure and thus cause environmental... 相似文献
632.
G. Yuan D. Chen L. Yin Z. Wang L. Zhao J.Y. Wang 《Waste management (New York, N.Y.)》2014,34(6):1045-1050
In this research a gas–liquid fluidized bed reactor was developed for removing chlorine (Cl) from polyvinyl chloride (PVC) to favor its pyrolysis treatment. In order to efficiently remove Cl within a limited time before extensive generation of hydrocarbon products, the gas–liquid fluidized bed reactor was running at 280–320 °C, where hot N2 was used as fluidizing gas to fluidize the molten polymer, letting the molten polymer contact well with N2 to release Cl in form of HCl. Experimental results showed that dechlorination efficiency is mainly temperature dependent and 300 °C is a proper reaction temperature for efficient dechlorination within a limited time duration and for prevention of extensive pyrolysis; under this temperature 99.5% of Cl removal efficiency can be obtained within reaction time around 1 min after melting is completed as the flow rate of N2 gas was set around 0.47–0.85 Nm3 kg?1 for the molten PVC. Larger N2 flow rate and additives in PVC would enhance HCl release but did not change the final dechlorination efficiency; and excessive N2 flow rate should be avoided for prevention of polymer entrainment. HCl is emitted from PVC granules or scraps at the mean time they started to melt and the melting stage should be taken into consideration when design the gas–liquid fluidized bed reactor for dechlorination. 相似文献
633.
Zhijian Liu Haiyang Liu Hang Yin Rui Rong Guoqing Cao Qihong Deng 《Frontiers of Environmental Science & Engineering》2021,15(3):36
634.
Md. Musfiqur Rahman Tae Woong Na A. M. Abd El-Aty Jong-Hyouk Park M. N. U. Al Mahmud Angel Yang Ki Hun Park Jae-Han Shim 《Environmental monitoring and assessment》2013,185(11):9461-9469
The pre-harvest residue limit (PHRL) of abamectin (abamectin B1a and B1b) in Perilla frutescens leaves grown under greenhouse conditions were investigated using high-performance liquid chromatography with a fluorescence detector. Samples were extracted with acetonitrile. The extract was purified through a solid phase extraction procedure. Then the purified extract was derivatized with trifluoroacetic anhydride and N-methylimidazole to form a strong stable fluorescent derivative of abamectin. Finally, derivatized abamectins were conveyed to the detector via an Atlantis C18 column, with water and methanol as a mobile phase. Calibration curves were linear over the calibration ranges with coefficients of determinants r 2?≥?0.999. The limits of detection and quantification were 0.0033 and 0.01 mg kg?1 for abamectin B1a and B1b, respectively. Recovery was assessed in a control matrix at two different fortification concentrations, with three replicates for each concentration. Good recoveries were obtained for the target analytes and ranged from 82.11 to 93.03 %, with relative standard deviations of less than 8 %. The rate of disappearance of total abamectin on perilla leaves for recommended and double the recommended doses was described as first-order kinetics with a half-life of 0.7 days. Using the PHRL curve, we could predict the residue level of total abamectin to be 0.92 mg kg?1 at 7 days before harvest or 0.26 mg kg?1 at 4 days before harvest, which would be below the provisional MRL designed by the Korea Food and Drug Administration. 相似文献
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反应位移法是目前地下结构抗震设计中应用最为广泛的简化方法之一,其中的一个关键参数是结构周围弹簧刚度系数。基于《城市轨道交通结构抗震设计规范》(GB 50909—2014)中简化的静力有限元法,进行了不同加载形式的静力有限元刚度法和柔度法计算弹簧刚度系数,将其计算结果应用于反应位移法与严格的动力时程计算结果进行对比研究。结果表明:不论静力有限元刚度法还是柔度法,除水平竖直加载方式外,其余的加载方式确定的地基弹簧系数对反应位移法计算的结构变形及内力影响较小。考虑计算次数,可以采用刚度法和柔度法中的径向切向和径向环向一次加载方式对静力有限元法进行简化计算。 相似文献
639.
Jianhua Wang Yizi Shang Hao Wang Yong Zhao Yin Yin 《Journal of the American Water Resources Association》2015,51(3):614-623
Beijing's local water resources have been overexploited and the ecological and environmental pressures exceed the carrying capacity of this densely populated megacity. This article examines the current status of Beijing's water resources with respect to its industrial, residential, and eco‐environmental water usage and the challenges it may face in the near future. The article describes the context of water uses, the steps taken by Beijing to alleviate the water shortage problems, and challenges to Beijing's abilities to meet its urgent and future water needs. A multipronged strategy is proposed that aims at both the present problems and the anticipated future challenges. In particular, engineering and institutional approaches for Beijing's successful transition from overexploitation to sustainable utilization of water resources are explained. Actions include reasonable water utilization, water conservation, reclaimed wastewater, and importing water from neighboring areas. We conclude that Beijing must take additional steps in water resource management to ensure its sustainable development that involves continued urbanization sprawls and population growth. Future water resource management strategies should focus on strengthening water demand management through water conservation, efficient interbasin water transfers, use of nontraditional water resources, strategically reserving water supply, and promoting rehabilitation of the eco‐environments. 相似文献
640.
利用新型组合填料的生物滴滤塔净化混合废气研究 总被引:1,自引:0,他引:1
建立了生物滴滤中试装置,并将前期研发的纹翼多面球和空心多面柱作为组合填料,以甲苯和乙醇混合气为废气,研究了组合填料生物滴滤塔的污染物去除性能.结果表明,装有组合填料的生物滴滤塔能在8 d内完成挂膜,稳定运行时对甲苯和乙醇的去除负荷分别为97.14 g·(m3·h)~(-1)和113.10 g·(m3·h)~(-1).空床停留时间(EBRT)和进气浓度对甲苯去除效果影响明显,当EBRT为21.11 s,甲苯和乙醇最大去除负荷分别为123.34 g·(m3·h)~(-1)和206.36 g·(m3·h)~(-1);受营养液喷淋量影响不明显,本系统最佳液气比为6.82 L·m~(-3).模拟了不稳定工况对系统处理效果的影响,用Na OH溶液减轻填料层堵塞效果明显,并可以3 d内恢复对甲苯和乙醇的去除效果;停运10 d后继续运行,净化性能可迅速恢复. 相似文献