Study on determination of iron,cobalt, nickel,copper, zinc and manganese in drinking water by solid-phase extraction and RP-HPLC with 2-(2-quinolinylazo)-5-diethylaminophenol as precolumn derivatizing reagent

A new method for the determination of iron, cobalt, nickel, copper, zinc and manganese in drinking water by the reversed-phase high-performance liquid chromatography (RP-HPLC) with 2-(2-quinolinylazo)-5-diethylaminophenol (QADEAP) as precolumn derivatizing reagent was studied in this paper. The iron, cobalt, nickel, copper, zinc, and manganese ions react with QADEAP to form color chelates in the presence of cetyl trimethylammonium bromide (CTMAB) and acetic acid-sodium acetic buffer solution medium of pH 4.0. These chelates were enriched by solid-phase extraction with a Waters Nova-Pak C18 cartridge and eluted the retained chelates from the cartridge with tetrahydrofuran (THF). The enrichment factor of 100 was achieved. Then the chelates were separated on a Waters Nova-Pak C18 column (3.9 x 150 mm, 5 microm) by gradient elution with methanol (containing 0.2% of acetic acid and 0.1% of CTMAB) and 0.05 mol L(-1) acetic acid-sodium acetic buffer solution (containing 0.1% of CTMAB) (pH 4.0) as mobile phase at a flow rate of 0.5 ml min(-1), and monitored with a photodiode array detector from 450 approximately 700 nm. The detection limits (S/N = 3) of iron, cobalt, nickel, copper, zinc and manganese are 0.8, 1.1, 0.9, 1.1, 1.5 and 2.0 ng L(-1), respectively, in the original sample. This method can be applied to determination at the microg L(-1) level of iron, cobalt, nickel, copper, zinc and manganese in drinking water with good results.     

采测分离中分析测站记录审核常见问题剖析

根据国家地表水采测分离工作实施要求,剖析了分析测站在采测分离记录审核中经常遇到的各种问题,诸如《国家地表水环境质量监测网监测任务作业指导书(试行)》执行中技术记录与质量保证和质量控制要求存在客观差异、分析测站人员对所用记录表理解不透以及分析人员的失误等。结合分析测站实际工作情况,提出了进一步完善质量体系、优化技术记录、规范技术要求、提高执行意识、综合提升监测数据质量的建议。     

我国城市污水工业回用的现状及存在问题的探讨

略述了近几年来我国城市污水工业回用的一些成功经验 ,提出了城市污水工业回用中存在的几个主要问题及其对策 ,展望了我国在这一领域的发展前景。     

生态系统健康评价的研究进展

回顾了生态系统健康的概念,阐述了水生态系统健康评价的三种指标体系:指示物种指标体系、结构功能指标体系、V-O-R指标体系.其中,结构功能指标体系从选取指标和指标分类两方面进行了方法归纳,分析了生态系统健康的几种评价方法,以及讨论了生态系统健康研究中存在的问题和发展趋势.     

重庆市区地质灾害信息数据库设计

本文通过对重庆市地质灾害系统分析，得到重庆市地质灾害的基本规律，在此基础上，将重庆市各种地质灾害的信息输入计算机，基于地理信息系统（MAPGIS）建立重庆市地质灾害属性数据库，实现地质灾害空间信息管理，查询，更新以及稳定性分析，为城市地质灾害的防治和管理提供了可靠的平台。     

新滩滑坡稳定性的有限元分析

根据新滩滑坡的地质背景和工程地质特征，建立了滑坡地质模型，运用有限元数值模拟方法对其稳定性与地质环境的关系进行了分析，并对影响因素作了比较，明确了其形成机理。     

对马陵山地震台观测环境的分析

1　台站概况马陵山地震台位于郯城县城东北 2 0千米马陵山主峰西坡 ,地理坐标东经 1 1 8°2 7′2 1″,北纬34°4 2′8″ ,海拔 1 1 0米。台站位于沂沭断裂带内安丘———莒县断裂带东侧。台基岩石为白垩系紫红色砂岩、粉页岩 ,地层倾向东南 ,倾角 6 0°～ 70°。受断裂构造影响 ,台基岩石比较破碎。该台是海城地震后 ,根据国务院 6 9号文件为加强郯庐活动断裂地震监测与研究而设立的。 1 975年 3月建成 ,同年部分仪器投入观测 ,台站大部分仪器放置在部队开挖的备战坑道 ,坑道全长1 51 5米 ,洞内年温差小于 0 3℃ ,从环境上看是比较理想的。…     

变截面门式刚架结构极限承载力分析

采用变截面薄腹构件是门式刚架结构轻型化的主要措施之一。如何利用变截面薄腹构件的腹板屈曲后强度并同时保证构件乃至结构的安全度始终是门式刚架结构工程设计的重要内容。根据有效宽度法的基本思想,提出了相关屈曲系数概念,在变截面H钢构件双重非线性数值分析基础上获得的局部屈曲荷载拟合公式,应用于变宽度楔形腹板的有效宽度简化计算公式当中。应用改进后的有效宽度法,进行了变截面门式刚架结构考虑构件局部屈曲影响的极限承载力分析,探讨了腹板平均宽厚比、腹板楔率对结构极限承载力的影响,提出了对变截面门式刚架结构优化设计的工程建议,并具有工程指导意义。     

含磷废水处理的研究现状

简要介绍了含磷废水造成的富营养化问题所带来的危害，分析了含磷废水的主要来源，详尽介绍了当前处理含磷废水的各种不同方法，主要介绍了化学沉淀法、生物法、吸附法等在含磷废水处理方面的应用。最后，简要介绍了排放废水污染的控制与恢复。     

A HYDRODYNAMIC MODELING STUDY TO DETERMINE THE OPTIMUM WATER INTAKE LOCATION IN LAKE PALDANG,KOREA1

A three‐dimensional hydrodynamic model was applied to Lake Paldang, South Korea. The lake has three inflows, of which Kyoungan Stream has the smallest flow rate and poorest water quality. Since all drinking water intake stations are located near the confluence of Kyoungan Stream within the lake, this contaminated tributary may have a significant impact on the quality of drinking water sources. The optimum drinking water intake location was determined from the applied model. The model was calibrated and verified using the data measured under different hydrological conditions. The model results were in reasonable agreement with the field measurements in both calibration and verification. The circulation and spreading patterns of the incoming flows in the lake, as well as their composition ratios to the drinking water intakes were determined from the model, and three alternative intake locations were proposed. The simulation results suggested that the horizontal and vertical relocations of the intake aqueduct could significantly decrease the composition ratio of the contaminated water. From this study, it was concluded that the three‐dimensional hydrodynamic model could successfully simulate the temporal and spatial mixing patterns of incoming flows and become a useful tool in determining the optimum water intake location in Lake Paldang.