电感耦合等离子体质谱技术在环境监测中的应用进展

电感耦合等离子体质谱技术(ICP-MS)是目前发展最快的痕量元素分析测试技术之一。由于该技术提供了极低的检出限、极宽的动态线性范围,干扰少、分析精密度高,可进行多元素同时快速分析,可与多种分离技术及样品前处理方法和进样方法相结合等优点,得到了迅速的发展。介绍了ICP-MS的基本原理及仪器构造、与其他分析测试技术的比较及发展趋势,并着重介绍了其在环境监测和环境科学研究领域的应用。     

用微宇宙法研究稀土元素在富营养化水体中的归趋

本文利用静态实验室水生微宇宙的方法研究了轻、中、重三类五种稀土混合物（La,Ce,Sm,Gd,Y）在富营养水体、底泥、浮萍、大型蚤、螺蛳和金鱼中的分布和富集。结果表明,稀土在水生微宇宙各组分中的分布和积累的趋势为轻稀土>中稀土>重稀土。稀土元素在水体中6h后基本趋于平衡,其大部分为底泥所吸附;不同生物对稀土的分布和富集存在着较大的差异,其趋势为浮萍>大型蚤>螺蛳>金鱼。     

二安替比林卤代苯基甲烷衍生物与锰显色反应研究

合成了６个二安替比林卤代苯基甲烷衍生物,研究了它们和锰的显色反应规律,提出了该类试剂的一些新用途,显示了其良好的应用前景。     

Enhancement of solar-driven photocatalytic activity of oxygen vacancy-rich Bi/BiOBr/Sr2LaF7:Yb3+,Er3+ composites through synergetic strategy of upconversion function and plasmonic effect

For better use of solar energy,the development of efficient broadband photocatalyst has attracted extraordinary attention.In this study,a ternary composite consisting of Sr₂ LaF₇:Yb³⁺,Er³⁺ upconversion(UC) nanocrystals and Bi nanoparticles loaded BiOBr nanosheets with oxygen vacancies(OVs,SLFBB) was designed and synthesized by multistep solvent-thermal method.Mechanisms of in-situ formation of Bi nanoparticles and OVs in BiOBr/Sr₂ LaF_7<...     

Characterization of heavy metal concentrations in the sediments of three freshwater rivers in Huludao City, Northeast China

Wuli River, Cishan River, and Lianshan River are three freshwater rivers flowing through Huludao City, in a region of northeast China strongly affected by industrialization. Contamination assessment has never been conducted in a comprehensive way. For the first time, the contamination of three rivers impacted by different sources in the same city was compared. This work investigated the distribution and sources of Hg, Pb, Cd, Zn and Cu in the surface sediments of Wuli River, Cishan River, and Lianshan River, and assessed heavy metal toxicity risk with the application of two different sets of Sediment Quality Guideline (SQG) indices (effect range low/effect range median values, ERL/ERM; and threshold effect level/probable effect level, TEL/PEL). Furthermore, this study used a toxic unit approach to compare and gauge the individual and combined metal contamination for Hg, Pb, Cd, Zn and Cu. Results showed that Hg contamination in the sediments of Wuli River originated from previous sediment contamination of the chlor-alkali producing industry, and Pb, Cd, Zn and Cu contamination was mainly derived from atmospheric deposition and unknown small pollution sources. Heavy metal contamination to Cishan River sediments was mainly derived from Huludao Zinc Plant, while atmospheric deposition, sewage wastewater and unknown small pollution were the primary sources for Lianshan River. The potential acute toxicity in sediment of Wuli River may be primarily due to Hg contamination. Hg is the major toxicity contributor, accounting for 53.3-93.2%, 7.9-54.9% to total toxicity in Wuli River and Lianshan River, respectively, followed by Cd. In Cishan River, Cd is the major sediment toxicity contributor, however, accounting for 63.2-66.9% of total toxicity.     

甲氰菊酯降解菌鉴定及其降解特性

从农药厂污泥中分离到一株能降解甲氰菊酯的光合细菌PSB07-19.鉴定结果表明,PSB07-19为沼泽红假单胞菌(Rhodopseudomonas palustris),其最适生长温度为30℃,最适pH为6.5.实验结果表明,该菌以共代谢方式降解甲氰菊酯,对甲氰菊酯的最大耐受质量浓度为600 mg/L,培养15 d对400 mg/L甲氰菊酯的降解率达45.51%,降解最适pH、温度分别为7.5、30℃.     

纳米Bi2O3/TiO2复合光催化剂的制备及性能研究

以光催化效果为评价标准,采用超声波作用下水解法制备Bi₂O₃/TiO₂复合光催化剂,考察了水解条件和Bi₂O₃掺入量等制备条件对复合光催化剂性能的影响。结果表明,与传统制备方法相比,该方法操作简单、快速;当水和乙醇的比例为4∶1时所得样品的光催化活性最好;Bi₂O₃的掺入拓宽了TiO₂对光的吸收范围,提高了TiO₂的光催化活性,掺入量(Bi₂O₃)为0.25%复合光催化剂催化活性最高;复合光催化剂对多种水溶性染料均具有较好的处理效果。     

自然灾害风险评估国际计划述评Ⅰ——指标体系

自然灾害风险评估是综合灾害风险管理的关键途径。概述了近年来3个重要的自然灾害风险评估国际计划：灾害风险指标计划（Din）、多发区指标计划（Hotspots）和美洲计划（American Programme）的目标与成果。重点介绍了3个国际计划选取的指标：DRI首次开发了2个脆弱性全球指标;Hotspots发展了3个灾害风险指数;美洲计划开发了4个独立的指标体系,用于描述国家级的灾害风险构成要素,同时,提出城市级的风险评估指标。通过比较3个国际计划选择的指标体系的优缺点,提出选择能全面反映脆弱性和风险特征、计算简便的指标是今后灾害风险评估的关键和重点。     

成渝地区大气污染生命统计价值评价研究——基于单边界二分式的条件价值法

大气污染生命统计价值是进行大气污染造成的人体健康损失核算和大气污染防治政策成效评估的关键指标。本文运用条件价值方法的单边界二分式函数模型,对成渝地区降低大气污染健康风险的平均支付意愿和生命统计价值进行了计算。主要结论如下:①成渝地区大气污染的平均支付意愿是1974.2元,生命统计价值为394.8万元。其中,四川部分地区和重庆地区的生命统计价值分别为402万元和392.8万元。②性别、家庭年收入和自我认知的身体健康状况等指标对平均支付意愿影响较大。③在生命价值评估方法中,国内普遍使用人力资本法,而国外主要使用条件价值法。条件价值法计算的生命统计价值高于人力资本法计算的结果,但与发达国家相比,我国成渝地区的生命统计价值相对较低。     

高校校园盥洗废水回用分析

以四川大学望江校区为例,分析了高校校园学生宿舍盥洗废水回用的必要性、可行性和优势,对盥洗废水回用方案进行了规划,并对人工湿地在校园中水回用中的意义进行了分析.结果表明,在高校校园中进行中水回用具有可观的环境效益、经济效益和社会效益.