Metals removal from aqueous solution by iron-based bonding agents

GOAL AND SCOPE AND BACKGROUND: The application of a promising method, termed sorptive flotation, for the removal of chromium(VI) and zinc ions was the aim of the present paper. A special case of sorptive flotation is adsorbing colloid flotation. Suitable sorbent preparation techniques have been developed in the laboratory. METHODS: Sorptive flotation, consisting of the sorption and flotation processes combined in series, has proved to give fast and satisfactory treatment of the industrial streams and effluents bearing dilute aqueous solutions of zinc and chromium(VI). RESULTS AND DISCUSSION: Goethite has proved to be effective for the removal of chromium(VI) and zinc ions. Also, adsorbing colloid flotation with ferric hydroxide (as the co-precipitant) could be an alternative method to the above-mentioned separation of metal ions. In both cases, chromium(VI) (pH=4) and zinc (pH=7) removal was about 100%. CONCLUSION: The reasons for selecting the iron-based bonding materials, like goethite and/or in-situ produced ferric hydroxide, are that they are cheap, easily synthesized, suitable both for cation and anion sorption, and, furthermore, that they present low risks for adding a further pollutant to the system. Promising results were obtained. RECOMMENDATION AND OUTLOOK: The application of goethite and in-situ produced ferric hydroxide has demonstrated their effectiveness in the removal of heavy metal ions, such as chromium anions and zinc cations. A proposed continuation of current work is the utilization of similar iron oxides, for instance synthesized akaganeite. The comparison between the results reported in this paper with the results reported in the literature, also deserves attention.     

Evaluation of the pollution of the surface waters of Greece from the priority compounds of list II, 76/464/EEC directive, and other toxic compounds

The pollution of the surface waters of Greece from the priority compounds of 76/464/EEC Directive was evaluated. The occurrence of 92 toxic compounds, 64 of which belong to priority compounds of List II, candidates for List I, of 76/464/EEC Directive, was studied in surface waters and wastewater through the developed network of 62 sampling stations, which covers the whole Greek territory. The analytical determination was performed by Purge and Trap-Gas chromatography-Mass spectrometry for volatile and semivolatile organic compounds (VOCs), Gas Chromatography-Electron Capture Detection for organochlorine insecticides, Gas Chromatography-Nitrogen Phosphorous Detection for organophosphorous insecticides, High Performance Liquid Chromatography-Photodiode Array Detection for herbicides, and Electrothermal Atomic Absorption Spectrophotometry and Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) for metals and the toluene extractable organotin compounds. The concentrations of VOCs and insecticides detected in the surface waters of Greece were very low, whereas the concentrations of herbicides and metals ranged generally at moderate levels. VOCs were detected almost exclusively in the rivers and very rarely in the lakes, while the frequency of occurrence of insecticides, herbicides and metals was similar for rivers and lakes. Water quality objectives (WQO) and emission limit values (ELV) have been laid down in national legal framework for a number of compounds detected in the samples, in order to safeguard the quality of surface waters from any future deterioration.     

Sediment pollution by heavy metals in the Strymonikos and Ierissos Gulfs,North Aegean Sea,Greece

Surface sediment samples from Strymonikos and Ierissos Gulfs wereanalyzed for Cu, Pb, Zn, Cr and Ni. The results showed that the sediment of Ierissos Gulf is more polluted with Cu, Pb, and Zn ascompared to that of Strymonikos Gulf. The benthal area located off the load-out facility of the mining operations in the town of Stratoni, in Ierissos Gulf is established as the most pollutedregion. The distribution of Cr and Ni in both gulfs indicates thenatural origin of these metals with the weathering of Strymon River and of other smaller rivers rocks being responsible for their enrichment.     

Comparative environmental assessment of biocides used in antifouling paints

In response to increasing scientific evidence on the toxicity and persistence of organotin residues from antifouling paints in the aquatic environment, the use of triorganotin antifouling products was banned on boats of less than 25 m length in many countries during 1987. Alternatives to tributyltin (TBT) paint are mainly copper based coatings containing organic booster biocides to improve the efficacy of the formulation, and have been utilised on small boats for the last 10 years. With policies encouraging a total ban on TBT, it is expected that these biocides will be used to a greater extent in the future. Limited data and information are available on the environmental occurrence, fate, toxicity, and persistence of these biocides, and thus any decisions on policies regulating antifoulants cannot be fully informed. In this study, a multicriteria comparison of alternative biocides, based on a general assessment of available information in the literature, provided support for the use of the precautionary principle with respect to policies on antifouling products. This assessment was validated by a more detailed comparison of four selected biocides and TBT. Results indicate that TCMS pyridine and TCMTB demonstrate environmental characteristics similar to TBT and thus detail risk assessments are needed before their use is permitted. The widespread use of the other biocides should be allowed only after research to fill the gaps in knowledge with respect to their toxicity and persistence in aquatic environments.     

Investigation of Cr(VI) reduction in continuous-flow activated sludge systems

The aim of this research was to investigate hexavalent chromium, Cr(VI), reduction by activated sludge and to evaluate the use of continuous-flow activated sludge systems for the treatment of Cr(VI)-containing wastewater. Three series of experiments were conducted using two parallel lab-scale activated sludge systems. During the first experiment, one system was used as a control, while the other received Cr(VI) concentrations equal to 0.5, 1, 3 and 5mg l(-1). For all concentrations added, approximately 40% of the added Cr(VI) was removed during the activated sludge process. Determination of chromium species in the dissolved and particulate phase revealed that the removed Cr(VI) was sorbed by the activated sludge flocs mainly as trivalent chromium, Cr(III), while the residual chromium in the dissolved phase was mainly detected as Cr(VI). Activated sludge ability to reduce Cr(VI) was independent of the acclimatization of biomass to Cr(VI) and it was not affected by the toxic effect of Cr(VI) on autotrophic and heterotrophic microorganisms. During the second experiment, both systems were operated under two different hydraulic residence time (theta equal to 20 and 28h) and three different initial organic substrate concentration (COD equal to 300, 150 and 0mg l(-1)). Cr(VI) reduction was favored by an increase of theta, while it was limited by influent COD concentration. Finally, at the last experiment the effect of anoxic and anaerobic reactors on Cr(VI) reduction was investigated. It was observed that the use of an anoxic zone or an anaerobic-anoxic zone ahead of the aerobic reactor favored Cr(VI) reduction, increasing mean percentage Cr(VI) reduction to almost 80%.     

Management of nutrient emissions of Axios River catchment: Their effect in the coastal zone of Thermaikos Gulf,Greece

The estimation of nutrient fluxes, the determination of spatial and temporal response and the understanding of biogeochemical changes in the past, present and future in the Axios River catchment, in Greece, as well as the impacts to the coastal zone of Thermaikos Gulf were accomplished by the use of harmonized watershed and coastal zone models. The mathematical model MONERIS was the watershed management model that was used to model the export loads of nutrients in Axios River. MONERIS was developed to estimate the nutrient inputs into river basins by point sources and various diffuse pathways. Watershed hydrologic and water quality data were collected and synthesized to develop input data sets for the simulation of Axios River catchment. The model was modified to better assess organic nitrogen export loads in Mediterranean watersheds. The results showed the importance of agricultural and livestock activities, concerning their nutrients emissions in the River. MONERIS was integrated with the coastal zone model WASP 6.0 to assess the impacts of the nutrient loads to the eutrophication status of the coastal zone. Several management scenarios were assessed. Management scenarios included measures for reduction in the emissions from the fertilizer plant of Veles, removal of phosphorous from the detergents in FYROM, treatment of urban wastes to EU Standards, reduction in N-fertilizer input, reduction in erosion and the green scenario that represented the maximum reduction scenario of all the measures together. The model simulations indicated that the coastal zone of Axios mouth will be eutrophic for nitrate (2.69–3.34 μM) and phosphate (0.2–0.68 μM) and upper mesotrophic for chlorophyll-a (0.74–1.45 μg/l) for the scenarios tested. The results suggest that the impact of the management scenarios will be largely negligible (no change in trophic status) for the Thermaikos Gulf sector nearby the Axios River due to additional sources such as the loads from Thessaloniki's waste water treatment plant which appear to affect the region to a greater extent. The integration of watershed and coastal zone models can be used to assess management scenarios in order to illustrate the significance of various land use practices to the eutrophication of the Gulf.     

Assessment of vulnerability of the eastern Cretan beaches (Greece) to sea level rise

Beaches are both sensitive and critical components of the coastal systems, as they are particularly vulnerable to environmental change (e.g., the sea level rise) and form valuable coastal ecosystems and economic resources. The objective of the present study has been to record the spatial characteristics and other attributes (e.g., topography, sediments and accessibility) of the 71 beaches of the E. Crete (Eastern Mediterranean) that are either already developed or have a reasonable development potential and assess their erosion risk under sea level rise. Beach retreats are predicted by ensembles of six cross-shore (1D) analytical and numerical morphodynamic models, set up/forced on the basis of collected/collated information and three sea level rise scenarios (0.26, 0.82 and 1.86 m); these retreats are then compared with the recorded maximum (dry) beach widths. Projections by the unified ensemble suggest that, in the case of a 0.26 m rise, 80 % of the examined beaches are to retreat by more than 20 and 16 % by more than 50 % of their maximum dry width. In the case of a 0.82 m rise, 72 % of the tested beaches are predicted to retreat by more than 50 % of their dry width and 21 % by a distance at least equal to their observed maximum dry widths. A sea level rise of 1.86 m represents a ‘doom’ scenario, as 75 % of the beaches are predicted to retreat by more than their maximum width. These results may be conservative, as other significant beach erosion factors (e.g., decreasing beach sediment supply) have not been considered.     

Chemical Characterization of Emissions from Vegetable Oil Processing and Their Contribution to Aerosol Mass Using the Organic Molecular Markers Approach

ABSTRACT

The organic fraction of aerosol emitted from a vegetable oil processing plant was studied to investigate the contribution of emissions to ambient particles in the surrounding area. Solvent-soluble particulate organic compounds emitted from the plant accounted for 10% of total suspended particles. This percentage was lower in the receptor sites (less than 6% of total aerosol mass). Nonpolar, moderate polar, polar, and acidic compounds were detected in both emitted and ambient aerosol samples. The processing and combustion of olive pits yielded a source with strong biogenic characteristics, such as the high values of the carbon preference index (CPI) for all compound classes. Polycyclic aromatic hydrocarbons (PAHs) detected in emissions were associated with both olive pits and diesel combustion. The chromatographic profile of dimethyl-phenanthrenes (DMPs) was characteristic of olive pit combustion. Organic aerosols collected in two receptor sites provided a different pattern.

The significant contribution of vehicular emissions was identified by CPI values (~1) of n-alkanes and the presence of the unresolved complex mixture (UCM). In addition, PAH concentration diagnostic ratios indicated that emissions from catalyst and noncatalyst automobiles and heavy trucks were significant. The strong even-to-odd predominance of n-alkanols, n-alkanoic acids, and their salts indicated the contribution of a source with biogenic characteristics. However, the profile of DMPs at receptor sites was similar to that observed for diesel particulates. These differences indicated that the contribution of vegetable oil processing emissions to the atmosphere was negligible.     

A multi-criteria sustainability assessment framework: development and application in comparing two food waste management options using a UK region as a case study

Preventing food wastage is a key element of sustainable resource management. But as food waste is still generated at high volumes, priority is placed on its proper management as a resource, maximising sustainability benefits. This study, by integrating a multi-criteria decision analysis with a sustainability assessment approach, develops a screening and decision support framework for comparing the sustainability performance of food waste management options. A structured process for selecting criteria based on the consideration of environmental, economic and social aspects related to region-specific food waste system planning, policy and management has been developed. Two food waste management options, namely the use of food waste disposal units, which grind food waste at the household’s kitchen sink and discharge it to the sewer, and the anaerobic co-digestion of separately collected food waste with sewage sludge, were selected for comparison due to their potential to create synergies between local authorities, waste and water companies, with local circumstances determining which of the two options to adopt. A simplified process used for assessing and comparing the two food waste management options in the Anglian region in the UK, indicated that there are benefits in using the framework as a screening tool for identifying which option may be the most sustainable. To support decision-making, a detailed analysis that incorporates stakeholders’ perspectives is required. An additional use of the framework can be in providing recommendations for optimising food waste management options in a specific region, maximising their sustainability performance.     

Fumaric acid production using renewable resources from biodiesel and cane sugar production processes

The microbial production of fumaric acid by Rhizopus arrhizus NRRL 2582 has been evaluated using soybean cake from biodiesel production processes and very high polarity (VHP) sugar from sugarcane mills. Soybean cake was converted into a nutrient-rich hydrolysate via a two-stage bioprocess involving crude enzyme production via solid state fermentations (SSF) of either Aspergillus oryzae or R. arrhizus cultivated on soybean cake followed by enzymatic hydrolysis of soybean cake. The soybean cake hydrolysate produced using crude enzymes derived via SSF of R. arrhizus was supplemented with VHP sugar and evaluated using different initial free amino nitrogen (FAN) concentrations (100, 200, and 400 mg/L) in fed-batch cultures for fumaric acid production. The highest fumaric acid concentration (27.3 g/L) and yield (0.7 g/g of total consumed sugars) were achieved when the initial FAN concentration was 200 mg/L. The combination of VHP sugar with soybean cake hydrolysate derived from crude enzymes produced by SSF of A. oryzae at 200 mg/L initial FAN concentration led to the production of 40 g/L fumaric acid with a yield of 0.86 g/g of total consumed sugars. The utilization of sugarcane molasses led to low fumaric acid production by R. arrhizus, probably due to the presence of various minerals and phenolic compounds. The promising results achieved through the valorization of VHP sugar and soybean cake suggest that a focused study on molasses pretreatment could lead to enhanced fumaric acid production.