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61.
Guanglong Pang Donghui Wang Yunhong Zhang Chunyan Ma Zhengping Hao 《Frontiers of Environmental Science & Engineering》2016,10(3):447-457
MnO2 microspheres with various surface structures were prepared using the hydrothermal method, and Au/MnO2 catalysts were synthesized using the sol-gel method. We obtained three MnO2 microspheres and Au/MnO2 samples: coherent solid spheres covered with wire-like nanostructures, solid spheres with nanosheets, and hierarchical hollow microspheres with nanoplatelets and nanorods. We investigated the properties and catalytic activities of formaldehyde oxidation at room temperature. Crystalline structures of MnO2 are the main factor affecting the catalytic activities of these samples, and γ-MnO2 shows high catalytic performance. The excellent redox properties are responsible for the catalytic ability of γ-MnO2. The gold-supported interaction can change the redox properties of catalysts and accelerate surface oxygen species transition, which can account for the catalytic activity enhancement of Au/MnO2. We also studied intermediate species. The dioxymethylene (DOM) and formate species formed on the catalyst surface were considered intermediates, and were ultimately transformed into hydrocarbonate and carbonate and then decomposed into CO2. A proposed mechanism of formaldehyde oxidation over Au/MnO2 catalysts was also obtained. 相似文献
62.
Reimo Rivis Are Kont Urve Ratas Valdeko Palginõmm Kait Antso Hannes Tõnisson 《Journal of Coastal Conservation》2016,20(3):199-209
The structure of coastal land cover in Estonia is intricate and exhibits considerable differences from site to site. The diverse geomorphology of the seashores is one of the key factors affecting the speed and magnitude of land cover changes. Likewise, the history of human inhabitance on the coast has also shaped the character of land cover. The Estonian coastal zone has experienced abrupt and radical changes in land ownership and its related land use during the last century. The main objectives of this paper are: 1) to give an overview of land use and the trends of development of land cover pattern along different parts of the Estonian coast; and 2) to analyze the relationships of natural and human processes and their cumulative impact on the evolution of coastal land cover pattern in Estonia. This study is based on results obtained during fieldwork in the study areas and on the analysis of large-scale (1:10,000) historical maps. In agriculturally dominant coastal areas, the traditional open landscape of fields and grassland at the beginning of the 20th century had been replaced by woodland and grasslands with shrubs by the start of the 21st century. Expansion of reed beds in areas of former seashore grasslands is another striking phenomenon. The structure of land cover on forested coasts has been fairly stable during the last 100 years. Areas of urban sprawl are characterised by dramatic changes in land cover structure. Rapidly increasing population and expanding settlements imposes on the ecological balance of the fragile dune forests in the coastal zone. 相似文献
63.
64.
Alamgir Hossain Jamal Naser Monzur Alam Imteaz 《Environmental Modeling and Assessment》2011,16(4):359-367
This paper presents comprehensive 3D numerical investigations on depositions of particles flowing through a horizontal pipe
loop consisting of four bends. The multiphase mixture model available in FLUENT 6.2 was used in this study. In this numerical
simulation, five different particle sizes have been used as secondary phases to calculate real multiphase effect in which
inter-particle interaction has been considered. The deposition of particles along the periphery of the pipe wall was investigated
as a function of particle size and fluid velocity. The simulations showed that near the upstream of the bends, maximum particle
concentration occurred at the bottom of the pipe. However, downstream the bends, the maximum particle concentration occurred
at an angle of 60° from the bottom. The larger particles clearly showed deposition near the bottom wall except downstream.
As expected, the smaller particles showed less tendency of deposition and lesser at higher velocity. This numerical investigation
showed qualitative agreement with the experiments conducted by Commonwealth Scientific and Industrial Research Organisation,
Melbourne team for similar conditions. 相似文献
65.
Konstantinos C. Makris Dibyendu Sarkar Jason Salazar Pravin Punamiya Rupali Datta 《Environmental science and pollution research international》2010,17(1):195-202
Background, aim, and scope
Alum (aluminum sulfate) is the currently preferred chemical amendment for phosphorus (P) treatment in poultry litter (PL). Aluminum-based drinking-water treatment residuals (Al-WTRs) are the waste by-product of the drinking-water treatment process and have been effectively used to remove P from aqueous solutions, but their effectiveness in PL water extracts has not been studied in detail. Elevated cost associated with alum could be minimized by using the equally effective WTRs to remove soluble P from PL, and they can be obtained at a minimal cost from drinking-water treatment plants. 相似文献66.
Leila Mehrparvar Siyamak Safapour Mousa Sadeghi-Kiakhani Kamaladin Gharanjig 《Environmental Chemistry Letters》2016,14(4):533-539
The classical use of synthetic dyes is causing issues of environmental pollution and heath risk. As a consequence natural dyes are gaining interest, but the use of natural dyes still includes toxic reagents such as metals as mordants and acids to enhance color and yield. Therefore, we designed a new chitosan-polypropylene imine dendrimer hybrid at 0–2000 mg/L to treat wool before dyeing with cochineal. We compared dye exhaustion, color depth, color characteristics, and color fastness of the new process with dyed pristine and metal mordanted wool. Results show that wool pretreatment improved dye exhaustion from 48 to 88 %, shifted saturation point toward lower dye concentration from 3000 to 1000 mg/L, and improved color depth from 13.68 for pristine wool and 15.17 for metal mordanted wool to 23.89 for the new process. 相似文献
67.
International environmental agreements (IEAs) can coordinate abatement of transboundary pollutants. This paper investigates
how heterogeneous countries facing a stock pollutant might structure such an agreement. In particular, we examine how an IEA
might be implemented with a set of monetary transfers. The focus is on transfers that are time invariant, linear in emissions,
and consistent with budget balance. There is a range of such schemes that would induce efficient emissions. We provide a simple
and intuitive characterization of these penalties and describe how specific proposals might be chosen in order to facilitate
compliance and implementation. Our proposals are illustrated with a simple example. We show that heterogeneity reduces the
scope for penalty schemes to jointly satisfy desirable properties. 相似文献
68.
Adewuyi Adeolu O. Awodumi Olabanji B. 《Environmental science and pollution research international》2021,28(12):14434-14468
Environmental Science and Pollution Research - Simultaneous achievement of sustainable development goals (SDGs), especially energy efficiency (SDG 7), economic growth (SDG 8), and pollution... 相似文献
69.
Christopher D. Pull William O. H. Hughes Mark J. F. Brown 《Die Naturwissenschaften》2013,100(12):1125-1136
Pathogens exert a strong selection pressure on organisms to evolve effective immune defences. In addition to individual immunity, social organisms can act cooperatively to produce collective defences. In many ant species, queens have the option to found a colony alone or in groups with other, often unrelated, conspecifics. These associations are transient, usually lasting only as long as each queen benefits from the presence of others. In fact, once the first workers emerge, queens fight to the death for dominance. One potential advantage of co-founding may be that queens benefit from collective disease defences, such as mutual grooming, that act against common soil pathogens. We test this hypothesis by exposing single and co-founding queens to a fungal parasite, in order to assess whether queens in co-founding associations have improved survival. Surprisingly, co-foundresses exposed to the entomopathogenic fungus Metarhizium did not engage in cooperative disease defences, and consequently, we find no direct benefit of multiple queens on survival. However, an indirect benefit was observed, with parasite-exposed queens producing more brood when they co-founded, than when they were alone. We suggest this is due to a trade-off between reproduction and immunity. Additionally, we report an extraordinary ability of the queens to tolerate an infection for long periods after parasite exposure. Our study suggests that there are no social immunity benefits for co-founding ant queens, but that in parasite-rich environments, the presence of additional queens may nevertheless improve the chances of colony founding success. 相似文献
70.
Ghostin J Habib-Jiwan JL Rozenberg R Daloze D Pasteels JM Braekman JC 《Die Naturwissenschaften》2007,94(7):601-605
The adults of the leaf beetle Platyphora kollari (Chrysomelidae) are able to metabolise the oleanane triterpene β-amyrin (1) into the glycoside 3-O-β-d-glucopyranosyl-(1→4)-β-d-glucuronopyranosyl-hederagenin (2) that is stored in their defensive glands. The aim of this study was to test the hypothesis that oleanolic acid (3) is an intermediate in the conversion of 1 into 2 and to check whether the sequestration of pentacyclic triterpenes is selective in favour of β-amyrin (1). To this end, adults of P. kollari were fed with Ipomoea batatas leaf disks painted with a solution of [2,2,3-2H3]oleanolic acid or [2,2,3-2H3]α-amyrin and the secretion of their defensive glands analysed by HPLC–ESIMS. The data presented in this work indicated that
the first step of the transformation of β-amyrin (1) into the sequestered glycoside 2 is its oxidation into oleanolic acid (3) and that this conversion is selective but not specific in favour of β-amyrin (1). 相似文献