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981.
Craig A. Evans Kevin S. McLeary George P. Partridge Richard S. Huebner 《Journal of the American Water Resources Association》2004,40(2):409-417
ABSTRACT: Computer programs that model the fate and transport of organic contaminants through porous media typically use Fick's first law to calculate vapor phase diffusion. Fick's first law, however, is limited to the case of a single, dilute species diffusing into a stagnant, high concentration, bulk vapor phase. When dealing with more than one diffusing species and at higher concentrations, the multicomponent coupling effects on vapor phase diffusion and advection of the various constituents become significant. VLEACH, a one‐dimensional finite difference model developed for the U.S. Environmental Protection Agency (USEPA), is typical of the models using Fick's first law to model vapor‐phase diffusion. The VLEACH model was modified to accommodate up to 10 components and to calculate the binary diffusion coefficients for each of the components based on molecular weight, molecular volume, temperature and pressure, and to address the coupling effects on multiple component vapor phase diffusion and its impact on ground water. The resulting model was renamed MC‐CHEMSOIL. At low vapor phase concentrations, MC‐CHEMSOIL predicts identical ground water impacts (dissolved phase loading) to those from VLEACH 2.2a. At higher vapor phase concentrations, however, the relative difference between the models exceeded 20 percent. 相似文献
982.
Brent J. Dalzell Prasanna H. Gowda David J. Mulla 《Journal of the American Water Resources Association》2004,40(2):533-543
ABSTRACT: This paper studies the effectiveness of alternative farm management strategies at improving water quality to meet Total Maximum Daily Loads (TMDLs) in agricultural watersheds. A spatial process model was calibrated using monthly flow, sediment, and phosphorus (P) losses (1994 to 1996) from Sand Creek watershed in south‐central Minnesota. Statistical evaluation of predicted and observed data gave r2 coefficients of 0.75, 0.69, and 0.49 for flow (average 4.1 m3/s), sediment load (average 0.44 ton/ha), and phosphorus load (average 0.97 kg/ha), respectively. The calibrated model was used to evaluate the effects of conservation tillage, conversion of crop land to pasture, and changes in phosphorus fertilizer application rate on pollutant loads. TMDLs were developed for sediment and P losses based on existing water quality standards and guidelines. Observed annual sediment and P losses exceeded these TMDLs by 59 percent and 83 percent, respectively. A combination of increased conservation tillage, reduced application rates of phosphorus fertilizer, and conversion of crop land to pasture could reduce sediment and phosphorus loads by 23 percent and 20 percent of existing loads, respectively. These reductions are much less than needed to meet TMDLs, suggesting that control of sediment using buffer strips and control of point sources of phosphorus are needed for the remaining reductions. 相似文献
983.
984.
We draw on the economic, corporate governance, and family business literatures to explain why the effects of family on family firms makes this governance form theoretically distinct from those of public and private non‐family firms. Our thesis is that parental altruism, when combined with private ownership and owner‐management, influences the ability of the firm's owner‐manager to exercise self‐control, which, in turn, can expose some family firms to conflicts rooted in the agency threats of moral hazard, hold‐up, and adverse selection. We then discuss why some other family firms are able to minimize these dark side threats and thereby attain altruism's brighter side. Finally, we discuss how altruism's influence changes over time as ownership becomes dispersed among family members and across generations. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
985.
B. Y. Aminuddin M. H. Ghulam W. Y. Wan Abdullah M. Zulkefli R. B. Salama 《Water, Air, & Soil Pollution: Focus》2005,5(1-2):89-101
Cameron Highlands is a mountainous region with steep slopes. Gradients exceeding 20∘ are common. The climate is favourable to the cultivation of tea, sub-tropical vegetables and flowers (under rain-shelter).
Crop production is sustained by high fertiliser and manure applications. However, agriculture in this environment is characterised
by high levels of soil erosion and environmental pollution. A study on the sustainability of these agro-ecosystems was conducted.
Results indicated that soil loss was in the range of 24–42 ton/ha/yr under vegetables and 1.3 ton under rain-shelter. Sediment
load in the vegetable sub-catchment reached 3.5 g/L, 50 times higher than that associated with flowers under rain-shelter
and tea. The sediments contained high nutrient loads of up to 470 kg N/ha/yr. The N, P and K lost in runoff from cabbage farms
was 154 kg/season/ha, whereas in chrysanthemum farms it was 5 kg. In cabbage farms, the N, P, and K lost through leaching
was 193 kg/season/ha. The NO3–N concentration in the runoff from the cabbage farms reached 25 ppm but less than 10 ppm in runoff from rain-shelters. Inorganic
pollution in the rivers was within the acceptable limit of 10 ppm. The sustainability of the agro-ecosystems is in the order
of tea { > } rain–shelter ≫ vegetables. 相似文献
986.
P. Hill C. Marshall H. Harmens D. L. Jones J. Farrar 《Water, Air, & Soil Pollution: Focus》2005,4(6):177-186
Soil respiration is a large C flux which is of primary importance in determining C sequestration. Here we ask how it is altered by atmospheric CO2 concentration and N additions. Swards of Lolium perenne L. were grown in a Eutric cambisol under controlled conditions with and without the addition of 200 kg NO? 3 ?N ha?1, at either 350 ppm or 700 ppm CO2, for 3 months. Soil respiration and net canopy photosynthesis were both increased by added N and elevated CO2, but soil respiration increased proportionately less than fixation by photosynthesis. Thus, both elevated CO2 and N appeared to increase potential C sequestration, although adding N at elevated CO2 reduced the C sequestered as a proportion of that fixed relative to elevated CO2 alone. Across all treatments below-ground respiratory C losses were predicted by root biomass, but not by soil solution C and N concentrations. Specific root-dependent respiration was increased by elevated CO2, such that below-ground respiration per unit biomass and per unit plant N was increased. 相似文献
987.
R. Skinner P. Ineson W. K. Hicks H. E. Jones D. Sleep I. D. Leith L. J. Sheppard 《Water, Air, & Soil Pollution: Focus》2005,4(6):219-228
A field ammonia (NH3) release experiment and open top chambers containing moorland monoliths continuously fumigated with NH3 or sprayed with NH4Cl were used to assess the potential for using δ15N values in determining the area of influence around a point NH3 emission source. δ15N values are being increasingly used as environmental tracers and we tested the hypothesis that the δ15N signal from an NH3 emission source is observable in nearby vegetation. Using modified monitoring devices, atmospheric NH3 concentrations were found to decrease with distance from source, with δ15N values also reflecting this trend, producing a signal shift with changing concentration. Open top chamber studies of δ15N values of Calluna vulgaris (L.) Hull indicated a correlation with deposition treatments in current year shoots. Analysis of Calluna shoots from the NH3 release showed a similar trend of δ15N enrichment. Significant linear correlations between δ15N and percent N in plant material were found, both in the controlled conditions of the open top chambers and at the NH3 release site, illustrating the possible use of this technique in N deposition biomonitoring. 相似文献
988.
The government of Canada ratified the Kyoto Protocol on 17 December 2002, but over 100 Canadian municipalities had joined the International Council for Local Environmental Intitatives' (ICLEI) Cities for Climate Protection (CCP) campaign up to a decade earlier. A low-cost home energy rating system (HERS) evaluation and individualized energy plan was provided to 420 households in Kitchener, Ontario, from September 2000 to August 2001. To assess the impact of the energy efficiency program, natural gas consumption in the year prior to the evaluation was compared with that in the year following. Overall, a 5% reduction was achieved, but individual responses varied widely. Situational and psychological factors were evaluated for three groups of households: the conservers, the consumers and the steady middle group. Conservers (30% of households) had higher initial energy consumption levels and achieved two-thirds of the potential savings identified by the energy evaluation. Consumers (12% of households) had higher ownership rates of high-efficiency furnaces and water heaters and demonstrated the rebound effect of increased demand for energy services following the evaluation. Low-income groups were the most likely to behave as conservers (42%) while high-income groups were the least likely to be conservers (13%) and the most likely to be consumers. Local programs need to be inclusive of all income groups to increase participation and implementation rates by systematically reducing barriers (financial, knowledge, trust) or increasing incentives (financial, regulatory or social) if the desired goal (e.g. Kyoto target) is to be achieved. 相似文献
989.
Maie Bachmann Maksim Säkki Jaan Kalda Jaanus Lass Viiu Tuulik Hiie Hinrikus 《The Environmentalist》2005,25(2-4):165-171
Summary This study focuses on discrimination of changes, produced by low-level microwave exposure in intensity and time variability
of the human EEG at rest. The power spectral density (PSD) method and nonlinear scaling analysis of the length distribution
of low variability periods (LDLVP) were selected for analysis of the EEG signal. During the study, 19 healthy volunteers were
exposed to a microwave (450 MHz) of 217 Hz frequency on-off modulation. The field power density at the scalp was 0.16 mW/cm2. The experimental protocol consisted of ten cycles of repetitive microwave exposure. Signals from frontal, temporal, parietal
and occipital EEG channels on EEG theta, alpha and beta rhythms were analysed. Exposure to microwave causes average increase
of EEG activity. LDLVP analysis discriminated significant effect in time variability for 2 subjects (11%). PSD method detected
significant changes in intensity for 4 subjects (21%). The effect of low-level microwave exposure is stronger on EEG beta
rhythm in temporal and parietal regions of the human brain. 相似文献
990.
A. Wieraszko Z. Ahmed J. Armani N. Maqsood S. Philips H. Raja 《The Environmentalist》2005,25(2-4):145-155
Summary The influence of pulsed magnetic fields (PMF) on the properties of nervous tissue was investigated. Hippocampal slices or
synaptosomes obtained from hippocampal tissue were used as model systems. The amplitude of potentials recorded in vitro from one of the hippocampal pathways (Schaffer collaterals that use glutamate as a neurotransmitter) was employed as a measure
of the influence of magnetic fields on synaptic efficiency. The synaptic glutamate turnover and radioactive calcium accumulation
were used as markers of the PMF influence on biochemistry of synaptic mechanisms. The exposure of hippocampal slices for 30
min to PMF amplified evoked potentials. While the frequency of 0.16 Hz exerted the strongest effect, lower (0.01, 0.07, 0.03
Hz) and higher (0.5 Hz) frequencies were much less effective. The enhancement of the neuronal excitability was correlated
with significant increase in the neuronal spontaneous activity mediated by electrical synapses. The PMF-induced changes in
the excitability of the tissue were accompanied by an increase in the synaptic turnover of glutamate. The release of radioactive
D-Aspartate (a glutamate analog used as a marker for glutamate turnover) from the slices, and its uptake by synaptosomes were
enhanced, and reduced respectively, following the stimulation with pulsed magnetic fields. The frequency which was the most
efficient in amplification of evoked potentials (0.16 Hz) was also the most effective in the modulation of the release and
uptake processes. The PMF-induced changes in neurotransmitter turnover coincided with an increase in 45Ca2+ accumulation observed in hippocampal slices exposed to PMF. 相似文献