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751.
752.
Jiade Wang Binxun Hong Xinyang Tong Shufeng Qiu 《Journal of the Air & Waste Management Association (1995)》2016,66(12):1268-1275
The process of recovering waste sulfuric acids using H2O2 catalytic oxidation is studied in this paper. Activated carbon was used as catalyst. Main operating parameters, such as temperature, feed rate of H2O2, and catalyst dosage, have effects on the removal of impurities from waste sulfuric acids. The reaction kinetics of H2O2 catalytic oxidation on impurities are discussed. At a temperature of 90°C, H2O2 feeding rate of 50 g (kg waste acid)?1 per hour, and catalyst dosage of 0.2 wt% (waste acid weight), the removal efficiencies of COD and chrominance were both more than 99%, the recovery ratio of sulfuric acid was more than 95%, and the utilization ratio of H2O2 was 88.57%.Implications: Waste sulfuric acid is a big environmental problem in China. The amount of waste sulfuric acid is huge every year. Many small and medium-sized businesses produced lots of waste acids, but they don’t have an appropriate method to treat and recover them. H2O2 catalytic oxidation has been used to treat and recover waste sulfuric acid and activated carbon is the catalyst here. Main parameters, such as temperature, feed rate of H2O2, and catalyst dosage, have been investigated. The reaction kinetics are discussed. This method can be economical and feasible for most small and medium-sized businesses. 相似文献
753.
Nguyen Kim Nga Huynh Dang Chinh Phi Thi Thuy Hong Tran Quang Huy 《Journal of Polymers and the Environment》2017,25(2):146-155
This study aimed at finding effective strategies for high-performance removal of reactive blue 19 (RB19) dye from aqueous solution. Chitosan (CS) films had been prepared by using solvent casting with mild drying for this purpose. The CS films were characterized by X-ray diffraction, field-emission scanning electron microscopy, and Fourier transform infrared (FTIR) spectroscopy. The performance of RB19 removal using CS were evaluated by varying contact time, solution pH, initial dye concentration, and adsorbent dosage. Adsorption isotherms, kinetics, and desorption were investigated by batch experiments. Results showed that CS films exhibited the optimal adsorption performance for RB19 removal and high maximum adsorption capacities of RB19, which were 799 and 822.4 mg g?1 at 20 and 40 °C, respectively. Adsorption kinetic data were well described by the pseudo-second-order kinetic model. FTIR analyses further indicated that interactions between RB19 and the CS film occurred during adsorption. The CS films also exhibited satisfactory desorption of RB19 at about 80 % after 30 min of desorption at pH 11. Our study demonstrated that the CS films can be easily prepared and applied for effective removal of RB19 in treatment of wastewater. 相似文献
754.
Tao Zhang Yaqun He Fangfang Wang Linhan Ge Xiangnan Zhu Hong Li 《Waste management (New York, N.Y.)》2014,34(6):1051-1058
Mineral processing operation is a critical step in any recycling process to realize liberation, separation and concentration of the target parts. Developing effective recycling methods to recover all the valuable parts from spent lithium-ion batteries is in great necessity. The aim of this study is to carefully undertake chemical and process mineralogical characterizations of spent lithium-ion batteries by coupling several analytical techniques to provide basic information for the researches on effective mechanical crushing and separation methods in recycling process. The results show that the grade of Co, Cu and Al is fairly high in spent lithium ion batteries and up to 17.62 wt.%, 7.17 wt.% and 21.60 wt.%. Spent lithium-ion batteries have good selective crushing property, the crushed products could be divided into three parts, they are Al-enriched fraction (+2 mm), Cu and Al-enriched fraction (?2 + 0.25 mm) and Co and graphite-enriched fraction (?0.25 mm). The mineral phase and chemical state analysis reveal the electrode materials recovered from ?0.25 mm size fraction keep the original crystal forms and chemical states in lithium-ion batteries, but the surface of the powders has been coated by a certain kind of hydrocarbon. Based on these results a flowsheet to recycle spent LiBs is proposed. 相似文献
755.
海岛是海洋生态系统的重要组成部分,保护海岛生态环境是推进海洋生态文明建设、保护海洋生态环境的重要方面。海岛居民是保护海岛生态环境的主体之一,研究海岛居民环境友好行为的影响因素,引导和鼓励海岛居民主动采取环境友好行为是改善海岛生态环境的有效途径。本研究在梳理国内外相关文献的基础上,对海岛居民环境友好行为的概念、类型及影响因素进行理论分析,建立包含生态管理行为、消费行为、说服行为、公民行为四个环境友好行为变量,环境态度、环境保护知识、环境经历、社会政策、行为约束五个影响因素变量在内的理论模型。结合海岛生态环境和海岛居民的特点,设计海岛居民版环境友好行为测量量表,并在长岛县进行问卷调查,运用描述性统计分析、结构方程模型分析探究海岛居民环境友好行为的影响因素及影响因素间的内在关系。研究发现:①海岛居民环境友好行为总体水平差异较大,难度较低的环境友好行为实施较好,而难度较高的实施较差;影响因素变量中,环境态度积极,环境经历丰富,环境保护知识掌握较好,相关社会政策较为不利,行为约束偏中性。②环境态度、环境经历、社会政策对海岛居民环境友好行为具有显著正向影响。③环境保护知识对环境态度具有显著正向影响,但对海岛居民环境友好行为无显著影响,存在“知易行难”现象。行为约束对海岛居民环境友好行为无显著影响。④环境经历不仅直接影响海岛居民环境友好行为,而且通过环境态度对海岛居民环境友好行为施加间接影响。基于研究结论,提出了改善海岛居民环境友好行为的对策建议。 相似文献
756.
CO2浓度升高对半干旱区春小麦光合作用及水分生理生态特性的影响 总被引:2,自引:0,他引:2
大气CO2浓度升高已成为世界范围内重要环境问题。为了解大气CO2浓度升高对春小麦光合作用及水分生理生态特性的影响,在典型半干旱区定西利用开顶式气室(OTC)试验平台,以春小麦“定西24号”为供试品种,开展了CO2浓度增加模拟试验。试验设对照(390μmol·mol?1)、480μmol·mol?1和570μmol·mol?1等3个CO2浓度(摩尔分数)梯度。结果表明:在对照和增加CO2浓度条件下,春小麦叶片净光合速率和蒸腾速率日变化均呈“双峰型”分布,出现明显的“午休”现象;胞间CO2浓度的日变化表现为斜“V”字型曲线;叶水势日变化呈现反抛物线曲线走向,在中午后出现水势曲线拐点。在不同生育时期内,净光合速率、气孔导度和胞间CO2浓度均表现为开花期最大,乳熟期最小。而蒸腾速率表现为开花期最大,拔节期最小,叶片水平水分利用效率表现为孕穗期最大,乳熟期最小。随着CO2浓度升高,春小麦叶片净光合速率、胞间CO2浓度、水分利用效率和水势提高,气孔导度和蒸腾速率降低。与对照大气CO2浓度相比,在480μmol·mol?1浓度和570μmol·mol?1浓度下,整个生育期净光合速率平均分别提高了14.68%和28.20%,气孔导度平均降低了15.29%和24.83%,胞间CO2浓度平均提高了10.38%和26.15%,蒸腾速率平均减小了6.63%和12.41%,WUE平均增加了22.9%和46.9%。随着CO2浓度升高,蒸腾失水减少,叶片水势不断增加,从而增强了春小麦对干旱胁迫的抵御能力。研究结果为我国半干旱区春小麦对全球气候变化下的敏感性及适应性提供理论参考。 相似文献
757.
Pham Huong Giang Harada Hidenori Fujii Shigeo Nguyen Pham Hong Lien Huynh Trung Hai 《Journal of Material Cycles and Waste Management》2017,19(2):827-839
Journal of Material Cycles and Waste Management - Human and livestock waste, i.e., excreta, were intensively used in crop cultivation in Asia over the years. However, rapid economic growth induced... 相似文献
758.
Liang Lu Yuqi Jin Hongmei Liu Xiaojun Ma Kunio Yoshikawa 《Waste management (New York, N.Y.)》2014,34(1):79-85
Nitrogen evolution was studied during the co-combustion of hydrothermally treated municipal solid wastes (HT MSW) and coal in a bubbling fluidized bed (BFB). HT MSW blending ratios as 10%, 20% and 30% (wt.%) were selected and tested at 700, 800, 900 °C. Emissions of NO and N2O from blends were measured and compared with the results of mono-combustion trials. Moreover, concentrations of precursors like NH3 and HCN were also quantified. The results are summarized as follows: NO emissions were predominant in all the cases, which rose with increasing temperature. The blending of HT MSW contributed to the NO reduction. N2O emissions decreased with temperature rising and the blending of HT MSW also presented positive effects. At 30% HT MSW addition, both NO and N2O emissions showed the lowest values (391.85 ppm and 55.33 ppm, respectively at 900 °C). For the precursors, more HCN was detected than NH3 and both played important roles on the gas side nitrogen evolution. 相似文献
759.
高层建筑竖井火灾中影响因素众多,并且各因素对高层楼梯井火灾中重要现象、关键数值等的影响大小不一,使得此类火灾中的实验或理论研究成本较高。通过建立全局敏感性分析平台,定量考察了高层楼梯井结构所涉及因素的影响大小,并能够方便地筛选掉对所考察量影响较小的因素,以降低实验或计算成本。使用数值模拟方法,通过CFD软件对包含阶梯几何框架的高层楼梯井结构火灾进行了共计60次工况计算。并且根据计算结果,使用全局参数敏感性分析方法,得出建筑尺寸、热释放速率、环境参数对高层楼梯井内烟气湍流特性及输运特性的敏感性排序。结果表明,火源热释放速率对各输出参数的影响均占38%以上。 相似文献
760.
Chukwujindu M. A. Iwegbue Godwin E. Nwajei Jude E. Ogala Chukwudumebi L. Overah 《Environmental geochemistry and health》2010,32(5):415-430
The concentrations of trace metals (Cd, Pb, Cu, Cr, Fe, Ni, Zn and Co) were studied in soil profiles of eight municipal waste
dump sites in Warri metropolis. The results indicate that concentrations of trace metals varied widely among the different
dumpsites and decreased with depths in a studied soil profile. The accumulation pattern for the heavy metals in the soil profiles
follows the order: Fe > Pb > Mn > Co > Cr > Zn > Ni > Cu > Cd. The concentrations of metals found in these sites was below
the Canadian remediation criteria for land for agricultural, residential and commercial/industrial purposes except for the
cadmium levels in some sites that exceeded criterion values for agricultural and residential. In such sites, remedial actions
are required before any form of chosen development can take place. The levels of heavy metals found in these dump sites were
higher than that of the control site. The examined metals showed no significant correlation with soil physicochemical properties
at the surface horizon, which is suggestive evidence that these metals arise from anthropogenic input. 相似文献