Ozone Air Quality over North America: Part I—A Review of Reported Trends

ABSTRACT

Ozone and precursor trends can be used to measure the effectiveness of regulatory programs that have been implemented. In this paper, we review trends in the concentrations of O₃, NO_x, and HCs over North America that have been reported in the literature. Although most existing trend studies are confounded by meteorological variability, both the raw data trends and the trends adjusted for meteorology collectively indicate a general decreasing trend in O concentrations in most areas of the United States during 1985-1996. In Canada, mean daily maximum 1-hr O₃ concentrations at urban sites show mixed trends with a majority of sites showing an increase from 1980 to 1993. Mean daily maximum 1-hr O₃ at most regionally representative Canadian sites appears to decrease from 1985 to 1993 or shows no significant change. There are far fewer data and analyses of NO_x and HC trends. Available studies covering various ranges of years indicate decreases in ambient NO_x and HC concentrations in Los Angeles, CA, decreases in HC concentrations in northeastern U.S. cities, and decreases in NO concentrations in Canadian cities. Two key needs are long-term HC and NO_x measurements, particularly at rural sites, and a systematic comparison of trend detection techniques on a reference data set.     

电解锰渣的综合利用进展与研究展望

电解锰渣是电解金属锰时产生的酸性滤渣,含有大量有害物质。随着电解锰行业的快速发展,大量堆放填埋的电解锰渣引发了严重的水土、生态环境污染问题,对锰渣的无害化处理与资源化利用已成为电解锰行业和环保领域的研究热点。在电解锰渣特性的分析基础上,对国内外电解锰渣的综合利用进展(如锰离子回收、肥料制作和建筑材料应用)进行了回顾,分析了锰渣各种资源化利用方法的优缺点。最后,展望了电解锰渣的研究与应用前景,旨在为锰矿资源的可持续性开发与电解锰渣的综合回收利用提供参考。     

Allometric models for the estimation of above- and below-ground biomass of Jatropha curcas L. in semi-arid regions of Southern India

Jatropha curcas L. (Jatropha) is an important multipurpose tree valued for oil. In India, plans are underway to bring substantial area under this crop for meeting the biofuel requirements of the country. A study was conducted to develop allometric relationships in Jatropha to predict various biomass-related components (above ground and below ground) using easily measurable attributes, viz. collar diameter, tree height, number of branches, crown diameter, and crown depth. Further, it was aimed to establish the reliability of these relationships using an independent dataset obtained from varied management situations. Destructive sampling was carried out during the rainy season of 2011, when Jatropha plants were eight years old. Highly significant allometric relationships (F-values significant at 1% level) were obtained while predicting various biomass components (above, below, and total) using easily measurable attributes with R² values ranging from 0.89 to 0.98. Of all the predictors, collar diameter exhibited a highly significant relationship with total dry biomass per plant (R² = 0.97). The allometric relationships developed were validated with an independent dataset. The allometric relationships developed would serve as valuable tools for estimating total dry biomass production and carbon sequestration with reasonable accuracy in Jatropha systems, as they are proposed to be taken up in substantial area in the years to come.     

LivestockPlus: Forages,sustainable intensification,and food security in the tropics

The increased use of grain-based feed for livestock during the last two decades has contributed, along with other factors, to a rise in grain prices that has reduced human food security. This circumstance argues for feeding more forages to livestock, particularly in the tropics where many livestock are reared on small farms. Efforts to accomplish this end, referred to as the ‘LivestockPlus’ approach, intensify in sustainable ways the management of grasses, shrubs, trees, and animals. By decoupling the human food and livestock feed systems, these efforts would increase the resilience of the global food system. Effective LivestockPlus approaches take one of two forms: (1) simple improvements such as new forage varieties and animal management practices that spread from farmer to farmer by word of mouth, or (2) complex sets of new practices that integrate forage production more closely into farms’ other agricultural activities and agro-ecologies.     

Fate and transport of fragrance materials in principal environmental sinks

Fragrance materials are widely present in the environment, such as air, water, and soil. Concerns have been raised due to the increasing utilization and suspected impact on human health. The bioaccumulating property is considered as one of the causes of the toxicity to human beings. The removal of fragrance materials from environmental sinks has not been paid enough attention due to the lack of regulation and research on their toxicity. This paper provides systematic information on how fragrance materials are transferred to the environment, how do they affect human lives, and what is their fate in water, wastewater, wastewater sludge, and soil.     

Decadal time-scale monitoring of forest fires in Similipal Biosphere Reserve,India using remote sensing and GIS

Analyzing the spatial extent and distribution of forest fires is essential for sustainable forest resource management. There is no comprehensive data existing on forest fires on a regular basis in Biosphere Reserves of India. The present work have been carried out to locate and estimate the spatial extent of forest burnt areas using Resourcesat-1 data and fire frequency covering decadal fire events (2004–2013) in Similipal Biosphere Reserve. The anomalous quantity of forest burnt area was recorded during 2009 as 1,014.7 km². There was inconsistency in the fire susceptibility across the different vegetation types. The spatial analysis of burnt area shows that an area of 34.2 % of dry deciduous forests, followed by tree savannah, shrub savannah, and grasslands affected by fires in 2013. The analysis based on decadal time scale satellite data reveals that an area of 2,175.9 km² (59.6 % of total vegetation cover) has been affected by varied rate of frequency of forest fires. Fire density pattern indicates low count of burnt area patches in 2013 estimated at 1,017 and high count at 1,916 in 2004. An estimate of fire risk area over a decade identifies 12.2 km² is experiencing an annual fire damage. Summing the fire frequency data across the grids (each 1 km²) indicates 1,211 (26 %) grids are having very high disturbance regimes due to repeated fires in all the 10 years, followed by 711 grids in 9 years and 418 in 8 years and 382 in 7 years. The spatial database offers excellent opportunities to understand the ecological impact of fires on biodiversity and is helpful in formulating conservation action plans.     

Methane oxidation and abundance of methane oxidizers in tropical agricultural soil (vertisol) in response to CuO and ZnO nanoparticles contamination

There is worldwide concern over the increase use of nanoparticles (NPs) and their ecotoxicological effect. It is not known if the annual production of tons of industrial nanoparticles (NPs) has the potential to impact terrestrial microbial communities, which are so necessary for ecosystem functioning. Here, we have examined the consequences of adding the NPs particularly the metal oxide (CuO, ZnO) on CH₄ oxidation activity in vertisol and the abundance of heterotrophs, methane oxidizers, and ammonium oxidizers. Soil samples collected from the agricultural field located at Madhya Pradesh, India, were incubated with either CuO and ZnO NPs or ionic heavy metals (CuCl₂, ZnCl₂) separately at 0, 10, and 20 μg g^?1 soil. CH₄ oxidation activity in the soil samples was estimated at 60 and 100 % moisture holding capacity (MHC) in order to link soil moisture regime with impact of NPs. NPs amended to soil were highly toxic for the microbial-mediated CH₄ oxidation, compared with the ionic form. The trend of inhibition was Zn 20?>?Zn 10?>?Cu 20?>?Cu 10. NPs delayed the lag phase of CH₄ oxidation to a maximum of 4-fold and also decreased the apparent rate constant k up to 50 % over control. ANOVA and Pearson correlation analysis (α?=?0.01) revealed significant impact of NPs on the CH₄ oxidation activity and microbial abundance (p?<?0.0001, and high F statistics). Principal component analysis (PCA) revealed that PC1 (metal concentration) rendered 76.06 % of the total variance, while 18.17 % of variance accounted by second component (MHC). Biplot indicated negative impact of NPs on CH₄ oxidation and microbial abundance. Our result also confirmed that higher soil moisture regime alleviates toxicity of NPs and opens new avenues of research to manage ecotoxicity and environmental hazard of NPs.     

Spatial and temporal estimation of soil loss for the sustainable management of a wet semi-arid watershed cluster

The ungauged wet semi-arid watershed cluster, Seethagondi, lies in the Adilabad district of Telangana in India and is prone to severe erosion and water scarcity. The runoff and soil loss data at watershed, catchment, and field level are necessary for planning soil and water conservation interventions. In this study, an attempt was made to develop a spatial soil loss estimation model for Seethagondi cluster using RUSLE coupled with ARCGIS and was used to estimate the soil loss spatially and temporally. The daily rainfall data of Aphrodite for the period from 1951 to 2007 was used, and the annual rainfall varied from 508 to 1351 mm with a mean annual rainfall of 950 mm and a mean erosivity of 6789 MJ mm ha^?1 h^?1 year^?1. Considerable variation in land use land cover especially in crop land and fallow land was observed during normal and drought years, and corresponding variation in the erosivity, C factor, and soil loss was also noted. The mean value of C factor derived from NDVI for crop land was 0.42 and 0.22 in normal year and drought years, respectively. The topography is undulating and major portion of the cluster has slope less than 10°, and 85.3 % of the cluster has soil loss below 20 t ha^?1 year^?1. The soil loss from crop land varied from 2.9 to 3.6 t ha^?1 year^?1 in low rainfall years to 31.8 to 34.7 t ha^?1 year^?1 in high rainfall years with a mean annual soil loss of 12.2 t ha^?1 year^?1. The soil loss from crop land was higher in the month of August with an annual soil loss of 13.1 and 2.9 t ha^?1 year^?1 in normal and drought year, respectively. Based on the soil loss in a normal year, the interventions recommended for 85.3 % of area of the watershed includes agronomic measures such as contour cultivation, graded bunds, strip cropping, mixed cropping, crop rotations, mulching, summer plowing, vegetative bunds, agri-horticultural system, and management practices such as broad bed furrow, raised sunken beds, and harvesting available water using farm ponds and percolation tanks. This methodology can be adopted for estimating the soil loss from similar ungauged watersheds with deficient data and for planning suitable soil and water conservation interventions for the sustainable management of the watersheds.     

Integrated hydrochemical and geophysical studies for assessment of groundwater pollution in basaltic settings in Central India

The Pithampur Industrial sectors I, II, and III, located approximately, 45 km from Indore in Central India have emerged as one of the largest industrial clusters in the region. Various types of industries ranging from automobiles to chemicals and pharmaceuticals have been set up in the region since 1990. Most of the industries have effluent treatment plants (ETP) for treating wastewater before its disposal on land and/or in water body. The present study is an attempt to assess the groundwater quality in the watersheds surrounding these industrial sectors to develop the baseline groundwater quality in order to enable the policy makers to facilitate decisions on the development of industries in this region. The industries are located in two sub-watersheds, namely, Gambhir river sub-watershed and Chambal river sub-watershed. Geologically, the study area is located in the Deccan traps of Cretaceous to Paleocene age. The different basaltic flow units underlie clayey soils varying in thickness from 2–3 m. The aquifer is mostly of unconfined nature. Samples have been collected from a network of observation wells set up in the watersheds. The water quality analysis of the groundwater samples has been carried out six times during three hydrological cycles of 2004, 2005, and 2006. The results indicate that a few observation wells in the vicinity of the industrial clusters have very high TDS concentration and exceed the Bureau of Indian Standards (BIS) guideline for TDS concentration. The contamination of groundwater has been more severe in the Gambhir watershed as compared to the Chambal watershed. The presence of the impermeable clay layers has resulted in a slow migration of contaminants from the sources. The findings reveal that there is no significant groundwater contamination in the Pithampur industrial sectors except in the vicinity of the industrial clusters, which indicates that there is good environmental space available for the expansion of industrial units in the Pithampur industrial hub.