The sensitivity of PM2.5 source-receptor relationships to atmospheric chemistry and transport in a three-dimensional air quality model

Air quality model simulations constitute an effective approach to developing source-receptor relationships (so-called transfer coefficients in the risk analysis framework) because a significant fraction of particulate matter (particularly PM2.5) is secondary (i.e., formed in the atmosphere) and, therefore, depends on the atmospheric chemistry of the airshed. In this study, we have used a comprehensive three-dimensional air quality model for PM2.5 (SAQM-AERO) to compare three approaches to generating episodic transfer coefficients for several source regions in the Los Angeles Basin. First, transfer coefficients were developed by conducting PM2.5 SAQM-AERO simulations with reduced emissions of one of four precursors (i.e., primary PM, sulfur dioxide (SO2), oxides of nitrogen (NOx), and volatile organic compounds) from each source region. Next, we calculated transfer coefficients using two other methods: (1) a simplified chemistry for PM2.5 formation, and (2) simplifying assumptions on transport using information limited to basin-wide emission reductions. Transfer coefficients obtained with the simplified chemistry were similar to those obtained with the comprehensive model for VOC emission changes but differed for NOx and SOz emission changes. The differences were due to the parameterization of the rates of secondary PM formation in the simplified chemistry. In 90% of the cases, transfer coefficients estimated using only basin-wide information were within a factor of two of those obtained with the explicit source-receptor simulations conducted with the comprehensive model. The best agreement was obtained for VOC emission changes; poor agreement was obtained for primary PM2.5.     

Geometric variability and surface finish of weld zones in Yb:YAG laser welded advanced high strength steels

Laser welding is used for joining advanced high strength steels (AHSS) to improve formability and performance. In this paper, the geometric variability observed in the fusion zones and heat affected zones of several combinations of AHSS (different types, coatings and thicknesses), which were butt welded using a Trumpf TRUDISK 6000^® Yb:YAG laser beam, is presented. The surface texture parameters such as roughness and waviness of laser welds were also measured and correlated with geometric variability. Results indicate that although high quality welds with minimal defects can be obtained using the Yb:YAG laser welding process, there is considerable variation in both the shape and the dimensions of weld zones. The variability increased with an increase in thickness differentials between the sheets being welded. Analysis of the top of the weld surfaces also suggested that aluminum coating on USIBOR samples contributes significantly to increased roughness. An increase in laser power coupled with corresponding increase in welding speed did not impact variability. A fair correlation between the surface roughness and weld region variability exists, although this needs further study.     

Identification and characterization of extracted microplastics from agricultural soil near industrial area: FTIR and X-ray diffraction method

Microplastics have been found in large quantities in agricultural soil and now become a major global issue. Different types of microplastic have adverse effects on agricultural soil. The most widely used method for the extraction of microplastics in agricultural soil is the density floatation method by using saturated NaCl solution. This method includes the pre-digestion of soil samples with H₂O₂ to remove all the organic matter present in the soil. Different types of microplastic particles were extracted and identified by using ATR-FTIR viz polypropylene, polybutylene tetrapthalate, polyethylene, polystyrene, and polyethylene tetrapthalate. The crystalline nature of extracted microplastic was checked by employing XRD analytical technique. Floatation with higher density saturated sodium chloride (NaCl) solution recovered approximately 80% MPs from soil. Floatation methods were found to be effective for extracting microplastics from soils.     

Interactions between lead(II) ions and dissolved organic matter derived from organic fertilizers incubated in the field

This work was to study composition characteristics and the subsequent effect on the lead (Pb) binding properties of dissolved organic matter (DOM) derived from seaweed-based (SWOF) and chicken manure organic fertilizers (CMOF) during a one-year field incubation experiment using the excitation-emission matrix-parallel factor (EEM-PARAFAC) and two-dimensional correlation spectroscopy (2DCOS) analysis. Results showed that high aromatic and hydrophobic fluorescent substances were enriched in CMOF-derived DOM and SWOF-derived DOM and enhanced over time. And phenolic groups in the fulvic-like substances for SWOF-derived DOM and carboxyl groups in the humic-like substances for CMOF-derived DOM had the fastest responses over time, respectively. Moreover, both non-fluorescent polysaccharides and fluorescent humic-like substances or fulvic-like substances with aromatic (C=C) groups first participated in the binding process of Pb to SWOF-derived DOM on day 0 and 180 during the lead binding process. In contrast, humic-like substances associated with aromatic (C=C) and phenolic groups gave a faster response to Pb binding on day 360. Regarding CMOF-derived DOM, the fulvic-like substances associated with aromatic (C=C) and carboxylic groups displayed a faster response to Pb ions on day 0. Nonetheless, polysaccharides and humic-like associated with phenolic groups had a faster response on days 180 and 360. It is noteworthy that the polysaccharides, which participated in Pb binding to CMOF-derived DOM, posed a higher risk of Pb in the environment after 360 days. Therefore, these findings gave new insights into the long-term applications of commercial organic fertilizers for the amendment of soil.     

Cell phone electromagnetic field radiations affect rhizogenesis through impairment of biochemical processes

Indiscriminate adoption and use of cell phone technology has tremendously increased the levels of electromagnetic field radiations (EMFr) in the natural environment. It has raised the concerns among the scientists regarding the possible risks of EMFr to living organisms. However, not much has been done to assess the damage caused to plants that are continuously exposed to EMFr present in the environment. The present study investigated the biochemical mechanism of interference of 900 MHz cell phone EMFr with root formation in mung bean (Vigna radiata syn. Phaseolus aureus) hypocotyls, a model system to study rhizogenesis in plants. Cell phone EMFr enhanced the activities of proteases (by 1.52 to 2.33 times), polyphenol oxidases (by 1.5 to 4.3 times), and peroxidases (by 1.5 to 2.0 times) in mung bean hypocotyls over control. Further, EMFr enhanced malondialdehyde (an indicator of lipid peroxidation), hydrogen peroxide, and proline content, indicating a reactive oxygen species-mediated oxidative damage in hypocotyls. It was confirmed by the upregulation in the activities of antioxidant enzymes (superoxide dismutase, ascorbate peroxidase, guaiacol peroxidase, catalase, and glutathione reductase) suggesting their possible role in providing protection against EMFr-induced oxidative damage. The study concluded that cell phone radiations affect the process of rhizogenesis through biochemical alterations that manifest as oxidative damage resulting in root impairment.     

Review of ozone and temperature lidar validations performed within the framework of the Network for the Detection of Stratospheric Change

The use of assimilation tools for satellite validation requires true estimates of the accuracy of the reference data. Since its inception, the Network for Detection of Stratospheric Change (NDSC) has provided systematic lidar measurements of ozone and temperature at several places around the world that are well adapted for satellite validations. Regular exercises have been organised to ensure the data quality at each individual site. These exercises can be separated into three categories: large scale intercomparisons using multiple instruments, including a mobile lidar; using satellite observations as a geographic transfer standards to compare measurements at different sites; and comparative investigations of the analysis software. NDSC is a research network, so each system has its own history, design, and analysis, and has participated differently in validation campaigns. There are still some technological differences that may explain different accuracies. However, the comparison campaigns performed over the last decade have always proved to be very helpful in improving the measurements. To date, more efforts have been devoted to characterising ozone measurements than to temperature observations. The synthesis of the published works shows that the network can potentially be considered as homogeneous within +/-2% between 20-35 km for ozone and +/-1 K between 35-60 km for temperature. Outside this altitude range, larger biases are reported and more efforts are required. In the lower stratosphere, Raman channels seem to improve comparisons but such capabilities were not systematically compared. At the top of the profiles, more investigations on analysis methodologies are still probably needed. SAGE II and GOMOS appear to be excellent tools for future ozone lidar validations but need to be better coordinated and take more advantage of assimilation tools. Also, temperature validations face major difficulties caused by atmospheric tides and therefore require intercomparisons with the mobile systems, at all sites.     

Synthesis of nanoparticles using microorganisms and their applications: a review

Environmental Chemistry Letters - Nanoparticles synthesis under green conditions has been performed using natural resources to diminish the use of toxic chemicals. For instance, microbial synthesis...     

Impact of river flow modification on wetland hydrological and morphological characters

A good number of researchers investigated the impact of flow modification on hydrological, ecological, and geomorphological conditions in a river. A few works also focused on hydrological modification on wetland with some parameters but as far the knowledge is concerned, linking river flow modification to wetland hydrological and morphological transformation following an integrated modeling approach is often lacking. The current study aimed to explore the degree of hydrological alteration in the river and its effect on downstream riparian wetlands by adopting advanced modeling approaches. After damming, maximally 67 to 95% hydrological alteration was recorded for maximum, minimum, and average discharges. Wavelet transformation analysis figured out a strong power spectrum after 2012 (damming year). Due to attenuation of flow, the active inundation area was reduced by 66.2%. After damming, 524.03 km² (48.9% of total pre-dam wetland) was completely obliterated. Hydrological strength (HS) modeling also reported areas under high HS declined by 14% after post-dam condition. Wetland hydrological security state (WSS) and HS matrix, a new approach, are used to explore wetland characteristics of inundation connectivity and hydrological security state. WSS was defined based on lateral hydrological connectivity. HS under critical and stress WWS zones deteriorated in the post-dam period. The morphological transformation was also well recognized showing an increase in area under the patch, edge, and a decrease in the area under the large core area. All these findings established a clear linkage between river flow modification and wetland transformation, and they provided a good clue for managing wetlands.

     

Assessment of phenol infiltration resilience in soil media by HYDRUS-1D transport model for a waste discharge site

The movement of contaminants through soil imparts a variety of geo-environmental problem inclusive of lithospheric pollution. Near-surface aquifers are often vulnerable to contamination from surface source if overlying soil possesses poor resilience or contaminant attenuation capacity. The prediction of contaminant transport through soil is urged to protect groundwater from sources of pollutants. Using field simulation through column experiments and mathematical modeling like HYDRUS-1D, assessment of soil resilience and movement of contaminants through the subsurface to reach aquifers can be predicted. An outfall site of effluents of a coke oven plant comprising of alarming concentration of phenol (4–12.2 mg/L) have been considered for studying groundwater condition and quality, in situ soil characterization, and effluent characterization. Hydrogeological feature suggests the presence of near-surface aquifers at the effluent discharge site. Analysis of groundwater of nearby locality reveals the phenol concentration (0.11–0.75 mg/L) exceeded the prescribed limit of WHO specification (0.002 mg/L). The in situ soil, used in column experiment, possess higher saturated hydraulic conductivity (K _S ?=?5.25?×?10^?4 cm/s). The soil containing 47 % silt, 11 % clay, and 1.54 % organic carbon content was found to be a poor absorber of phenol (24 mg/kg). The linear phenol adsorption isotherm model showed the best fit (R ²?=?0.977, RMSE?=?1.057) to the test results. Column experiments revealed that the phenol removal percent and the length of the mass transfer zone increased with increasing bed heights. The overall phenol adsorption efficiency was found to be 42–49 %. Breakthrough curves (BTCs) predicted by HYDRUS-1D model appears to be close fitting with the BTCs derived from the column experiments. The phenol BTC predicted by the HYDRUS-1D model for 1.2 m depth subsurface soil, i.e., up to the depth of groundwater in the study area, showed that the exhaustion point was reached within 12 days of elapsed time. This clearly demonstrated poor attenuation capacity of the soil to retard migration of phenol to the groundwater from the surface outfall site. Suitable liner, based on these data, may be designed to inhibit subsurface transport of phenol and thereby to protect precious groundwater from contamination.