Mass loading of nickel and uranium on plant surfaces: application of laser ablation-ICP-MS

Transport of contaminated sediments from a former radiological settling pond results in the deposition of U and Ni in the Lower Tims Branch (LTB)(Aiken, SC, USA). Uranium is unavailable for plant uptake, but elevated U and Ni concentrations associated with foliage of understory plants suggested mass loading. Mass loading of contaminated soil on Andropogon elliottii Chapman (Poaceae) was investigated using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The technique allows for rapid quantitative elemental depth profiling. Fresh washed and unwashed leaves (n= 5) from the contaminated area were compared with those from an uncontaminated area, analysing Ni and U at ten randomly chosen points on each leaf. Nickel and U concentrations differed significantly between washed and unwashed leaves from LTB. Particles on unwashed leaves measured up to 300 [micro sign]m in diameter, and were enriched with U. Uranium was detected on the surface of the leaf, whereas Ni was detected within leaf tissues. In unwashed LTB leaves, Ni and U concentrations did not significantly differ in areas with and without visible particles, suggesting that there were much smaller particles, indistinguishable at [times]100 magnification, which contributed to the overall metal burden. Washing removed the majority of the Ni and U on the surface, but residual U and Ni was detected. Irregularities in the leaf surface, such as scars from herbivory contained elevated U concentrations despite a washing step, presumably from trapping soil particles. Laser ablation ICP-MS revealed that mass loading makes a significant contribution to the contaminant burden of understory plants at LTB.     

Economic appraisal and evaluation of UK waste minimisation clubs: proposals to inform the design of sustainable clubs

Waste minimisation clubs have been established for some 12 years in the UK. During that time, they have been significant driving forces in disseminating sustainable waste management practices in industry and commerce. Clubs have also demonstrated that they can achieve significant reductions in levels of waste. However, data on the economic benefits of these clubs remain scanty and disparate. In addition, no standard methodology has developed to assess whether the investment costs of clubs can be justified on grounds of either economic welfare or sustainable development, despite the theoretical advantages from doing so. Against this background, the paper considers the need for economic appraisal and evaluation of waste minimisation clubs and discusses how these methods could be applied to the creation of clubs that will be sustainable over time.     

Solubility of antimony and other elements in samples taken from shooting ranges

The aim of this study was to determine whether or not Sb and other elements (Ni, Cu, Bi, Tl, and Hg) originating from Pb alloy (2-5 wt. % Sb) bullets become more soluble as a result of weathering and what mechanisms possibly control their solubility. Samples were taken from bank material behind the targets at seven Swiss shooting ranges. The samples were dried, sieved, analyzed, and subjected to leaching experiments. Total average concentrations of Sb ranged from 0.5 to 13.8 g kg(-1). In the leaching experiments, Sb was almost exclusively present in solution as the oxidized species Sb(V) in concentrations of up to 5 mg L(-1). The Ca mineral Ca[Sb(OH)6]2 is suggested to control dissolved Sb(V) concentrations in soils at high concentrations. Oxalate extractions suggested that approximately 50% of Sb [predominantly Sb(V)] in the <0.5-mm fraction was adsorbed to Fe (hydr)oxides and possibly other minerals, such as calcite, that are soluble at pH 2. However, it is possible that only a fraction of the oxalate-extractable Sb(V) is reversibly bound to mineral surfaces. It was concluded that the release of Sb is significant and considerably higher than the other elements under investigation and that the mechanisms controlling Sb mobility should be further investigated.     

MAPPING HYDROLOGIC UNITS FOR THE NATIONAL WATERSHED BOUNDARY DATASET1

ABSTRACT: In 2002, Wyoming became the first state to complete development of a statewide 1:24,000‐scale Watershed Boundary Dataset (WBD) under the new Federal Standards for Delineation of Hydrologic Unit Boundaries. The product was developed through the coordinated efforts of numerous state, federal, and local entities both within Wyoming and in neighboring states. Development of a comprehensive, standardized hydrologic unit boundary dataset in a “headwaters” state such as Wyoming poses a number of unique challenges. This paper details the WBD's development in Wyoming, highlighting technical methodology development and interagency coordination strategies. Evolution of the WBD standard is reviewed, addressing inconsistencies between definitions for hydro‐logic units and “true” watershed delineations. While automated methods are improving, manual and semi‐automated techniques continue to serve as valuable approaches to hydrologic unit boundary delineation given the quality of digital terrain models and the multijurisdictional nature of watershed based management. This case study provides insight on future development and maintenance of the WBD within and across other states and regions of the country and on opportunities for linking the WBD to related water resource geospatial data products like the National Hydrography Dataset.     

The alcohol interlock: an underutilized resource for predicting and controlling drunk drivers

This report summarizes evidence presented during the Third Annual Ignition Interlock Symposium at Vero Beach, Florida, 29 October 2002. The ignition interlock prevents a car from starting when blood alcohol concentration (BAC) is elevated. We review some of our prior work as well as introduce previously unpublished results to demonstrate the manner in which the data recorded by the alcohol ignition interlock device can serve as an advance predictor of future driving under the influence (DUI) of alcohol risks. Data used in this current report represent approximately 2,200 ignition interlock users from Alberta, Canada, and about 8,000 interlock users from Quebec, Canada; the Alberta data set contained 5.5 million breath tests and the Quebec data 18.8 million breath tests. All tests are time and date stamped and this information was used to characterize patterns of BAC and vehicle use, and the relationship between BAC elevations and DUI offenses that accumulated after the interlock was removed from the vehicles. Findings from Cox regression (Marques et al., 2003) show that BAC elevations > .02-.04% are more potent predictors of repeat DUI (p < .0001) than even prior DUI (p < .006), usually found to be the strongest indicator of driver risk. Prior DUI obviously has no use for scaling the risk of first-time offenders. Drivers who are both multiple offenders and who have more than a few elevated interlock BAC tests are much more likely to repeat DUI. The timing and pattern of elevated BAC tests provided during the time drivers were required to use an alcohol ignition interlock device are remarkably similar on both a daily basis and an hourly basis when the interlock programs from the two provinces are compared directly. Both provinces had higher rates of elevated tests on Saturday and Sunday, and the fewest elevated tests on Tuesdays. The absolute rate of elevated tests is similar despite the two provinces adhering to different interlock lockout points (.02% Quebec; .04% Alberta). Charts tracking the Monday-Friday timing of elevated BAC tests by hour are nearly identical for both provinces. The most elevated BAC tests occurred between 7 and 9 A.M. Monday to Friday, even though most vehicle start attempts occurred much later in the day. This higher rate of elevated morning BAC likely represents drinking from the prior evening with alcohol not yet cleared from circulation; those with elevated BAC in the early morning were more likely to have a repeat offense even after accounting for prior DUI and the higher overall rate of elevated BAC tests. This is viewed as evidence of a drinking problem that will lead to impaired driving after the controlling function of the interlock is removed. Policy changes are discussed that might take better advantage of interlock information to improve the public response to drunk driving.     

Sediment retention in rangeland riparian buffers

Controlling nonpoint-source sediment pollution is a common goal of riparian management, but there is little quantitative information about factors affecting performance of rangeland riparian buffers. This study evaluated the influence of vegetation characteristics, buffer width, slope, and stubble height on sediment retention in a Montana foothills meadow. Three vegetation types (sedge wetland, rush transition, bunchgrass upland) were compared using twenty-six 6- x 2-m plots spanning 2 to 20% slopes. Plots were clipped moderately (10-15 cm stubble) or severely (2-5 cm stubble). Sediment (silt + fine sand) was added to simulated overland runoff 6, 2, or 1 m above the bottom of each plot. Runoff was sampled at 15-s to > 5-min intervals until sediment concentrations approached background levels. Sediment retention was affected strongly by buffer width and moderately by vegetation type and slope, but was not affected by stubble height. Mean sediment retention ranged from 63 to > 99% for different combinations of buffer width and vegetation type, with 94 to 99% retention in 6-m-wide buffers regardless of vegetation type or slope. Results suggest that rangeland riparian buffers should be at least 6 m wide, with dense vegetation, to be effective and reliable. Narrower widths, steep slopes, and sparse vegetation increase risk of sediment delivery to streams. Vegetation characteristics such as biomass, cover, or density are more appropriate than stubble height for judging capacity to remove sediment from overland runoff, though stubble height may indirectly indicate livestock impacts that can affect buffer performance.     

The alcohol interlock: an underutilized resource for predicting and controlling drunk drivers

This report summarizes evidence presented during the Third Annual Ignition Interlock Symposium at Vero Beach, Florida, 29 October 2002. The ignition interlock prevents a car from starting when blood alcohol concentration (BAC) is elevated. We review some of our prior work as well as introduce previously unpublished results to demonstrate the manner in which the data recorded by the alcohol ignition interlock device can serve as an advance predictor of future driving under the influence (DUI) of alcohol risks. Data used in this current report represent approximately 2,200 ignition interlock users from Alberta, Canada, and about 8,000 interlock users from Quebec, Canada; the Alberta data set contained 5.5 million breath tests and the Quebec data 18.8 million breath tests. All tests are time and date stamped and this information was used to characterize patterns of BAC and vehicle use, and the relationship between BAC elevations and DUI offenses that accumulated after the interlock was removed from the vehicles. Findings from Cox regression show that BAC elevations >.02-.04% are more potent predictors of repeat DUI (p<.0001) than even prior DUI (p<.006), usually found to be the strongest indicator of driver risk. Prior DUI obviously has no use for scaling the risk of first-time offenders. Drivers who are both multiple offenders and who have more than a few elevated interlock BAC tests are much more likely to repeat DUI. The timing and pattern of elevated BAC tests provided during the time drivers were required to use an alcohol ignition interlock device are remarkably similar on both a daily basis and an hourly basis when the interlock programs from the two provinces are compared directly. Both provinces had higher rates of elevated tests on Saturday and Sunday, and the fewest elevated tests on Tuesdays. The absolute rate of elevated tests is similar despite the two provinces adhering to different interlock lockout points (.02% Quebec;.04% Alberta). Charts tracking the Monday-Friday timing of elevated BAC tests by hour are nearly identical for both provinces. The most elevated BAC tests occurred between 7 and 9 A.M. Monday to Friday, even though most vehicle start attempts occurred much later in the day. This higher rate of elevated morning BAC likely represents drinking from the prior evening with alcohol not yet cleared from circulation; those with elevated BAC in the early morning were more likely to have a repeat offense even after accounting for prior DUI and the higher overall rate of elevated BAC tests. This is viewed as evidence of a drinking problem that will lead to impaired driving after the controlling function of the interlock is removed. Policy changes are discussed that might take better advantage of interlock information to improve the public response to drunk driving.     

Modelling trends in woody vegetation structure in semi-arid Australia as determined from aerial photography

Accounting of carbon stocks in woody vegetation for greenhouse purposes requires definition of medium term trends with accurate error assessment. Tree and shrub cover was sampled through time at randomly located sites over a large area of central Queensland, Australia using aerial photography from 1945 to 1999. Calibration models developed from field data for the same land types as those represented within the study area allowed for the extrapolation of overstorey and understorey cover, basal area and biomass values and these were modelled as trends over the latter half of the 20th century. These structural attributes have declined over the region because of land clearing with values for biomass changing from a mean of 58.0(+/-1.2)t/ha in 1953 to 41.1(+/-1.0)t/ha in 1991. The biomass of Acacia on clay and Eucalypt on texture contrast soils land types has declined most dramatically. Within uncleared vegetation there was an overall trend of increase from 56.1(+/-1.2)t/ha in 1951 to 67.6(+/-1.3)t/ha in 1995. The increase in structural attributes within uncleared vegetation was most pronounced for the Eucalypt on texture contrast soils and Eucalypt on clay land types. It was demonstrated that the sites sampled were representative of their land types and that spatial bias of the photography, undetected tree-killing, sampling error, inherent variability of structural attributes and measurement error should not have impacted greatly on bias or precision of trend estimates for well-sampled land types. Certainly the errors are not likely to be substantial for trends averaged over all land types and they provide an accurate assessment of the magnitude and direction of change. The technique presented here would appear to be a robust means of accounting for the above-ground woody component of woodlands and open forests and will also contribute to a broader understanding of savanna dynamics.     

Photochemical smog effects in mixed conifer forests along a natural gradient of ozone and nitrogen deposition in the San Bernardino Mountains

Toxic effects of photochemical smog on ponderosa and Jeffrey pines in the San Bernardino Mountains were discovered in the 1950s. It was revealed that ozone is the main cause of foliar injury manifested as chlorotic mottle and premature needle senescence. Various morphological, physiological and biochemical alterations in the affected plants have been reported over a period of about 40 years of multidisciplinary research. Recently, the focus of research has shifted from studying the effects of ozone to multiple pollutant effects. Recent studies have indicated that the combination of ozone and nitrogen may alter biomass allocation in pines towards that of deciduous trees, accelerate litter accumulation, and increase carbon sequestration rates in heavily polluted forests. Further study of the effects of multiple pollutants, and their long-term consequences on the mixed conifer ecosystem, cannot be adequately done using the original San Bernardino Mountains Air Pollution Gradient network. To correct deficiencies in the design, the new site network is being configured for long-term studies on multiple air pollutant concentrations and deposition, physiological and biochemical changes in trees, growth and composition of over-story species, biogeochemical cycling including carbon cycling and sequestration, water quality, and biodiversity of forest ecosystems. Eleven sites have been re-established. A comparison of 1974 stand composition with data from 2000 stand composition indicate that significant changes in species composition have occurred at some sites with less change at other sites. Moist, high-pollution sites have experienced the greatest amount of forest change, while dryer low-pollution sites have experienced the least amount of stand change. In general, ponderosa pine had the lowest basal area increases and the highest mortality across the San Bernardino Mountains.     

Geophysical and Hydrologic Monitoring of Air Sparging Flow Behavior: Comparison of Two Extreme Sites

The distribution of air around injection wells is an important determinant of the effectiveness, design, and cost of air sparging remediation systems. High-level air sparging field tests were conducted at two sites for the purpose of determining the pattern of airflow under widely different subsurface conditions. One site consisted of relatively homogeneous dune sand (Site A). The other consisted of highly heterogeneous glacial till (Site B). At both sites, cross-borehole electrical resistance tomography (ERT) was used to image the principal region of airflow in the saturated zone. The response of conventional monitoring data was compared with the ERT results. At Site A, the principal region of airflow was approximately symmetric about the sparge well and only 2.4 m in radius. At Site B, the pattern of airflow was much more complex and had a major horizontal component. In both site studies, conventional monitoring data provided a much more ambiguous indication of the region of airflow in the saturated zone than did ERT. The investigations at these two sites demonstrate that, while the exact distribution of injected air is not readily discernible by conventional monitoring, the character of the airflow pattern can be recognized when appropriate physical response data are collected. Such response data can be used to evaluate site suitability for air sparging and to improve the system design and operation.