浅埋隧道覆岩变形沉降的分布式光纤监测与分析

针对在浅埋隧道下穿既有设施的施工过程中上覆层变形难以实现分布式监测这一问题,基于脉冲预泵浦光时域分析(PPP-BOTDA)分布式光纤传感技术,以云南某浅埋隧道连续下穿二级公路和钢筋加工车间场地为例,提出分布式光纤的布设方案,对隧道上覆层沉降变形进行监测,分析上覆层的变形特征。结果表明:上覆层中光纤应变的时空演化过程与岩土体物理力学性质、掌子面推进过程、初衬支护作用以及水文地质条件有关;掌子面前方和后方上覆层分别处于拉应力和压应力控制区,掌子面的位置对应着拉—压应变过渡带。同时,将分布式光纤和地表水准仪沉降监测进行比较,两种方法测得沉降结果趋势一致,验证了分布式光纤在隧道施工过程中对上覆岩土体纵向沉降监测的可行性。分布式光纤监测由于能够获取覆岩的整体变形时空演化特征,具有较明显的优势。     

Decontamination of Cr(VI) facilitated formation of persistent free radicals on rice husk derived biochar

PFRs were produced on biochar during Cr(VI) decontamination. PFRs formation on biochar was owing to the oxidization of phenolic-OH by Cr(VI). Appearance of excessive oxidant led to the consumption of PFRs on biochar. Biochar charred at high temperature possessed great performance to Cr(VI) removal. This study investigated the facilitation of Cr(VI) decontamination to the formation of persistent free radicals (PFRs) on rice husk derived biochar. It was found that Cr(VI) remediation by biochar facilitated the production of PFRs, which increased with the concentration of treated Cr(VI). However, excessive Cr(VI) would induce their decay. Biochar with high pyrolysis temperature possessed great performance to Cr(VI) removal, which was mainly originated from its reduction by biochar from Inductively Coupled Plasma Optical Emission Spectroscopy and X-ray Photoelectron Spectroscopy. And the corresponding generation of PFRs on biochar was primarily ascribed to the oxidization of phenolic hydroxyl groups by Cr(VI) from Fourier Transform Infrared Spectroscopy analysis, which was further verified by the H₂O₂ treatment experiments. The findings of this study will help to illustrate the transformation of reactive functional groups on biochar and provide a new insight into the role of biochar in environmental remediation.     

Structural and technological determinants of carbon intensity reduction of China’s electricity generation

Environmental Science and Pollution Research - Electricity generation is the largest sector with decarbonization potential for China and the world. Based on the new emission factors, this paper...     

Magnetic graphene-based nanocomposites as highly efficient absorbents for Cr(VI) removal from wastewater

Environmental Science and Pollution Research - Due to the merits of their high adsorption and convenient separation, magnetic graphene-based composites have become a promising adsorbent in terms of...     

Distillers’ grains anaerobic digestion residue biochar used for ammonium sorption and its effect on ammonium leaching from an Ultisol

Environmental Science and Pollution Research - The aim of this work was to explore the potential application of biochar from distillers’ grains anaerobic digestion residue pyrolyzed at...     

Simultaneous adsorption and immobilization of As and Cd by birnessite-loaded biochar in water and soil

Environmental Science and Pollution Research - A novel biochar was prepared by loading birnessite to improve its capability to simultaneously adsorb As(III), As(V), and Cd(II) in water and soil....     

间接蒸发冷却新风机组净化室内PM2.5特性

为有效降低室内PM2.5,指导间接蒸发冷却新风机组的设计选型,推导了新风机组净化效力和净化能效评价指标的数学表达式,并利用自行研制的间接蒸发冷却新风机组,分析了2种过滤器在不同运行工况下净化PM2.5的特性。结果表明,MERV 7+16和MERV 7+13的计数效率均随颗粒物粒径增加而提高,且前者的计数效率高于后者;由于滤材的不同,MERV 7+16的初阻力更小。MERV 7+16的渗透系数更小,其净化效力也要大于MERV 7+13;由于PM10在室内的自然沉降作用更显著,过滤器对PM10的净化效力明显大于PM2.5和PM1。将室内新风负荷作为新风机组能耗的一部分,在对比天津和南宁地区新风机组的净化能效时发现,由于两地区冬季室外温度存在明显差异,导致处于天津地区的新风机组若要在冬季获得同等的洁净空气量,需付出更多的能耗代价。     

Glyphosate application increased catabolic activity of gram-negative bacteria but impaired soil fungal community

Environmental Science and Pollution Research - Glyphosate is a non-selective organophosphate herbicide that is widely used in agriculture, but its effects on soil microbial communities are highly...