Verification of a 3D CFD model for vertical slot fish-passes

In the present work, we verified a 3D computational fluid dynamics model for vertical slot fish-passes (VSFs) that employs the renormalization-group k-epsilon turbulence model (RNG KE) and the volume of fluid (VOF) method. We compared model calculations with experiments in two pool designs T1 and T2 of an experimental VSF and with 2D calculations using the shallow water equations (SWE) and the standard k-epsilon (2D SKE) model. Calculations of the 3D model showed (1) good agreement with experiments and 2D calculations in predicting mean flow velocities, (2) better performance in the determination of the water surface in the VSF, which is attributed to the accurate VOF method, (3) superior prediction of turbulence characteristics than the 2D model, which is due to the 3D RNG KE model that overcomes the problem of turbulence overestimation of the 2D SKE model, and to the fact that the 3D model takes into account the 3D features of the flow in the fish pass. Moreover, the present 3D calculations showed that the common assumptions in VSFs that (1) the flow is 2D, and (2) the simulation of 4 pools of a VSF is sufficient to obtain satisfactory results, are not always valid. Flow can be considered as 2D only in pool design T2 and for certain geometries and flow characteristics in pool design T1; while, eventually, all the pools of a fish pass need to be modeled to ensure accurate results. Finally, the present work illustrates the need to perform fish experiments simultaneously with flow experiments.     

Sustainable development frontiers and divides: Transnational actors and US/China greenhouse gas emissions

Perpetuation of the South-North divide over climate change threatens to undermine the sustainability of the planet's vulnerable ecosystems. The current focus of international attention is on the USA and the PRC since both countries are in a position to negate or clinch the global warming mitigation efforts of the rest of the world community and because the two governments are primarily responsible for the entrenched global impasse over greenhouse gas (GHG) abatement. This contribution illustrates how transnational non-state actors, specifically Chinese American transmigrants, can make a difference in surmounting the US-China divide over GHG emissions, even in a time of state stalemate. Specific opportunities to shape sustainable development outcomes are explored by reference to energy efficiency, renewable energy, transportation, GHG capture, and public education projects. The discussion shows that, by teaming up with the NGOs, universities, foundations and firms engaged in or contemplating involvement in GHG emission mitigation projects in China, Chinese Americans from many walks of life who can manoeuvre skilfully along the climate change frontier occupy a potentially decisive position in terms of supporting sustainable development.     

Eco‐efficiency,self‐sufficiency and sustainability in transport: The limits for Brazilian sugarcane ethanol policy

This paper examines the historic development of the Brazilian sugarcane ethanol sector and the largely successful attempt to create a sustainable, renewable fuel for the transport sector. The policy that resulted from this process is an example of meeting the need for sustainable transport through the consideration of location‐specific characteristics and appropriate policy. The paper then questions the current and expected trajectory of the sugarcane ethanol sector with the focus on one key question: can sustainability be exported? In this analysis, the paper identifies new threats to the sustainability of Brazilian sugarcane ethanol and potential “opportunity costs” incurred in further development and internationalization of the sector. The paper concludes that exporting sugarcane ethanol may bring unanticipated deleterious consequences, which in turn means that both policy and theory need to be more precise about how sustainable transport is defined and bounded by time and space.     

Pollution and potential mobility of Cd, Ni and Pb in the sediments of a wastewater-receiving river in Hanoi, Vietnam

Large quantities of untreated industrial and domestic wastewater are discharged from the city of Hanoi into urban rivers. Sediment samples from three sites in the To Lich River in Hanoi were assessed with respect to the concentrations and potential mobility of cadmium (Cd), nickel (Ni) and lead (Pb). Due to very high Cd concentrations up to 700 mg kg^?1 at one site, the sediment was considered highly unsuitable for any types of land use if dredged and disposed of on land. Chemical sequential extractions of wet and anoxic sediment samples showed that Cd and Pb were largely associated with the redox-sensitive fractions and could thus be mobilised following measures such as resuspension or dredging. To assess the potential mobilisation of heavy metals from the anoxic sediment due to oxidation, the samples were exposed to different oxidants (i.e. atmospheric air and hydrogen peroxide) and afterwards submitted to a leaching test. These experiments showed that although oxidation may increase the equilibrium pore water concentrations of heavy metals in the sediments, other sediment mineral fractions seem to effectively immobilise heavy metals potentially released from the oxidisable fraction.     

Evaluation of the forest growth simulator SILVA on dominant trees in mature mixed Silver fir–Norway spruce stands in South-West Germany

Forest growth simulators go beyond a mere tabulation of empirical measurements by employing biometric models that functionally describe the dependence of forest growth of the initial forest structure, growth conditions and management regime. This makes them very flexible and allows predicting growth reactions for unknown and/or complex forest growth scenarios. When simulation outcomes are to be used in silvicultural strategic planning, the results are of direct and delicate importance, and the correct simulator performance must be ascertained. This is especially so when the considered forest situation differs from the forest data used to parameterise the model (e.g. different geographical region).In this article, the forest growth simulator SILVA (version 2.2) was validated for 55 long-term experimental plots of mature mixed Silver fir–Norway spruce stands in southwest Germany (Picea abies, Abies alba). The evaluation was restricted to the upper canopy trees during the survey period 1989–2004. Following the general evaluation criteria for ecological models from [Vanclay, J.K., Skovsgaard, J.P., 1997. Evaluating forest growth models. Ecol. Mod. 98, 1–12], a specific methodology was developed to evaluate the simulated height and diameter growth on the basis of forest growth principles.The qualitative analysis proved the SILVA growth algorithms to be in accordance with physiologically based standard growth equations. The quantitative evaluation was limited by incomplete knowledge of the site conditions. To overcome this problem, the experimental plots were regarded as a “heterogeneous growth series” which allows analysing the growth behaviour in a more general way. It could be shown that for the given data set, the SILVA simulations produced an overestimation of height growth (median: +61% spruce, +12% fir), and an underestimation of diameter growth and competition sensitivity (median: ?16% spruce, ?70% fir). The errors partially compensated in the volume growth resulting in an overall over-/underestimation of +9% for spruce and ?58% for fir (median).The unbalanced height and diameter growth cannot be compensated by a change in the site conditions because this affects both height and diameter growth either positive or negative. Hence, an adjustment of selected parameterisation values appears to offer the best solution to adapt SILVA to the considered forest situation. This approach of adaptive parameterisation is discussed against a more general background of deductive vs. inductive forest growth modelling.     

Optimization of selective pressurized liquid extraction for extraction and in-cell clean-up of PCDD/Fs in soils and sediments

This paper describes the development of methods for selective extraction of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) from soils and sediments, using pressurized liquid extraction with in-cell clean-up (SPLE). Two binary solvent mixtures, viz. dichloromethane/n-heptane (DCM/Hp), and diethylether/n-heptane (DEE/Hp), were evaluated. The SPLE extraction conditions were optimized using central composite face (CCF) design. Three factors were investigated: extraction temperature (60–160 °C), number of extraction cycles (1–3) and time per cycle (2–18 min). The results showed that DCM/Hp (1/1, v/v) and DEE/Hp (1/2, v/v) were the best extraction solvent compositions and that the extraction temperature was a critical factor that needed careful optimization to achieve high extraction efficiency without co-extraction of sulfuric acid. Under the optimal conditions, the SPLE methods provided results with good accuracy and precision. For the sandy soil certified reference material (CRM-529) the quantification results ended up in the range 82–110% as compared to the concentrations obtained by a reference method based on Soxhlet extraction and external column clean-up. Furthermore, for a clay soil (CRM-530) and a sediment reference material (WMS-01), the accuracy (trueness) of the TEQ values were +11% (DCM/Hp) and +8% (DEE/Hp) for CRM-530, +8% and ?7% for WMS-01, respectively. The individual congener concentrations also agreed well with the certified values. These findings show that SPLE is a promising method for combined extraction and clean-up of PCDD/Fs in soil/sediment samples.     

Erprobung und Erfolgskontrolle eines Phytoremediationsverfahrens zur Sanierung Sprengstoff-kontaminierter Böden

The final article of a series of three evaluates the in situ-remediation of TNT(trinitrotoluene)-contaminated soil from ‘Werk Tanne’. The multidisciplinary approach allows a differentiated assessment. Grading with large-scale machinery leads to a depletion of TNT for almost 90% within the first 6 months, while ADNT(amino-dinitrotoluene)-content decreases more or less steadily over 1,5 years. Grading reduces the heterogenous distribution of the contamination only slightly. Results from field-monitoring and biotest-battery indicate residual toxicities of ecotoxicological relevance and a reduced capacity for biological regeneration, in comparison with the uncontamined site. Mycorrhized plants safe-guard the site and improve the soilecological conditions. Their role in reducing lower level residual toxicity requires further investigation. There is need for future research (1) on the dynamics and mechanisms of the initial decrease of TNT followed by stagnation, (2) on the fate of the primary metabolites, (3) on long-term effects of the phytoremediation, and (4) on the establishment of the complex monitoring for routine work.