Sorption of biodegradation end products of nonylphenol polyethoxylates onto activated sludge

IntroductionRecently ,nonylphenolpolyethoxylates (NPnEO (n :numberofethoxyunits(EOs) )havebecomeaproblematicissueforthereasonthatthesecompounds,animportantgroupofnonionicsurfactants ,havebeenusedwidelyinvariousindustriesasflocculants,dispersants,emulsifie…     

A preliminary risk assessment of trace elements accumulated in fish to the Indo-Pacific Humpback dolphin (Sousa chinensis) in the northwestern waters of Hong Kong

In order to assess the potential risks associated with consumption of contaminated prey items to the Indo-Pacific Humpback dolphin (Sousa chinensis), fish species (Collichthys lucida, Pseudosciaena crocea, Johnius sp., Thryssa sp., Mugil sp. and Trichiurus sp.) representing the main food items of the dolphin were collected from the northwestern waters of Hong Kong, including the Sha Chau and Lung Kwu Chau Marine Park, which form the main habitat of the dolphin in Hong Kong. Within these waters, there are several potential sources of pollution including significant inputs from the Pearl River catchment, several major sewage outfalls and a series of mud pits that receive contaminated dredged sediments. Concentrations of thirteen trace elements (Ag, As, Cd, Co, Cr, Cs, Cu, Hg, Mn, Ni, Se, V, and Zn) in the fish tissue were analyzed by inductively coupled plasma mass spectrometer (ICP-MS). An assessment of the risks of adverse effects on the dolphin due to consumption of tainted fish was undertaken using two toxic reference benchmarks, namely the reference dose (RfD) and toxicity reference value (TRV). The risk quotient (RQ) calculated for each element showed that the risks from consumption of fish were generally low and within safe limits. The risks associated with arsenic, cadmium and mercury were, however, elevated. The highest calculated RQ was associated with total arsenic; however, the majority of arsenic in marine organisms tends to be in the non-toxic organic form, and the actual risk to the dolphin due to this metalloid is likely to be lower.     

Preparation of sulfurized powdered activated carbon from waste tires using an innovative compositive impregnation process

The objective of this study is to develop an innovative compositive impregnation process for preparing sulfurized powdered activated carbon (PAC) from waste tires. An experimental apparatus, including a pyrolysis and activation system and a sulfur (S) impregnation system, was designed and applied to produce sulfurized PAC with a high specific surface area. Experimental tests involved the pyrolysis, activation, and sulfurization of waste tires. Waste-tire-derived PAC (WPAC) was initially produced in the pyrolysis and activation system. Experimental results indicated that the Brunauer-Emmett-Teller (BET) surface area of WPAC increased, and the average pore radius of WPAC decreased, as water feed rate and activation time increased. In this study, a conventional direct impregnation process was used to prepare the sulfurized PAC by impregnating WPAC with sodium sulfide (Na2S) solution. Furthermore, an innovative compositive impregnation process was developed and then compared with the conventional direct impregnation process. Experimental results showed that the compositive impregnation process produced the sulfurized WPAC with high BET surface area and a high S content. A maximum BET surface area of 886 m2/g and the S content of 2.61% by mass were obtained at 900 degrees C and at the S feed ratio of 2160 mg Na2S/g C. However, the direct impregnation process led to a BET surface area of sulfurized WPAC that decreased significantly as the S content increased.     

Whole-mount in situ TUNEL method revealed ectopic pattern of apoptosis in cadmium treated naupliar larvae of barnacle (Balanus amphitrite Darwin)

The effect of cadmium on stage II naupliar larvae of barnacle (Balanus amphitrite Darwin) was investigated. Barnacle larvae were exposed to 0-15 microM CdCl(2) for 24 h. Apoptotic cells were stained by the terminal deoxyribonucleotidyl transferase mediated dUTP nick end labelling (TUNEL) method. Incidence of apoptosis, as measured by numbers of animals with ectopic pattern of apoptosis as well as numbers of apoptotic cells per animal, was assessed using confocal microscopy. An increase in incidence of apoptosis was observed in the experimental animals with an increase in cadmium concentration. Mortality increased, and motility decreased, when barnacle larvae were exposed to an increasing concentration of cadmium. The relationship between the occurrence of apoptosis and swimming behaviour was investigated in larvae exposed to 10 microM CdCl(2). Significant increases in apoptosis were detected in the non-motile and dead nauplii. This study suggested that whole-mount in situ TUNEL method may be used to study increased occurrence of apoptotic cells in crustacean larvae.     

Assessment of pilot direct contact membrane distillation regeneration of lithium chloride solution in liquid desiccant air-conditioning systems using computer simulation

Environmental Science and Pollution Research - Membrane distillation (MD) has been increasingly explored for treatment of various hyper saline waters, including lithium chloride (LiCl) solutions...     

Physical Characterization and Pre-assessment of Recycled High-Density Polyethylene as 3D Printing Material

3D printing has received lots of attention due to its limitless potential and advantages in comparison to traditional manufacturing processes. This study focuses on the most popular type of home 3D printers, namely fused filament fabrication (FFF) printers, which use plastic filaments as the feedstock. The rather high material cost and large amount of plastic waste generated by FFF 3D printers have driven the need for plastic filaments produced from recycled plastic waste. This study evaluates, in terms of physical characterization, the feasibility of using recycled high-density polyethylene (HDPE), one of the most commonly used plastics, as the feedstock for 3D printers, in comparison with the common acrylonitrile butadiene styrene plastic pellets. In-house extrusion using recycled HDPE pellets and flakes is possible. The diameter consistency and extrusion rate results, along with other physical characterization results, including differential scanning calorimetry, thermogravimetric analysis, Fourier transform infrared spectroscopy, Raman spectroscopy, and water absorption, suggest that making filaments from recycled HDPE pellets is a viable option, as the obtained filament has favorable water rejection and comparable extrusion rate and thermal stability. Existing methods for overcoming the warping and adhesion problems in 3D printing with HDPE were also reviewed. In order to increase the market competitiveness of waste-derived filaments, optimization of the extrusion process, studies on the mechanical and aging properties, and development of a standard characterization methodology and database are crucial.     

Trophic relationships and health risk assessments of trace metals in the aquaculture pond ecosystem of Pearl River Delta,China

Cadmium, lead, zinc, Chromium, copper, nickel and manganese in sediments and in aquatic organisms were collected from the aquaculture pond ecosystem of the Pearl River Delta (PRD), China and analyzed to evaluate bioaccumulation and trophic transfer in food chains, as well as the potential health risk of exposure to the Hong Kong residents via dietary intake of these aquatic products. The results revealed that based on the biota–sediment accumulation factor, omnivorous fish and zooplankton accumulated more trace metals from sediment than carnivorous fish. Concentrations of seven trace metals in aquaculture pond of PRD significantly decreased with increasing trophic levels, showing that these trace metals were trophically diluted in predatory and omnivorous food chains. The hazard index values of all fish species were smaller than 1 for adults and children, indicating there was no health risk from the multiple metals via ingestion of the freshwater fish for the inhabitants.     

The status and distribution of PCBs along the coast of Vietnam

Environmental Geochemistry and Health - Polychlorinated biphenyls (PCBs), well-known as an important scientific achievement, are now considered as one of the most persistent organic pollutants...     

Atmospheric heavy metal deposition in Northern Vietnam: Hanoi and Thainguyen case study using the moss biomonitoring technique,INAA and AAS

Background, aim, and scope  

The moss technique is widely used to monitor atmospheric deposition of heavy metals in many countries in Europe, whereas this technique is scarcely used in Asia. To implement this international reliable and cheap methodology in the Asian countries, it is necessary to find proper moss types typical for the Asian environment and suitable for the biomonitoring purposes. Such a case study was undertaken in Vietnam for assessing the environmental situation in strongly contaminated areas using local species of moss Barbula indica.     

Persistent organic pollutants in food items collected in Hong Kong

This study aims to investigate levels of POPs in meat, edible oils, nuts, milk and wine collected from Hong Kong. Naphthalene, pp-DDE, beta-, gamma-HCH and PBDE 47 were detected in most of the food items. Goose liver accumulated the highest PAHs (47.9 ng g⁻¹ wet wt), DDTs (25.6), HCHs (13.0), PCBs (4.17), PBDEs (468 pg g⁻¹ wet wt) among all the selected food. Meat and nut groups had significant (p < 0.01 or 0.05) correlations between lipid contents and concentrations of PAHs (meat: r = 0.878), HCHs (meat: r = 0.753), DDTs (meat: r = 0.937; nuts: r = 0.968) and PCBs (meat: r = 0.832; nut: r = 0.946). The concentrations of DDTs, HCHs and PCBs in vegetable oil were lower, but HCHs in fish oil were higher, when compared with other countries. The concentrations of PAHs, DDTs, PCBs and PBDEs in food tested in the present study were all below various safety guidelines.