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411.
研究了用Fenton试剂处理选矿废水中残余的黄药,分别考查了氧化时间、反应初始pH值、Fe2+浓度及H2O2用量对黄药降解效果的影响,用正交试验确定了4个因素的最好条件。结果表明:初始pH值和H2O2用量是影响去除效果的主要因素;氧化时间为60 m in,反应初始pH=4,[Fe2+]=20 mg/L,[H2O2]=20 mg/L,黄药的浓度为125 mg/L时,黄药的去除率达到99.5%;初步探讨了Fenton试剂净化废水中黄药的机理是.OH自由基先将黄药氧化为过氧化黄原酸盐,再将其氧化为CO2,黄药得到去除。 相似文献
412.
The Influence of Mycorrhiza on Uranium and Phosphorus Uptake by Barley Plants from a Field-contaminated Soil (7 pp) 总被引:3,自引:0,他引:3
Chen B Zhu YG Zhang X Jakobsen I 《Environmental science and pollution research international》2005,12(6):325-331
Background Recent studies indicated that arbuscular mycorrhizal fungi (AMF) play important roles in plant accumulation of uranium (U)
from contaminated environments, but the impacts of fertilization practices on functioning of the symbiotic associations, which
are crucial factors influencing plant nutrition and growth responses to mycorrhiza, have rarely been considered.
Materials and Methods In a greenhouse experiment, a bald root barley mutant (brb) together with the wild type (wt) were used to test the role of
root hairs and AMF in uranium (U) uptake by host plants from a U contaminated soil. Nil, 20 and 60 mg KH2PO4-P kg–1 soil were
included to investigate the influences of phosphorus (P) fertilization on plant growth and accumulation of U.
Results Dry matter yield of barley plants increased with increasing P additions and wt produced significantly higher dry weight than
brb. Mycorrhiza markedly improved dry matter yield of both genotypes grown at nil P, whereas only brb responded positively
to mycorrhiza at 20 mg P kg-1. At the highest P level, mycorrhiza resulted in growth depressions in both genotypes, except
for the roots of wt. In general, plant P concentrations increased markedly with increasing P additions and in response to
mycorrhiza.
Mycorrhiza and P additions had no significant effects on shoot U concentrations. However, root U concentrations in both genotypes
were significantly increased by mycorrhiza. On the other hand, shoot U contents increased with increasing P levels, while
20 mg P kg-1 stimulated, but 60 mg P kg-1 marginally affected the U accumulation in roots. Root length specific U uptake was
moderately enhanced both by root hairs and strongly enhanced by mycorrhiza. Moreover, non-inoculated plants generally had
higher shoot-root ratios of U content than the corresponding inoculated controls.
Conclusion Our study shows that AMF and root hairs improves not only P acquisition but also the root uptake of U, and mycorrhiza generally
decreases U translocation from plant root to shoot. Hence, mycorrhiza is of potential use in the phytostabilization of U contaminated
environments.
Perspectives The complex impacts of P on U accumulation by barley plants suggested that U behavior in mycorrhizosphere and translocation
along the soil-fungi-plant continuum as affected by fertilization practices deserve extensive studies for optimizing the function
of mycorrhizal associations for phytoremediation purposes. 相似文献
413.
硫化氢废气治理研究进展 总被引:9,自引:0,他引:9
综合评述了硫化氢废气的各类净化方法及最新的研究进展。硫化氢废气的净化有吸收法、吸附法、氧化法、分解法和生物法。本文对超级克劳斯法和分解法研究进展进行了重点阐述。 相似文献
414.
Chlorinated and polycyclic aromatic hydrocarbons in riverine and estuarine sediments from Pearl River Delta, China 总被引:53,自引:0,他引:53
Mai BX Fu JM Sheng GY Kang YH Lin Z Zhang G Min YS Zeng EY 《Environmental pollution (Barking, Essex : 1987)》2002,117(3):457-474
Spatial distribution of chlorinated hydrocarbons [chlorinated pesticides (CPs) and polychlorinated biphenyls (PCBs)] and polycyclic aromatic hydrocarbons (PAHs) was measured in riverine and estuarine sediment samples from Pearl River Delta, China, collected in 1997. Concentrations of CPs of the riverine sediment samples range from 12 to 158 ng/g, dry weight, while those of PCBs range from 11 to 486 ng/g. The CPs concentrations of the estuarine sediment samples are in the range 6-1658 ng/g, while concentrations of PCBs are in the range 10-339 ng/g. Total PAH concentration ranges from 1168 to 21,329 ng/g in the riverine sediment samples, whereas the PAH concentration ranges from 323 to 14,812 ng/g in the sediment samples of the Estuary. Sediment samples of the Zhujiang River and Macao harbor around the Estuary show the highest concentrations of CPs, PCBs, and PAHs. Possible factors affecting the distribution patterns are also discussed based on the usage history of the chemicals, hydrologic condition, and land erosion due to urbanization processes. The composition of PAHs is investigated and used to assess petrogenic, combustion and naturally derived PAHs of the sediment samples of the Pearl River Delta. In addition, the concentrations of a number of organic compounds of the Pearl River Delta samples indicate that sediments of the Zhujiang river and Macao harbor are most likely to pose biological impairment. 相似文献
415.
GuanNan Xiong YunHui Zhang YongHong Duan ChuanYang Cai Xin Wang JingYa Li Shu Tao WenXin Liu 《Environmental science and pollution research international》2017,24(23):18953-18965
Samples of ambient air (including gaseous and particulate phases), dust fall, surface soil, rhizosphere soil, core (edible part), outer leaf, and root of cabbage from eight vegetable plots near a large coking manufacturer were collected during the harvest period. Concentrations, compositions, and distributions of parent PAHs in different samples were determined. Our results indicated that most of the parent PAHs in air occurred in the gaseous phase, dominated by low molecular weight (LMW) species with two to three rings. Specific isomeric ratios and principal component analysis were employed to preliminarily identify the local sources of parent PAHs emitted. The main emission sources of parent PAHs could be apportioned as a mixture of coal combustion, coking production, and traffic tailing gas. PAH components with two to four rings were prevailing in dust fall, surface soil, and rhizosphere soil. Concentrations of PAHs in surface soil exhibited a significant positive correlation with topsoil TOC fractions. Compositional profiles in outer leaf and core of cabbage, dominated by LMW species, were similar to those in the local air. Overall, the order of parent PAH concentration in cabbage was outer leaf > root > core. Partial correlation analysis and multivariate linear stepwise regression revealed that PAH concentrations in cabbage core were closely associated with PAHs present both in root and in outer leaf, namely, affected by adsorption, then absorption, and translocation of PAHs from rhizosphere soil and ambient air, respectively. 相似文献
416.
Using multivariate analyses and GIS to identify pollutants and their spatial patterns in urban soils in Galway, Ireland 总被引:8,自引:0,他引:8
Zhang C 《Environmental pollution (Barking, Essex : 1987)》2006,142(3):501-511
Galway is a small but rapidly growing tourism city in western Ireland. To evaluate its environmental quality, a total of 166 surface soil samples (0-10 cm depth) were collected from parks and grasslands at the density of 1 sample per 0.25 km2 at the end of 2004. All samples were analysed using ICP-AES for the near-total concentrations of 26 chemical elements. Multivariate statistics and GIS techniques were applied to classify the elements and to identify elements influenced by human activities. Cluster analysis (CA) and principal component analysis (PCA) classified the elements into two groups: the first group predominantly derived from natural sources, the second being influenced by human activities. GIS mapping is a powerful tool in identifying the possible sources of pollutants. Relatively high concentrations of Cu, Pb and Zn were found in the city centre, old residential areas, and along major traffic routes, showing significant effects of traffic pollution. The element As is enriched in soils of the old built-up areas, which can be attributed to coal and peat combustion for home heating. Such significant spatial patterns of pollutants displayed by urban soils may imply potential health threat to residents of the contaminated areas of the city. 相似文献
417.
418.
419.
420.
Occurrence of PAHs, PCBs and organochlorine pesticides in the Tonghui River of Beijing, China 总被引:48,自引:0,他引:48
Tonghui River, a typical river in Beijing, People's Republic of China, was studied for its water and sediment quality, by determining the levels of 16 polycyclic aromatic hydrocarbons (PAHs), 12 polychlorinated biphenyls (PCBs) and 18 organochlorine pesticides in water and sediment samples. Total PAHs, PCBs and organochlorine pesticides concentrations in water varied from 192.5 to 2651 ng/l, 31.58-344.9 ng/l and 134.9-3788 ng/l, respectively. The total PAHs, PCBs and organochlorine pesticides concentrations in surficial sediments were 127-928 ng/g, 0.78-8.47 ng/g and 1.79-13.98 ng/g dry weight, respectively. The results showed that the concentration of these selected organic pollutants in sediment was higher than those in surface water. It may be due to the fact that organic hydrophobic pollutants tend to stay in the sediments. The PAHs were dominated by 2-, 3-ring components in water samples and by 3- and 4-ring compounds in sediment. For organochlorines, alpha-HCH, delta-HCH, Heptachlor, Endosulfan II, DDT are the major organochlorine pesticides in water while Heptachlor, Dieldrin and DDE composed of 95% of total organochlorine pesticides in sediment. For HCHs (HCHs=alpha-HCH+beta-HCH+gamma-HCH+delta-HCH), the predominance of alpha-HCH of total HCHs were clearly observed in water and sediment. PCB18, PCB31 and PCB52 were predominant in water, on average these compounds collectively accounted for 67% of total PCBs. But in sediment, the predominant compounds were PCB28, PCB31 and PCB153, which accounted for 71% of total PCBs in sediment. The levels of micro pollutants in our study areas were compared with other studies. 相似文献