Spray irrigation of landfill leachate: estimating potential exposures to workers and bystanders using a modified air box model and generalised source term

Generalised source term data from UK leachates and a probabilistic exposure model (BPRISC(4)) were used to evaluate key routes of exposure from chemicals of concern during the spraying irrigation of landfill leachate. Risk estimates secured using a modified air box model are reported for a hypothetical worker exposed to selected chemicals within a generalised conceptual exposure model of spray irrigation. Consistent with pesticide spray exposure studies, the key risk driver is dermal exposure to the more toxic components of leachate. Changes in spray droplet diameter (0.02-0.2 cm) and in spray flow rate (50-1000 l/min) have little influence on dermal exposure, although the lesser routes of aerosol ingestion and inhalation are markedly affected. The risk estimates modelled using this conservative worst case exposure scenario are not of sufficient magnitude to warrant major concerns about chemical risks to workers or bystanders from this practice in the general sense. However, the modelling made use of generic concentration data for only a limited number of potential landfill leachate contaminants, such that individual practices may require assessment on the basis of their own merits.     

Spread of metals through an invertebrate food chain as influenced by a plant that hyperaccumulates nickel

Summary. Hyperaccumulation of metals in the shoot system of plants is uncommon, yet taxonomically and geographically widespread. It may have a variety of functions, including defense against herbivores. This study investigated the effects of hyperaccumulation on metal concentrations across trophic levels. We collected plant material, soil, and invertebrates from Portuguese serpentine outcrops whose vegetation is dominated by the nickel hyperaccumulator Alyssum pintodasilvae. Samples were analyzed for nickel, chromium, and cobalt. Grasshoppers, spiders, and other invertebrates collected from sites where A. pintodasilvae was common had significantly elevated concentrations of nickel, compared to nearby sites where this hyperaccumulator was not found. Chromium and cobalt, occurring in high concentrations in the serpentine soil but not accumulated by A. pintodasilvae, were not elevated in the invertebrates. Therefore, it appears likely that a flux of nickel to herbivore and carnivore trophic levels is specifically facilitated by the presence of plants that hyperaccumulate this metal. The results may be relevant to the development of phytoremediation and phytomining technologies, which use plants to extract metals from the soil. Reveived 22 August 2002; accepted 2 April 2003. R1D=" Correspondence to: A. J. Pollard, e-mail:joe.pollard@furman.edu     

‘Coastal squeeze’— an historical perspective

The use of salt marsh for agricultural use has probably been going on for thousands of years. This paper will look at the situation in southeast England, particularly the Wash. Here enclosure for extended grazing and over the last several hundred years, for arable cultivation, may have taken place since Roman Times. An enclosure of Freiston Shore salt marsh (1979) and a proposed further enclosure at Gedney Drove End at about the same time raised concerns about the cumulative effect of these developments on nature conservation interests. These concerns prompted the nature conservation agencies to oppose the Gedney Drove End enclosure. Though the conservation argument did not persuade the Government that no further enclosure should take place, economic circumstances changed such that the pressure for the creation of new agricultural land diminished. This marked the end of ‘reclamation’ in the Wash. Since then, in the UK at least, there have been no further enclosures of salt marsh for agriculture. What were the arguments that lead to this change? Up to this point the perceived wisdom, in the Wash at least, was that as enclosure took place new inter-tidal land was created to seaward— with no net loss of inter-tidal land. Today we accept that this is not the case and a policy of managed re-alignment has increasingly been adopted in England, at sites ranging from the Porlock shingle ridge in north Devon to the salt marshes of Freiston in the Wash. It is argued that recognition of ‘coastal squeeze’ probably began in the Wash some 20 years ago. It would appear that we are now witnessing a reversal of this trend. How far will it take us? Will we see a return of the large expanses of tidal swamp around the Wash and elsewhere along the southern North Sea coast? Is this an inevitable consequence of global warming? This paper provides an historical perspective of the issues and arguments that have led us to recognize ‘coastal squeeze’ and the importance of dynamic coast, including the European Commission’s ‘EURosion Project’, which reported in 2004 (Salman et al. 2004).     

FLOODPLAINS AND HOUSING VALUES: IMPLICATIONS FOR FLOOD MITIGATION PROJECTS1

ABSTRACT: The hedonic valuation method was used to quantify the impact of floodplain location on housing values in Fargo‐Moor‐head. Being located in the 100‐year floodplain lowered the home values by $8,990, and such homes were worth $10,241 less than similar homes located outside the floodplain before the major flood event of 1997. Required flood insurance premiums for these homes were determined to account for approximately 81 percent of this price depreciation. In contrast, homes in the 500‐year floodplain were worth $3,100 more than similar homes not in the floodplain. It was concluded that more disclosure is needed regarding the location of the 500‐year floodplain, and that the hedonic valuation method can be used to calculate the economic gains and losses associated with flood mitigation projects or floodplain remapping efforts that result in the reclassification of the legal floodplain status of individual homes.     

Results of Treatment Evaluations of a Contaminated Synthetic Soil

Under Phase I of EPA’s Superfund soil treatability research program, which was conducted from April to November 1987, a surrogate soil containing a wide range of chemical contaminants typically occurring at Superfund sites was prepared and subjected to bench- or pilot-scale performance evaluations using the following treatment technologies: 1) physical separation/volume reduction (soil washing); 2) chemical treatment (KPEG); 3) thermal desorption; 4 ) incineration; and 5) stabilization/fixation. This report covers the formulation and development of the surrogate soil; it also highlights the results of the five treatment evaluations. Virtually all of the analytical data underlying this research were developed using EPA-SW846 methods. Detailed project reports covering the findings of each study are available through EPA’s Risk Reduction Engineering Laboratory in Cincinnati, Ohio.     

Comparison of continuous and filter-based carbon measurements at the Fresno supersite

Results from six continuous and semicontinuous black carbon (BC) and elemental carbon (EC) measurement methods are compared for ambient samples collected from December 2003 through November 2004 at the Fresno Supersite in California. Instruments included a multi-angle absorption photometer (MAAP; lambda = 670 nm); a dual-wavelength (lambda = 370 and 880 nm) aethalometer; seven-color (lambda = 370, 470, 520, 590, 660, 880, and 950 nm) aethalometers; the Sunset Laboratory carbon aerosol analysis field instrument; a photoacoustic light absorption analyzer (lambda = 1047 nm); and the R&P 5400 ambient carbon particulate monitor. All of these acquired BC or EC measurements over periods of 1 min to 1 hr. Twenty-four-hour integrated filter samples were also acquired and analyzed by the Interagency Monitoring of Protected Visual Environments (IMPROVE) thermal/optical reflectance carbon analysis protocol. Site-specific mass absorption efficiencies estimated by comparing light absorption with IMPROVE EC concentrations were 5.5 m2/g for the MAAP, 10 m2/g for the aethalometer at a wavelength of 880 nm, and 2.3 m2/g for the photoacoustic analyzer; these differed from the default efficiencies of 6.5, 16.6, and 5 m2/g, respectively. Scaling absorption by inverse wavelength did not provide equivalent light absorption coefficients among the instruments for the Fresno aerosol measurements. Ratios of light absorption at 370 nm to those at 880 nm from the aethalometer were nearly twice as high in winter as in summer. This is consistent with wintertime contributions from vehicle exhaust and from residential wood combustion, which is believed to absorb more shorter-wavelength light. To reconcile BC and EC measurements obtained by different methods, a better understanding is needed of the wavelength dependence of light-absorption and mass-absorption efficiencies and how they vary with different aerosol composition.     

A commentary on recent water safety initiatives in the context of water utility risk management

Over the last decade, suppliers of drinking water have recognised the limitations of relying solely on end-product monitoring to ensure safe water quality and have sought to reinforce their approach by adopting preventative strategies where risks are proactively identified, assessed and managed. This is leading to the development of water safety plans; structured 'route maps' for managing risks to water supply, from catchment to consumer taps. This paper reviews the Hazard Analysis and Critical Control Point (HACCP) procedure on which many water safety plans are based and considers its appropriateness in the context of drinking water risk management. We examine water safety plans in a broad context, looking at a variety of monitoring, optimisation and risk management initiatives that can be taken to improve drinking water safety. These are cross-compared using a simple framework that facilitates an integrated approach to water safety. Finally, we look at how risk management practices are being integrated across water companies and how this is likely to affect the future development of water safety plans.     

A rapid, direct measurement of bacterial growth rate in anaerobic wastewater treatment.

Reliable design and operation of biological wastewater treatment systems demand robust models of biological degradation processes. However, methods to directly measure key bacterial growth kinetics have not been readily available. Those methods that are available rely on the classic measurement of aerobic respiration using oxygen uptake take rates. This paper shows how the thymidine assay can be used as a rapid and direct measurement of bacterial specific growth rates (mu) in situ for an anaerobic treatment process, independent of aerobic respiration. A filtration-based assay is applied and evaluated a dispersed-phase high-rate anaerobic treatment process, with results obtained in less than an hour. The chemical oxygen demand (COD) biomass in the reactor was 0.52 kg COD m(-3) and the specific growth rate of these anaerobic bacteria was 0.8 +/- 0.2 d(-1). It took the bacterial populations 21.6 hours to double. This is an important advancement from existing methods that use aerobic respiration as a pseudo measurement of bacterial specific growth rates. The method allows rapid and direct measures of microbial growth rates for anaerobic treatment processes.