基于排队论的城市垃圾箱最佳间距研究

针对城市垃圾箱最佳间距的研究不够精细的现状,本文通过建立排队论模型得到了可供不同城市参考的城市垃圾箱最佳间距参数表。通过对部分城市街道的垃圾箱摆放间距情况进行实地调查,运用层次分析法将影响垃圾箱间距分布的多重因素转化为单因素;建立了基于指数分布的数学模型,利用排队论分析单因素状态下的垃圾箱间距分布,得到了求解城市垃圾箱最佳间距的一般方法。     

羧酸盐型双子表面活性剂的合成及性能研究

以月桂酰氯、乙二胺与丁二酸酐为原料合成了一种羧酸盐型双子(gemini)表面活性剂。采用IR、1 HNMR对中间产物和目标产物进行结构表征,并考察了合成所得羧酸盐型gemini表面活性剂的表面活性。结果表明:合成产物即为目标产物。合成产物的临界胶束浓度为0.027mmol/L,比普通单链表面活性剂低2～3个数量级,表面张力最低可降至29.5mN/m。     

气相色谱法测定气田产出水中的甲醇含量

文章建立了使用气相色谱仪分析气田产出水中甲醇含量的方法。通过实验在设定不同分流比的情况下,能有效监测出气田产出水中不同浓度的甲醇含量,此方法灵敏度高,最低检出限为0.02%,测定气田产出水中甲醇加标回收率达到93%～94%。     

变压吸附技术的应用及其发展简述

文章分析了变压吸附技术存在的问题,并提出解决措施。通过对变压吸附技术应用现状的总结,对该技术未来的发展方向进行预测与评价。指出变压吸附技术能够经济高效地实现物质的分离,有望成为分离技术未来的发展方向,为环保和工业生产做出更大贡献。     

微型测定法测定白醋中的总酸度

利用微型滴定法测定白醋中的总酸度,并对常量实验和微型实验的测定结果进行了比较分析。结果两种方法无显著性差异,F检验、t检验均在允许范围内,微型实验的准确度和精密度均达到常量实验的测定水平,完全满足化学分析要求,并且有效地节省了实验试剂,大大降低了实验成本。     

秦皇岛海岸侵蚀动态研究

利用不同时期的地形图、遥感图片对比,并选取典型海岸岸滩监测剖面实测数据,对海岸侵蚀现状进行了分析和定量计算。分析结果显示,秦皇岛海岸全线处于侵蚀状态,平均蚀退率1.5～4 m/a,根据蚀退率可将秦皇岛海岸划分为严重侵蚀、强侵蚀、侵蚀、微侵蚀、稳定5种岸线侵蚀类型。     

Seawater Intrusion and Sustainable Yield of Basal Aquifers1

Liu, Clark C.K. and John J. Dai, 2012. Seawater Intrusion and Sustainable Yield of Basal Aquifers. Journal of the American Water Resources Association (JAWRA) 48(5): 861‐870. DOI: 10.1111/j.1752‐1688.2012.00659.x Abstract: Basal aquifers, in which freshwater floats on top of saltwater, are the major freshwater supply for the Hawaiian Islands, as well as many other coastal regions around the world. Under unexploited or natural conditions, freshwater and the underlying seawater are separated by a relatively sharp interface located below mean sea level at a depth of about 40 times the hydraulic head. With forced draft, the hydraulic head of a basal aquifer would decline and the sharp interface would move up. It is a serious problem of seawater intrusion as huge amounts of freshwater storage is replaced by saltwater. Also, with forced draft, the sharp interface is replaced by a transition zone in which the salinity increases downward from freshwater to saltwater. As pumping continues, the transition zone expands. The desirable source‐water salinity in Hawaii is about 2% of the seawater salinity. Therefore, the transition zone expansion is another serious problem of seawater intrusion. In this study, a robust analytical groundwater flow and salinity transport model (RAM2) was developed. RAM2 has a simple mathematical structure and its model parameters can be determined satisfactorily with the available field monitoring data. The usefulness of RAM2 as a viable management tool for coastal ground water management is demonstrated by applying it to determine the sustainable yield of the Pearl Harbor aquifer, a principal water supply source in Hawaii.     

Treatment of coking wastewater by an advanced Fenton oxidation process using iron powder and hydrogen peroxide

In this study the treatment of coking wastewater was investigated by an advanced Fenton oxidation process using iron powder and hydrogen peroxide. Particular attention was paid to the effect of initial pH, dosage of H₂O₂ and to improvement in biodegradation. The results showed that higher COD and total phenol removal rates were achieved with a decrease in initial pH and an increase in H₂O₂ dosage. At an initial pH of less than 6.5 and H₂O₂ concentration of 0.3 M, COD removal reached 44-50% and approximately 95% of total phenol removal was achieved at a reaction time of 1 h. The oxygen uptake rate of the effluent measured at a reaction time of 1 h increased by approximately 65% compared to that of the raw coking wastewater. This indicated that biodegradation of the coking wastewater was significantly improved. Several organic compounds, including bifuran, quinoline, resorcinol and benzofuranol were removed completely as determined by GC-MS analysis. The advanced Fenton oxidation process is an effective pretreatment method for the removal of organic pollutants from coking wastewater. This process increases biodegradation, and may be combined with a classical biological process to achieve effluent of high quality.     

Historical change of mercury pollution in remote Yongle archipelago, South China Sea

We collected three ornithogenic coral sand sedimentary profiles from Jinyin Island, Jinqing Island and Guangjin Island of Yongle archipelago, South China Sea and reconstructed the deposition flux of anthropogenic Hg over the past 700 years in the study area. On the whole, the anthropogenic Hg flux is relatively low; it remained at a low level before the Industrial Revolution with a small peak at about 1450-1550 AD, which may record the enhanced metallurgy activity in Ming Dynasty of China. During the 20th century, the deposition flux of anthropogenic Hg increased rapidly, but two troughs occurred during the periods around 1940s and 1970s, corresponding to the economic depression caused by World War II, Civil War in China (1945-1949), and the Culture Revolution (1966-1976) in China. Since the 1970s the deposition flux of anthropogenic Hg has been persistently increasing, apparently the result of fast economic development in East and Southeast Asia countries around South China Sea.