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771.
Romário J. da Silv Lizeth Carolina Mojica-Sánchez Filipe D.S. Gorz Graciela C. Pedro Bruna G. Maciel Gabriela P. Ratkovski Hérica D. da Roch Kamila T.O. do Nascimento Juan C. Medina-Llamas Alicia E. Chávez-Guajardo José J. Alcaraz-Espinoz Celso P. de Melo 《环境科学学报(英文版)》2021,33(2):62-73
We report the preparation of poly(3,4-ethylene dioxythiophene) (PEDOT)-modified polyvinylidene fluoride electrospun fibers and their use as a novel adsorbent material for the removal of the anionic dye Methyl Orange (MO) from aqueous media. This novel adsorbent material can be used to selectively remove MO on a wide pH range (3.0–10.0), with a maximum capacity of 143.8 mg/g at pH 3.0. When used in a recirculating filtration system, the maximum absorption capacity was reached in a shorter time (20 min) than that observed for batch mode experiments (360 min). Based on the analyses of the kinetics and adsorption isotherm data, one can conclude that the predominant mechanism of interaction between the membrane and the dissolved dye molecules is electrostatic. Besides, considering the estimated values for the Gibbs energy, and entropy and enthalpy changes, it was established that the adsorption process is spontaneous and occurs in an endothermic manner. The good mechanical and environmental stability of these membranes allowed their use in at least 20 consecutive adsorption/desorption cycles, without significant loss of their characteristics. We suggest that the physical-chemical characteristics of PEDOT make these hybrid mats a promising adsorbent material for use in water remediation protocols and effluent treatment systems. 相似文献
772.
Effects of the forced ventilation on composting of a solid olive-mill by-product ("alperujo") managed by mechanical turning 总被引:1,自引:0,他引:1
Cegarra J Alburquerque JA Gonzálvez J Tortosa G Chaw D 《Waste management (New York, N.Y.)》2006,26(12):1377-1383
The evaluation of the most suitable aeration technology for olive-mill by-product "alperujo" (AL) composting was carried out by using two identical piles prepared by mixing AL with a bulking agent (fresh cow bedding) and a mature compost (as inoculant). Forced ventilation was employed in conjunction with mechanical turning in one of the piles, whereas only mechanical turning was used in the other pile. These two treatment methods were evaluated by assessing process efficiency and end-product quality. The results show that the composting process was completed in less time when forced ventilation was coupled with mechanical turning. A slight delay in the evolution of pH, C/N ratio, and biodegradation of fats and organic matter was observed when only turning was employed. However, the recommended method for composting AL was mechanical turning without forced ventilation since the composition of the end-product in this case was comparable to the composted AL using forced ventilation coupled with mechanical turning. Furthermore, there were substantial economic savings by selecting mechanical turning alone, which included capital costs for equipment. 相似文献
773.
J. Hejzlar K. Šámalová P. Boers B. Kronvang 《Water, Air, & Soil Pollution: Focus》2006,6(5-6):487-494
Steady-state models for the prediction of P retention coefficient (R) in lakes were evaluated using data from 93 natural lakes and 119 reservoirs situated in the temperate zone. Most of the
already existing models predicted R relatively successfully in lakes while it was seriously under-estimated in reservoirs. A statistical analysis indicated the
main causes of differences in R between lakes and reservoirs: (a) distinct relationships between P sedimentation coefficient, depth, and water residence
time; (b) existence of significant inflow–outflow P concentration gradients in reservoirs. Two new models of different complexity
were developed for estimating R in reservoirs: , where τ is water residence time (year), was derived from the Vollenweider/Larsen and Mercier model by adding a calibrated parameter
accounting for spatial P non-homogeneity in the water body, and is applicable for reservoirs but not lakes, and , where [Pin] is volume-weighted P concentration in all inputs to the water body (μg l−1), was obtained by re-calibrating the OECD general equation, and is generally applicable for both lakes and reservoirs. These
optimised models yield unbiased estimates over a large range of reservoir types. 相似文献
774.
In the long-term, landfills are producing landfill gas (LFG) with low calorific values. Therefore, the utilization of LFG in combined heat and power plants (CHP) is limited to a certain period of time. A feasible method for LFG treatment is microbial CH(4) oxidation. Different materials were tested in actively aerated lab-scale bio-filter systems with a volume of 0.167 m(3). The required oxygen for the microbial CH(4) oxidation was provided through perforated probes, which distributed ambient air into the filter material. Three air input levels were installed along the height of the filter, each of them adjusted to a particular flow rate. During the tests, stable degradation rates of around 28 g/(m(3) h) in a fine-grained compost material were observed at a CH(4) inlet concentration of 30% over a period of 148 days. Compared with passive (not aerated) tests, the CH(4) oxidation rate increased by a factor of 5.5. Therefore, the enhancement of active aeration on the microbial CH(4) oxidation was confirmed. At a O(2)/CH(4) ratio of 2.5, nearly 100% of the CH(4) load was decomposed. By lowering the ratio from 2.5 to 2, the efficiency fell to values from 88% to 92%. By varying the distribution to the three air input levels, the CH(4) oxidation process was spread more evenly over the filter volume. 相似文献
775.
Environmental assessment of mercury dispersion, transformation and bioavailability in the Lake Victoria Goldfields, Tanzania 总被引:2,自引:0,他引:2
Environmental dispersion and transformation of mercury discharged from gold mining operations has been investigated in field and laboratory studies in order to provide better understanding of the degree of mercury (Hg) pollution and bioavailability in the Lake Victoria goldfields (LVGF) ecosystems. This paper reviews results already published elsewhere and presents additional data on Hg dynamics in the LVGF. Studies conducted at the Mugusu and Rwamagaza artisanal mines indicated different degrees of Hg contamination and dispersion in environmental matrices. Mercury concentration in contaminated river sediments near the Mugusu mine varied from 6.0 to 0.5 mg/kg on a dry weight basis. The highest Hg contamination levels (165-232 mg/kg) were associated with mine tailings at the Rwamagaza mine. Mercury concentrations in fish representing different dietary habits on the southwestern shore of Lake Victoria at the Nungwe Bay were very low (2-35 microg/kg) and thought to represent background levels. These and other results suggested that the use of Hg in gold extraction in the LVGF has not caused high Hg levels in lake fish. The study of Hg in lichens showed Parmelia lichen to be an effective bioindicator for atmospheric Hg contamination due to Hg emissions from gold-amalgam firing and purification operations. The Hg levels in the lichens around the Mugusu mine ranged from 3.1 to 0.1 microg/g; the highest levels were recorded in the lichens sampled close to gold-amalgam processing sites. The regional background level in the Parmelia lichen was 0.05-0.10 microg/g, with a mean level of 0.07 microg/g. Studies of Hg transformation in the mine tailings revealed unexpectedly high methylmercury (MeHg) levels in the tailings (629-710 ng/g), which indicated that oxidation and methylation of metallic Hg in the tailings occurred at significant levels under tropical conditions. Re-equilibration of the tailings with freshwater (FW) indicated the MeHg was firmly bound in the tailings and therefore very little MeHg was released to the water column (0.2-1.5 ng/L). The methylation of Hg in tropical loamy clay soil contaminated with HgCl(2) (5 mg Hg/kg) yielded MeHg concentrations of 11 and 14 ng/g when inundated with seawater and FW, respectively, for 4 weeks. Little MeHg was transferred from the soil to the equilibrated water (< or = 0.4 ng/L). Atmospheric exposure of the soil pre-inundated with FW resulted in net degradation of MeHg during the 1st week of exposure, followed by net production and accumulation of MeHg in the soil (up to 15.5 ng/g) during atmospheric desiccation. Mercury uptake by fish from the Hg(0)-contaminated aquatic sediment-tailings system in the aquarium experiment was found to be low, suggesting the low availability of MeHg for bioaccumulation in the system. These and other results provide useful insights into Hg transformation, mobility and bioavailability in tropical aquatic systems affected by Hg pollution from gold mining operations. 相似文献
776.
Fish mercury increase in Lago Manso, a new hydroelectric reservoir in tropical Brazil 总被引:3,自引:0,他引:3
Hylander LD Gröhn J Tropp M Vikström A Wolpher H de Castro E Silva E Meili M Oliveira LJ 《Journal of environmental management》2006,81(2):155-166
It has been frequently demonstrated that mercury (Hg) concentrations in fish rise in newly constructed hydroelectric reservoirs in the Northern Hemisphere. In the present work, we studied whether similar effects take place also in a tropical upland reservoir during impoundment and discuss possible causes and implications. Total Hg concentrations in fish and several soil and water parameters were determined before and after flooding at Rio Manso hydroelectric power plant in western Brazil. The Hg concentrations in soil and sediment were within the background levels in the region (22-35 ng g(-1) dry weight). There was a strong positive correlation between Hg and carbon and sulphur in sediment. Predatory fish had total Hg concentrations ranging between 70 and 210 ng g(-1) f.w. 7 years before flooding and between 72 and 755 ng g(-1) f.w. during flooding, but increased to between 216 and 938 ng g(-1) f.w. in the piscivorous and carnivorous species Pseudoplatystoma fasciatum, cachara, and Salminus brasiliensis, dourado, 3 years after flooding. At the same time, concentrations of organic carbon in the water increased and oxygen concentrations decreased, indicating increased decomposition and anoxia as contributing to the increased Hg concentrations in fish. The present fish Hg concentrations in commonly consumed piscivorous species are a threat to the health of the population dependent on fishing in the dam and downstream river for sustenance. Mercury exposure can be reduced by following fish consumption recommendations until fish Hg concentrations decrease to a safe level. 相似文献
777.
The regional-scale importance of an aquatic stressor depends both on its regional extent (i.e., how widespread it is) and
on the severity of its effects in ecosystems where it is found. Sample surveys, such as those developed by the U.S. Environmental
Protection Agency’s Environmental Monitoring and Assessment Program (EMAP), are designed to estimate and compare the extents,
throughout a large region, of elevated conditions for various aquatic stressors. In this article, we propose relative risk
as a complementary measure of the severity of each stressor’s effect on a response variable that characterizes aquatic ecological
condition. Specifically, relative risk measures the strength of association between stressor and response variables that can
be classified as either “good” (i.e., reference) or “poor” (i.e., different from reference). We present formulae for estimating
relative risk and its confidence interval, adapted for the unequal sample inclusion probabilities employed in EMAP surveys.
For a recent EMAP survey of streams in five Mid-Atlantic states, we estimated the relative extents of eight stressors as well
as their relative risks to aquatic macroinvertebrate assemblages, with assemblage condition measured by an index of biotic
integrity (IBI). For example, a measure of excess sedimentation had a relative risk of 1.60 for macroinvertebrate IBI, with
the meaning that poor IBI conditions were 1.6 times more likely to be found in streams having poor conditions of sedimentation
than in streams having good sedimentation conditions. We show how stressor extent and relative risk estimates, viewed together,
offer a compact and comprehensive assessment of the relative importances of multiple stressors. 相似文献
778.
Geographical areas constitute the basic implementation locus for integrated coastal zone management strategies and activities.
Because the definition of territorial planning objectives may be affected by socioeconomic and environmental characteristics,
one of the main steps in the process involves dividing the coast into homogeneous environmental management units (HEMUs).
This article presents a general and simple method for regionalizing the landside of a coastal zone into HEMUs and illustrates
it through application to the Catalan coast. Socioeconomic and natural (biophysical) subsystems were selected as the most
appropriate dimensions of the regionalization process. Dimensions were described using 11 spatial themes, which were managed
in a geographic information system environment that proved to be an adequate tool for the purpose. A final coastal zone map
of four classes of HEMUs connected to local administrative units was obtained, and because it reflects the current natural
and socioeconomic dynamics, it can be considered as an initial step in the planning process for the Catalan coast. Although
the proposed method was developed based on the characteristics of the Catalan coast, it is general enough to be adapted and
applied to most developed or developing coastal areas. 相似文献
779.
TUGAI: An Integrated Simulation Tool for Ecological Assessment of Alternative Water Management Strategies in a Degraded River Delta 总被引:1,自引:0,他引:1
Schlüter M Rüger N Savitsky AG Novikova NM Matthies M Lieth H 《Environmental management》2006,38(4):638-653
The development of ecologically sound water allocation strategies that account for the needs of riverine ecosystems is a pressing
issue, especially in semiarid river basins. In the Aral Sea Basin, a search for strategies to mitigate ecological and socioeconomic
deterioration has been in process since the early 1990s. The Geographic Information System–based simulation tool TUGAI has
been developed to support the policy determination process by providing a simple, problem-oriented method to assess ecological
effects of alternative water management strategies for the Amudarya River. It combines a multiobjective water allocation model
with simple, spatially explicit statistical and rule-based models of landscape dynamics. Changes in environmental conditions
are evaluated by a fuzzy habitat suitability index for Populus euphratica, which is the dominant species of the characteristic riverine Tugai forests. Water management scenarios can be developed
by altering spatiotemporal water distribution in the delta area or the amount of water inflow into the delta. Outcomes of
scenario analysis are qualitative comparisons of the ecological effects of different options for a time period of up to 28
years. The given approach utilizes different types of knowledge, from quantitative hydrological data to qualitative local
expert knowledge. The main purpose of the tool is to integrate the knowledge in a comprehensive way to make it available for
discussions on alternative policies in moderated workshops with stakeholders. In this article, the modules of the tool, their
integration, and three hypothetical scenarios are presented. Based on the experience gained when developing the TUGAI tool,
we propose that the general framework can be transferred to other areas where tradeoffs in water allocation between the environment
and other water users are of major concern. The potential for a simulation tool to structure and inform a complex resource
management situation by involving local experts and stakeholders in the development of possible future scenarios will become
increasingly valuable for transparent and participatory resource management. 相似文献
780.
Soil pollution with Cd is an environmental problem common in the world, and it is necessary to establish what Cd concentrations
in soil could be dangerous to its fertility from toxicity effects and the risk of transference of this element to plants and
other organisms of the food chain. In this study, we assessed Cd toxicity on soil microorganisms and plants in two semiarid
soils (uncultivated and cultivated). Soil ATP content, dehydrogenase activity, and plant growth were measured in the two soils
spiked with concentrations ranging from 3 to 8000 mg Cd/kg soil and incubated for 3 h, 20 days, and 60 days. The Cd concentrations
that produced 5%; 10%;, and 50%; inhibition of each of the two soil microbiological parameter studied (ecological dose, ED,
values) were calculated using two different mathematical models. Also, the effect of Cd concentration on plant growth of ryegrass
(Lolium perenne, L.) was studied in the two soils. The Cd ED values calculated for soil dehydrogenase activity and ATP content were higher
in the agricultural soils than in the bare soil. For ATP inhibition, higher ED values were calculated than for dehydrogenase
activity inhibition. The average yields of ryegrass were reduced from 5.03 to 3.56 g in abandoned soil and from 4.21 to 1.15
g in agricultural soil with increasing concentrations of Cd in the soil. Plant growth was totally inhibited in abandoned and
agricultural soils at Cd concentrations above 2000 and 5000 mg/kg soil, respectively. There was a positive correlation between
the concentration of Cd in the plants and the total or DTPA-extractable concentrations of Cd in the soil. 相似文献