Evaluation of nitrogen dioxide photolysis rates in an urban area using data from the 1997 Southern California Ozone Study

The photolysis of nitrogen dioxide and formaldehyde are two of the most influential reactions in the formation of photochemical air pollution, and their rates are computed using actinic flux determined from a radiative transfer model. In this study, we compare predicted and measured nitrogen dioxide photolysis rate coefficients (j_NO2). We used the Tropospheric Ultraviolet-Visible (TUV) radiation transfer model to predict j_NO2 values corresponding to measurements performed in Riverside, California as part of the 1997 Southern California Ozone Study (SCOS’97). Spectrally resolved irradiance measured at the same site allowed us to determine atmospheric optical properties, such as aerosol optical depth and total ozone column, that are needed as inputs for the radiative transfer model. Matching measurements of aerosol optical depth, ozone column, and j_NO2 were obtained for 14 days during SCOS’97. By using collocated measurements of the light extinction caused by aerosols and ozone over the full height of the atmosphere as model input, it was possible to predict sudden changes in j_NO2 resulting from atmospheric variability. While the diurnal profile of the rate coefficient was readily reproduced, j_NO2 model predicted values were found to be consistently higher than measured values. The bias between measured and predicted values was 17–36%, depending on the assumed single scattering albedo. By statistical analysis, we restricted the most likely values of the single scattering albedo to a range that produced bias on the order of 20–25%. It is likely that measurement error is responsible for a significant part of the bias. The aerosol single scattering albedo was found to be a major source of uncertainty in radiative transfer model predictions. Our best estimate indicates its average value at UV-wavelengths for the period of interest is between 0.77 and 0.85.     

Mechanisms for copper tolerance in Amphora coffeaeformis-internal and external binding

Growth of the ship-fouling diatom Amphora coffeaeformis and accumulation of copper in the cells were evaluated for cultures exposed to copper. Comparisons with literature reports for other species revealed that A. coffeaeformis shows no ability to maintain normal growth rates in the presence of high cellular copper levels. This suggests that internal binding is not the principal copper tolerance mechanism for this species. In addition, the copper complexing capacity of A. coffeaeformis exudates was evaluated. Significant complexing by these exudates was demonstrated by DPASV analysis. When added to the culture medium of another species (Thalassiosira profunda), A. coffeaeformis exudates were also able to reduce copper toxicity and accumulation in the cells of that species. However, the copper tolerance of A. coffeaeformis was greater than that acquired by T. profunda grown with A. coffeaeformis exudates; thus exudate production was deemed not to be a primary tolerance mechanism. Comparison of copper accumulations inside and outside cells of A. coeffeaeformis suggests that binding at the cell surface or to mucilage may be an important factor in the tolerance of this species to copper.     

A Decision-Support System for Prioritizing Restoration Sites on the Mississippi River Alluvial Plain

Conversion of forested wetlands to agricultural use and the resulting fragmentation of the landscape has led to concerns for the functional integrity of the Mississippi River Alluvial Plain ecosystem. We describe an effort spearheaded by The Nature Conservancy to initiate a multi-decade partnership dedicated to creating and implementing a viable, cooperative, landscape-level restoration project in the Mississippi River Alluvial Plain. Important phases of the process during the first 5 years were (1) initiation of the development of an extensive network of partners, including state and federal agencies, private land owners, conservation groups, academicians, and other interested citizens; (2) development of a geographic information system (GIS) for the entire extent of the ecosystem; and (3) for one watershed, the Tensas basin in northeastern Louisiana, refinement of a high resolution GIS to generate more detailed land-use conversion statistics to demonstrate the feasibility of a semi-objective, landscape-scale restoration planning procedure, including methodology for prioritization of existing wetland forest patches and areas most suitable for reforestation and connection via corridors.     

Comparative Population Genetic Structure of the Rare Woodland Shrub Daviesia suaveolens and Its Common Congener D. mimosoides

Genetic (allozyme) variation and population genetic structure of the rare shrub Daviesia suaveolens , found in only a few large populations on the eastern escarpment of the southern tablelands of New South Wales, were compared to those of its abundant and widespread relative D. mimosoides at both spatially equivalent and rangewide scales. We hypothesized that the rare species is genetically depauperate relative to the common one. We also generated baseline data on D. suaveolens to provide management recommendations for its conservation. Both species had high variation relative to other widespread woody angiosperms. Rangewide, the rare species exhibited lower species-level genetic variation than its common relative but a similar level of variation to that found in D. mimosoides over an equivalent spatial scale. Population-level genetic variation was similar for the two species. Over its small geographic range, D. suaveolens populations were three times as genetically differentiated as D. mimosoides over the same scale, showing a clear northsouth genetic disjunction and as much interpopulation divergence as the common species exhibited rangewide. These results confirm that not all types of rarity have the same genetic implications. Conservation strategies for D. suaveolens need not be concerned about low population-level variation unless populations become significantly smaller than is currently typical. Of more importance is to maintain the high interpopulation differentiation by conserving populations from both the north and south of the species' range.     

Prenatal molecular diagnosis of gaucher disease

Prenatal diagnosis of Gaucher disease, the most prevalent glycolipid storage disease, is based on a reliable enzyme assay of cells from amniocentesis or chorionic villous samples. However, this method cannot differentiate among the various forms of the disease. This report details four cases of prenatal diagnosis of Gaucher disease, three of which predate the use of molecular diagnosis. DNA mutation analysis to determine the genotype was predictive of the phenotypic status of the fetus and conformed to the genotype of an affected proband where available.     

USE OF STREAMFLOW INCREASES FROM VEGETATION MANAGEMENT IN THE VERDE RIVER BASIN1

ABSTRACT: Although the effects of vegetation management on streamflow have been studied in many locations, the effects of augmented streamflow on downstream water users have not been carefully analyzed. This study examines the routing of streamflow increases that could be produced in the Verde River Basin of Arizona. Reservoir management and water routing to users in the Salt River Valley around Phoenix were carefully modeled. Simulation of water routing with and without vegetation modification indicates that, under current institutional conditions, less than one-half of the streamflow increase would reach consumptive users as surface water. Most of the remainder would accumulate in storage until a year of unusually heavy runoff, when it would add to reservoir spills. Under alternative scenarios, from 39 to 58 percent of the streamflow increase was delivered to consumptive users.     

THE CENTRAL ARIZONA WATER CONTROL STUDY: A CASE FOR MULTIOBJECTIVE PLANNING AND PUBLIC INVOLVEMENT1

This paper describes the successful application of a multiobjective planning framework, incorporating substantial public involvement, to a major water resources decision involving intense confilcts. The study was initiated to help resolve more than a decade of controversy over a project proposed to control flooding and provide regulatory storage in the Phoenix, Arizona, area. The public was actively involved in the development of study goals and the specification of acceptable tradeoffs between multiple objectives. A wide range of structural and nonstructural alternatives was formulated and evaluated in relation to these objectives, and broad-based support was developed for a new plan. Reasons for the successful outcome are discussed, as well as implications for water resources planning under the new Federal Principles and Guidelines.