Evaluation of Selected Gaseous Halocarbons for Use in source Test Performance Audits

A repository of 38 gaseous organic compounds in compressed gas cylinders has been established by EPA. This repository was established to provide standards for source test performance audits, that is, quantitative quality assurance tests. Among these compounds are ten halogenated organic species, which are the focus of this paper.

Stability studies of all ten compounds have been performed to determine the feasibility of using them as performance audit standards. Results indicate that all of the halocarbons tested are adequately stable to be used as reliable audit standards.

Subsequent to completion of stability studies, four of the ten halocarbons were used in source test performance audits. Results are available at this time for two of the four compounds; the results show agreement within 10% of the concentrations previously established by Research Triangle Institute.     

Relationship of Destruction Parameters to the Destruction/Removal Efficiency of PCBs

The destruction/removal efficiency (DRE), and the ability to accurately measure it, is a function of the concentration of the chemical compound in the input waste, the incinerator design and operation, sampling methods, and the analytical procedures. All of these are interrelated. This paper discusses the basic DRE equation [DRE = W_In W_out)/W_in × 100] and how it relates to some of the other destruction parameters. Some example data from the literature are presented. While PCBs have been used as the example, the equations and graphs are equally valid for some other hazardous compounds (POHCs), with the substitution of the 99.99% DRE requirement in lieu of the 99.9999% DRE for PCBs. The use of the relationships discussed in this paper should allow incinerator operators to more efficiently plan demonstration test burns which will adequately demonstrate the DRE.     

Improving Baghouse Performance at the Monticello Generating Station

At the Monticello station, operated by the Texas Utilities Generating Company, lignite coal obtained locally in Titus and Hopkins Counties fuels each of the three units. Units 1 and 2 are identical 575-MW Combustion Engineering (CE) boilers, each of which discharges its effluent to a 36- compartment shake/deflate cleaned baghouse paralleled with four electrostatic precipitators (ESP). Unit 3 is a larger boiler and is followed by an ESP and a scrubber. The Unit 1 and 2 baghouses were designed to clean 80 percent of the flue gas. Since startup, these baghouses have regularly experienced flange-to-flange pressure drops in excess of 10 in. H₂O, with large opacity spikes caused by ash bleeding through the bags after compartment cleanings. Because of higher-than-expected pressure drop, the baghouses receive only about 45-50 percent of the flue gas. Analysis has shown the Monticello lignite ash significantly differs from most other coal ashes. Testing has shown that the Monticello ash is not filtered effectively by many "standard" bag materials. However, this testing indicates that there are fabrics that show promise of eliminating the ash bleedthrough with little pressure drop penalty. Testing has also shown that injection of low concentrations (10-15 ppm) of ammonia (NH₃) into the flue gas significantly decreases ash bleedthrough, so that with NH₃ injection "standard" bag materials may perform adequately. Currently, fullcompartment testing of four fabrics, with and without NH₃ injection, is under way at the Unit 1 baghouse. The research conducted at the Monticello station is reviewed in this paper and the encouraging results from the full-compartment tests are presented.     

A New Audit Technique for EPA Method 25

A simple, inexpensive, and accurate technique for evaluating or auditing the sampling, recovery, and analytical phases of EPA Source Reference Method 25 has been developed. The technique involves spiking a U-shaped stainless steel cartridge containing Tenax® with known quantities of selected organic compounds and thermally desorbing them at temperatures from 160°C to 180°C to generate organic vapors quantitatively. The major advantages of this technique are that no other measurement methods can be used to determine the generated organic concentrations in lieu of Method 25; and that the cartridge can easily be taken to the field for evaluation. The organic compounds generated in test runs are collected and analyzed using the Method 25 procedure. The generation of organics is quantitative and recoveries were found to be 100 ± 10%. The time required for desorption of the majority of organics is generally less than forty-five minutes at a flow rate of 100 mL/min; however, based on laboratory experience the recommended sampling time is sixty minutes. These spiked cartridges are stable at room temperature over a two-month period. Results of interlaboratory studies showed close agreement with the expected concentrations based on calculations from the mass loadings and sample volumes.     

Particulate,Carbon Monoxide,and Acid Emission Factors for Residential Wood Burning Stoves

Emissions from residential wood burning stoves are of Increasing concern in many areas. This concern is due to the magnitude of the emissions and the toxic and chemical characteristics of the pollutants. Recent testing of standard and new technology woodstoves has provided data for developing a family of particulate and carbon monoxide emission factor curves. This testing has also provided data illustrating the acidity of woodstove emissions. The particulate and carbon monoxide curves relate the actual stove emissions to the stove size and operating parameters of burn rate, fuel loading, and fuel moisture. Curves relating stove types to the acidity of emissions have also been constructed.

Test data show actual emissions vary from 3 to 50 grams per kilogram for particles and from 50 to 300 grams per kilogram for carbon monoxide. Since woodstove emissions are the largest single category of particulate emissions in many areas, it Is essential that these emissions be quantified specifically for geographic regions, allowing meaningful impact analysis modeling to be accomplished. Emission factors for particles and carbon monoxide are presented from several stove sizes and burn rates.

The acidic nature of woodstove emissions has been clearly demonstrated. Tests indicate woodstove flue gas condensate solutions to be predominantly in the 2.8 to 4.2 pH range. Condensate solutions from conventional woodstoves exhibited the characteristic buffering capacity of carboxylic acids when titrations were performed with a strong base. The environmental impact of buffered acidic woodstove emissions is not currently well understood; however, it is possible with the data presented here to make semi-quantitative estimates of acid emissions from particulate and carbon monoxide emission factors and wood use inventories.     

Technical Session Preliminary Schedule Announced for 1988 APCA Annual Meeting

ABSTRACT

Stable heterogeneous catalysts for the oxidative removal of CO from air at ambient temperatures have been developed. An alumina support impregnated with PdCl₂, CuCl₂, and CuSO₄ is described. Optimal activity was obtained with Pd 0.020 mol/kg, Cu 0.50 mol/kg, CuCl₂ 20-30% of total Cu, a 2- to 24-hr soak, filtration of surplus raffinate, and a 2- to 4-hr firing in air at 200-350 °C. The catalysts are effective at 20-26 °C and relative humidities in the 15-90% range. They are reversibly deactivated by completely dry or water-saturated air streams. These catalysts have been tested at space velocities up to 30,000 hr^-1. In contact with <100 ppm CO, they are highly efficient, removing ~99% of the CO with contact times of ~120 msec (pseudo-first order k' > 25 sec^-1). At much higher CO concentrations, the maximum CO loading rate—limited by the Cu(I) reoxidation rate—is approximately 17 m mol CO per Limol Pd per hour.     

Eliminating Reheat from Existing FGD Systems

The Clean Air Act Amendments of the early 1970_s required coal burning utilities to reduce their emissions of sulfur dioxide. Lime or limestone based wet systems were employed for flue gas desulfurization (FGD). These systems reduced flue gas temperatures to below acid dew point conditions. Concerned about the prospect of ductwork exposed to a saturated, acid-rich environment, most utilities turned to stack gas reheat (SGR) to increase flue gas temperatures. By 1980, 82 percent of all FGD facilities employed SGR. Today there are about 130 FGD systems of which 101 employ some form of stack gas reheat.     

Filtration of Radioactive Aerosols By Glass Fibers

Abstract

An ozone (O₃) exposure assessment study was conducted in Toronto, Ontario, Canada during the winter and summer of 1992. A new passive O₃ sampler developed by Harvard was used to measure indoor, outdoor, and personal O₃ concentrations. Measurements were taken weekly and daily during the winter and summer, respectively. Indoor samples were collected at a total of 50 homes and workplaces of study participants. Outdoor O₃ concentrations were measured both at home sites using the passive sampler and at 20 ambient monitoring sites with continuous monitors. Personal O₃ measurements were collected from 123 participants, who also completed detailed time-activity diaries. A total of 2,274 O₃ samples were collected. In addition, weekly air exchange rates of homes were measured.

This study demonstrates the performance of our O₃ sampler for exposure assessment. The data obtained are further used to examine the relationships between personal, indoor (home and workplace), and outdoor O₃ concentrations, and to investigate outdoor and indoor spatial variations in O₃ concentrations. Based on home outdoor and indoor, workplace, and ambient O₃ concentrations measured at the Ontario Ministry of the Environment (MOE) sites, the traditional microenvironmental model predicts 72% of the variability in measured personal exposures. An alternative personal O₃ exposure model based on outdoor measurements and time-activity information is able to predict the mean personal exposures in a large population, with the highest R² value of 0.41.