Effective oil removal from water by magnetically driven superhydrophobic and oleophilic magnetic titania nanotubes

Development of efficient techniques to combat the harmful effects of oil spill is an emerging field, where fabrication of new sorbents for selective removal of oil has become a hot topic for environmental scientists. The present study reports the preparation of superhydrophobic/oleophilic magnetic titania nanotubes via a facile hydrothermal method, followed by the treatment with octadecylamine, as potential magnetically driven sorbent for selective removal of oil from water surface. The magnetic nature (superparamagnetism at 300 K) of the nanotubes enabled magnetic removal of the oil-sorbed material from water surface. Wettability test of the material depicted a static water contact angle of 166 ± 1°, indicating its superhydrophobic character. Oil uptake experiments and contact angle measurements revealed its superoleophilicity with maximum oil sorption capacity >1.5 g/g for a variety of oils. In addition to the ease of magnetic removal, the nanotubes possess sufficient buoyancy, high selectivity, and quick rate of oil uptake and is more than five times reusable.     

Solar oxidation and removal of arsenic from water: An experimental study

Arsenic poses a significant threat to both human health and the environment. Arsenic removal through solar oxidation has been investigated in a batch process. Arsenic was artificially added to both deionized and tap water to conduct the experiments. Clean, colorless, transparent, Polyethylene Terephthalate (PET) bottles were used for Solar Oxidation and Removal of Arsenic (SORAS) experiments. Various parameters including concentration of arsenic, iron, and photo-catalyst were varied during the experiments. The maximum arsenic removal efficiency obtained was 94% and 88% for deionized water and tap water respectively when ferrous ammonium sulphate and lemon juice were used. Maximum efficiency of 88% and 82% was obtained for deionized and tap water respectively when locally available ferrous alum and glacial acetic acid were used. The change in volume of the photo-catalyst (lemon juice and glacial acetic acid) also did not affect the SORAS process significantly. Therefore, the recommended volume for the photo-catalyst was 1–2 ml/L. SORAS can very well be used for areas contaminated with arsenic having concentrations less than 100 μg/L.     

Ameliorating effect of N-acetylcysteine and curcumin on pesticide-induced oxidative DNA damage in human peripheral blood mononuclear cells

Endosulfan, malathion, and phosphamidon are widely used pesticides. Subchronic exposure to these contaminants commonly affects the central nervous system, immune, gastrointestinal, renal, and reproductive system. There effects have been attributed to increased oxidative stress. This study was conducted to examine the role of oxidative stress in genotoxicity following pesticide exposure using peripheral blood mononuclear cells (PBMC) in vitro. Further possible attenuation of genotoxicity was studied using N-acetylcysteine (NAC) and curcumin as known modulators of oxidative stress. Cultured mononuclear cells was isolated from peripheral blood of healthy volunteers, and exposed to varying concentrations of different pesticides: endosulfan, malathion, and phosphamidon for 6, 12, and 24 h. Lipid peroxidation was assessed by cellular malondialdehyde (MDA) level and DNA damage was quantified by measuring 8-hydroxy-2'-deoxyguanosine (8-OH-dG) using ELISA. Both MDA and 8-OH-dG were significantly increased in a dose-dependent manner following treatment with these pesticides. There was a significant decrease in MDA and 8-OH-dG levels in PBMC when co-treated with NAC or/and curcumin as compared to pesticide alone. These results indicate that pesticide-induced oxidative stress is probably responsible for the DNA damage, and NAC or curcumin attenuate this effect by counteracting the oxidative stress.     

Cold plasma technology: advanced and sustainable approach for wastewater treatment

Environmental Science and Pollution Research - Cold plasma has been a potent energy-efficient and eco-friendly advanced oxidation technology which has gained attention in recent decades as a...     

Traditional knowledge and biodiversity conservation: a case study from Byans Valley in Kailash Sacred Landscape,India

Ethnobotanical knowledge plays a significant role in plant diversity conservation and the curing of various ailments in remote rural areas of the Indian Himalayan Region (IHR). A total of 53 plant species from 27 families have been documented from the Byans valley and are used traditionally for the treatment of various diseases. Valley inhabitants have maintained a symbiotic relationship between natural resources and their cultural belief system by developing sacred forests/groves which conserve the region's plant diversity pool. Information on sacred natural sites and traditional beliefs was documented in order to understand the environmental and conservationist implications of these rules and practices. The study provides comprehensive information about eroding traditional knowledge and biodiversity conservation practices. This study could be a pilot to strengthen the conservation practices and sustainable utilization of frequently used bioresources by understanding the traditional knowledge system and conservation ethics of tribal communities in the Himalayan region.     

Quantitative Interpretation of IR Spectra and Heat Capacity Calculations for Environment friendly Polymer

Biodegradable polymers are the need of the day. Due to their natural spontaneous degradation such materials are becoming the subject of intensive research. Poly(5-hydroxylevulinic acid) (PHLA) is a biodegradable polymer obtained from biomass resources. In the present study, one dimensional isolated chain model is used for quantitative characterization of FTIR spectra by vibrational dynamics giving potential energy distribution and dispersion curves for PHLA. The predicted values of heat capacity calculated in the range 10–500 K, via density-of-states are being reported.     

Evaluation of the presence-absence (P-A) test: A simplified bacteriological test for detecting coliforms in rural drinking water of India

One thousand three-hundred and ninety-four drinking water sources comprising ground water, surface water and piped supplies were tested in order to compare the presence-absence (P-A) test with standard MPN method to detect coliforms as indicators of water quality. Out of 1394 samples, 1074 (77.04%) and 1030 (74.88%) were positive by the MPN and P-A test, respectively. The P-A test detected 96% of the positives detected by the MPN test. The P-A test may be effectively used as a rapid screening method to detect coliform contamination in less polluted sources such as ground water and piped supplies.     

Potability of water sources in relation to metal and bacterial contamination in some northern and north-eastern districts of India

A total of 1094 water samples from 326 springs, 207 streams, 183 dug wells, 151 piped supplies, 90 tube wells, 75 hand pumps, 60 rivers and 2 lakes were collected from eight northern and six north-eastern districts of India. Samples were analysed to assess their potability by estimating the level of heavy metals and bacterial (coliform and faecal coliform) contaminations. Iron was found in a maximum number (53%) of water samples from hand pumps, followed by lead in 43% of the tube wells, chromium in 16% of dug wells, cadmium in 13% of streams and manganese in 7% of hand pumps above their maximum admissible concentrations (MACs). Maximum metal pollution has been observed in a considerable number of water samples from Doda, followed by Almora, Mirzapur and Bankura. Hand pump water samples exhibited maximum metal pollution followed by dug well, spring, stream and river water samples. Contamination of coliform and/or faecal coliform bacteria ranged between 41% and 67% of water samples from open water sources but it was also less, i.e. 6–15% of water samples from tube wells and hand pumps. In general, 42–85% of water samples from districts surveyed, except from Jammu (18%) and Mirzapur (27%), were found to be bacteriologically unsatisfactory. Since toxic metals and pathogenic bacteria pose a risk to public health, monitoring of drinking water sources is required.     

Impact of Post-Methanation Distillery Effluent Irrigation on Groundwater Quality

Molasses-based distilleries generate large quantities of effluent, which is used for irrigation in many countries including India. The effluent is rich in organic and inorganic ions, which may leach down and pollute the groundwater. An on-farm experiment was conducted to assess the impact of long-term irrigation with post-methanation distillery effluent (PMDE) on nitrate, sulphate, chloride, sodium, potassium, and magnesium contents in the groundwater of two sites in northwest India. Electrical conductivity (EC), pH, total dissolved solids (TDS), sodium adsorption ratio (SAR) and colour were also determined to assess the chemical load in the groundwater. Nitrate content in the groundwater samples ranged from 16.95 mg L⁻¹ in the unamended fields to 59.81 mg L⁻¹ in the PMDE-amended fields during the 2-year study (2001–2002). Concentrations of TDS in water samples from tubewell of the amended field was higher by 40.4% over the tubewell water of the unamended field. Colour of the water samples of the amended fields was also darker than that of the unamended fields. The study indicated that the organic and inorganic ions added through the effluent could pose a serious threat to the groundwater quality if applied without proper monitoring.     

Accumulation of heavy metals in soil and paddy crop (Oryza sativa), irrigated with water of Ramgarh Lake,Gorakhpur, UP,India

Heavy metals, a highly polluting group of constituents known to exert adverse effects, tend to accumulate in living organisms. The objective of this study was to determine the accumulation and translocation of heavy metals in soil and in paddy crop irrigated with lake water compared to soil and paddy crop irrigated with bore-well water. The quantities of heavy metals (Cd, Cr, Cu, Pb, Zn, As, Mn, and Hg) were determined in different parts of rice plants (Oryza sativa). Results revealed that the mean levels of soil Cd, Cr, Pb, Zn, As, Mn, and Hg in experimental soil and in different parts of rice plant (root, straw, and grain) were higher than the control except for Cu. The content of eight toxic metals was significantly higher in root than in aerial parts of the rice (straw and grains). Rice roots were enriched in Cd, As, Hg, and Pb from the soil, while Cr, Cu, Zn, and Mn were hardly taken by the roots. Bioaccumulation factor for Hg was significantly higher than other heavy metals. Metal transfer factors from soil to rice plants were significant for Cd, Cr, Cu, Pb, Zn, As, Mn, and Hg. The concentrations of metals in lake water were found to be within the permissible limit of Indian standard prescribed by Central Pollution Control Board (2000), except for Hg and As, which were higher than the limit of Indian standard. However, the concentrations of heavy metals in soil and rice grains were still below the maximal levels, as stipulated by Indian Prevention of Food Adulteration Act (PFA, 1954) and World Health Organization (WHO, 1993) guidelines.