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241.
Enfield CG Wood AL Espinoza FP Brooks MC Annable M Rao PS 《Journal of contaminant hydrology》2005,81(1-4):125-147
Aquifer heterogeneity (structure) and NAPL distribution (architecture) are described based on tracer data. An inverse modelling approach that estimates the hydraulic structure and NAPL architecture based on a Lagrangian stochastic model where the hydraulic structure is described by one or more populations of lognormally distributed travel times and the NAPL architecture is selected from eight possible assumed distributions. Optimization of the model parameters for each tested realization is based on the minimization of the sum of the square residuals between the log of measured tracer data and model predictions for the same temporal observation. For a given NAPL architecture the error is reduced with each added population. Model selection was based on a fitness which penalized models for increasing complexity. The technique is demonstrated under a range of hydrologic and contaminant settings using data from three small field-scale tracer tests: the first implementation at an LNAPL site using a line-drive flow pattern, the second at a DNAPL site with an inverted five-spot flow pattern, and the third at the same DNAPL site using a vertical circulation flow pattern. The Lagrangian model was capable of accurately duplicating experimentally derived tracer breakthrough curves, with a correlation coefficient of 0.97 or better. Furthermore, the model estimate of the NAPL volume is similar to the estimates based on moment analysis of field data. 相似文献
242.
Shenfang Liu Linli Rao Pupu Yang Xinyi Wang Linlin Wang Rui M Limin Yue Xin Hu 《环境科学学报(英文版)》2020,32(7):109-116
In this study, N-doped porous carbons were produced with commercial phenolic resin as the raw material, urea as the nitrogen source and KOH as the activation agent. Different from conventional carbonization-nitriding-activation three-step method, a facile two-step process was explored to produce N-incorporated porous carbons. The as-obtained adsorbents hold superior CO2 uptake, i.e. 5.01 and 7.47 mmol/g at 25?°C and 0?°C under 1 bar, respectively. The synergistic effects of N species on the surface and narrow micropores of the adsorbents decide their CO2 uptake under 25?°C and atmospheric pressure. These phenolic resin-derived adsorbents also possess many extremely promising CO2 adsorption features like good recyclability, quick adsorption kinetics, modest heat of adsorption, great selectivity of CO2 over N2 and outstanding dynamic adsorption capacity. Cheap precursor, easy preparation strategy and excellent CO2 adsorption properties make these phenolic resin-derived N-doped carbonaceous adsorbents highly promising in CO2 capture. 相似文献
243.
Martha Purnachander Rao Jerry J. Wu Abdullah M. Asiri Sambandam Anandan Muthupandian Ashokkumar 《环境科学学报(英文版)》2018,30(7):115-124
CuO nanomaterials were synthesized by a simple solution phase method using cetyltrimethylammonium bromide(CTAB) as a surfactant and their photocatalytic property was determined towards the visible-light assisted degradation of Reactive Black-5 dye. A detailed mechanism for the formation of CuO nanostructures has been proposed.The effect of various experimental parameters such as catalyst amount, dye concentration,p H and oxidizing agent on the dye degradation efficiency was studied. About 87% dye was degraded at p H 2 in the presence of CuO nanosheets under visible light. The enhanced photocatalytic activity of CuO nanosheets can be ascribed to good crystallinity, grain size,surface morphology and a strong absorption in the visible region. CuO is found to be a promising catalyst for industrial waste water treatment. 相似文献
244.
Respiration as a function of oxygen concentration was studied in two species of intertidal barnacles: Balanus amphitrite amphitrite
1 (Darwin) and B. tintinnabulum tintinnabulum (L.). A critical oxygen tension was observed in both species below which the respiratory regulation broke down. In B. amphitrite amphitrite the critical oxygen tension was 2.5 ml O2/l, and in B. tintinnabulum tintinnabulum 3.5 ml O2/l. Species differences and habitat relations were observed in both species in their respiratory adaptation to oxygen concentration. B. amphitrite amphitrite which inhabits oxygen-deficient areas was able to regulate to much lower concentrations than B. tintinnabulum tintinnabulum which inhabits oxygen-rich open intertidal regions. 相似文献
245.
Mihailovic Dragutin T. Rao S. Trivikrama Hogrefe Christian Clark Richard D. 《Environmental Fluid Mechanics》2002,2(4):315-337
Experimental evidence indicates that there is a significant departure of the wind profile above the underlying surface consisting of patches of solid and liquid parts, and plant communities with different morphological from that predicted by the logarithmic relationship, which gives the values larger than those observed. This situation can seriously affect the transfer of momentum, heat and water vapor from the surface fluxes into the atmosphere.The object of this paper is to generalize the calculation of the exchange of momentum between the atmosphere and a very heterogeneous surface, find a general equation for the wind speed profile in a roughness sublayer under neutral conditions, and, then, derive aggregated roughness length and displacement height over the grid cell. The suggested expression for the wind profile is compared with some earlier approaches, using a common parameterization of aerodynamic parameters over the grid cell, and the observations obtained at an experimental site in Philadelphia, PA. 相似文献
246.
Competitive adsorption of ethylbenzene (EB) and water on bentonite and of p-xylene (pXYL) and water on kaolin and silica gel was studied using a technique that allowed the amount of adsorbed water and alkylbenzene to be measured independently. EB adsorption on bentonite was not affected by water at relative humidities (RH) near 0.23 but was reduced significantly at RH's near 0.50. pXYL adsorption on kaolin and silica gel decreased with increasing RH, especially above a RH of about 0.2. Increasing RH not only decreased the amount of alkylbenzene adsorption but also resulted in a change from Type-II adsorption isotherms to ones that were essentially linear. Linear isotherms for the adsorption of hydrophobic organic compounds on hydrated soil have generally been attributed to partitioning into organic carbon (OC). However, since the clays and oxide used here had very low to trace amounts of OC, it is suggested that processes involving only mineral surfaces can give rise to linear isotherms. Based on solubility considerations alone, partitioning of EB and pXYL into adsorbed water films was not considered to be an important adsorption mechanism in this study. The effect of cation hydration on the amount of water adsorbed from a mixture of water and pXYL vapors was evaluated by comparing adsorption on Li- and Na-saturated kaolin. 相似文献
247.
The application of a solvophobic approach for predicting the sorption of hydrophobic organic compounds (HOC) was evaluated with data collected using synthetic sorbents and soils. The experimental data consisted of batch equilibrium sorption coefficients (KD), as well as soil-TLC and reversed-phase liquid chromatographic (RPLC) retention factors (κ′). All data were collected using aqueous solutions and binary or ternary solvent mixtures of water, methanol, acetone, and acetonitrile. As predicted by the theory, the chromatographic retention factors and sorption coefficients for HOC decreased log-linearly with increasing fraction of organic cosolvent in binary solvents. Model parameters estimated from the binary solvent data could be used to predict sorption (or retention) from ternary solvents. Reasonable agreement was found between model parameters reported in the literature and those estimated using the data from batch sorption, soil-TLC, and RPLC studies. 相似文献
248.
V. Suresh M. Kanthimathi P. Thanikaivelan J. Raghava Rao B. Unni Nair 《Journal of Cleaner Production》2001,9(6):802
Severe restrictions imposed by the pollution control authorities on the disposal of chromium, total dissolved solids and chlorides in tannery effluents have forced the tanners to look for low-waste, high exhaust chrome tanning salts. An improved chrome syntan with more than 90% uptake of chrome has been developed. The new product serves both as tanning and retanning agent and can be applied directly to delimed pelts thus eliminating the conventional pickling stage in the leather processing. This modified process helps to reduce the chemical oxygen demand (COD), total dissolved solids (TDS) and chlorides in the spent tan liquor by 51, 81 and 99%, respectively. The product offers full, soft leathers having shrinkage temperature comparable to conventional chrome tanned skins. Since the developed product is highly reactive, it saves time and reduces the water requirement when compared to the conventional chrome tanning method. Thus the novel product/process developed not only has advantages in reducing pollution loads but also seems to be techno-economically viable. 相似文献
249.
R. Srikant Vasant Rao N. B. R. K. Venugopal 《Environmental monitoring and assessment》1994,33(1):71-74
Cadmium is an important contaminant of superphosphate. Market samples of superphosphate revealed a concentration of cadmium in the range of 18.2–28.5 mg/kg. Application of periodic excess doses of superphosphate in vineyards 5–35 years old has led to elevated concentrations of cadmium in the ground water in the vineyards. Ground water samples from different vineyards analysed for cadmium by atomic absorption spectrophotometry revealed concentrations of cadmium in the range of 3.2–99.2 µg/I. These concentrations of cadmium in the ground water can be regarded as significant, since ground water serves as the only source of water for the vineyards. 相似文献
250.
A procedure has been developed for the determination of ziram, zineb and ferbam dithiocarbamate pesticides by converting ziram and zineb into a zinc-phenylfluorone complex and ferbam into an iron phenylfluorone complex, which are then dissolved in water in the presence of cetylpyridinium bromide and pyridine as a surfactant. The method is sensitive, highly selective and can be used for the determination of ziram, zineb and ferbam in commercial samples and in foodstuffs. 相似文献