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排序方式: 共有578条查询结果,搜索用时 31 毫秒
181.
Fang Xu Ting-Ting Zhu Qing-Quan Rao Sheng-Wen Shui Wen-Wei Li Hong-Bo He Ri-Sheng Yao 《环境科学学报(英文版)》2017,29(3):132-140
Lignocellulosic biomass offers the most abundant renewable resource in replacing traditional fossil resources. However, it is still a major challenge to directly convert the lignin component into value-added materials. The availability of plentiful hydroxyl groups in lignin macromolecules and its unique three-dimensional structure make it an ideal precursor for mesoporous biosorbents. In this work, we reported an environmentally friendly and economically feasible method for the fabrication of mesoporous lignin-based biosorbent (MLBB) from lignocellulosic biomass through a SO3 micro-thermal-explosion process, as a byproduct of microcrystalline cellulose. BET analysis reveal the average pore-size distribution of 5.50 nm, the average pore value of 0.35 cm3/g, and the specific surface area of 186 m2/g. The physicochemical properties of MLBB were studied by fourier transform infrared spectroscopy (FTIR), attenuated-total-reflection fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), and element analysis. These results showed that there are large amounts of sulfonic functional groups existing on the surface of this biosorbent. Pb(II) was used as a model heavy-metal-ion to demonstrate the technical feasibility for heavy-metal-ion removal. Considering that lignocellulosic biomass is a naturally abundant and renewable resource and SO3 micro-thermal-explosion is a proven technique, this biosorbent can be easily produced at large scale and become a sustainable and reliable resource for wastewater treatment. 相似文献
182.
Minghui Yang Seokjoon Kwon Yordan Kostov Avraham Rasooly Govind Rao Upal Ghosh 《Environmental Chemistry Letters》2011,9(2):235-241
Single-wall carbon nanotubes (CNT) are one of the most attractive engineered nanomaterials due to their unique electrical,
mechanical and thermal properties, and potential use in a variety of commercial products. Due to their small size, CNT could
become easily airborne and reach the various environmental compartments and eventually the food chain and humans. However,
the environmental fate processes and health impacts of CNT are not clear. This study investigated a method for the quantitative
measurement of carbon nanotube (CNT) in natural media such soil and benthic organism tissues. Fluorescence dye Nile blue was
used for noncovalent labeling of CNT to enable their fluorescence detection. Labeled nanotubes were successfully detected
in soil samples as well as in worm tissue. We were also able to detect the presence of labeled carbon nanotubes in worms exposed
for 1 week to CNT-laden soil, which indicates CNT may transfer through environmental food web. The method allows for laboratory
measurements of CNT mass transfer and partitioning into various environmental systems. 相似文献
183.
Vassilios A. Tsihrintzis Hector R. Fuentes Rao K Gadipudi 《Journal of the American Water Resources Association》1996,32(2):317-331
ABSTRACT: Agricultural and urban activities in the West Wellfield Interim Protection Area (WWIPA), located in West Dade County in South Florida, have the potential to impact both the environmentally sensitive Everglades and the Biscayne Aquifer. The Hydrological Simulation Program-FORTRAN (HSPF) is used to simulate surface runoff, ground water recharge, and transport of sediments, nutrients, and pesticides in the WWIPA, as a basis to quantify impacts and evaluate alternatives. Presented are four model test runs that consider current conditions, the effect of future urbanization of the agricultural land, as well as two preventive actions to minimize pollution levels. Preventive actions include application of minimum required rates of fertilizers and replacement of fertilizers by sewage sludge. Model results show that under current practices, sediments, nutrients, and pesticides are present in surface runoff and nutrients enter the ground water, and that both urbanization and preventive actions result in pollutant reductions. 相似文献
184.
In this study, Yamaska River water and Milli-Q water and organically extracted sediment extracts were used to evaluate the sensitivity of a new genotoxicity screening test, the Mutatox test. Also in this study, the samples were tested for acute and chronic toxicity using the following screening test procedures: Microtox, Daphnia magna, Ceriodaphnia reticulata and ATP-TOX Systems. The Mutatox test is based on the use of a dark mutant strain of Photobacterium phosphoreum and is sensitive to chemicals which are (1) DNA damaging agents (2) DNA intercalating agents, (3) DNA synthesis inhibitors and (4) direct mutagens. In this study, the Mutatox test was found to be a simple-to-perform sensitive procedure which added greater scope to the battery of tests approach. Preliminary indications are that this procedure may prove to be one of the more responsive and valuable tests in the 'battery of tests' approach to environmental screening. 相似文献
185.
Ku-Fan Chen Chih-Ming Kao Chiu-Wen Chen Rao Y. Surampalli Mu-Sheng Lee 《环境科学学报(英文版)》2010,22(6):864-871
In the first phase of this study, the e ectiveness of intrinsic bioremediation on the containment of petroleum hydrocarbons was
evaluated at a gasoline spill site. Evidences of the occurrence of intrinsic bioremediation within the BTEX (benzene, toluene,
ethylbenzene, and xylenes) plume included (1) decreased BTEX concentrations; (2) depletion of dissolved oxygen (DO), nitrate,
and sulfate; (3) production of dissolved ferrous iron, methane, and CO2; (4) deceased pH and redox potential; and (5) increased
methanogens, total heterotrophs, and total anaerobes, especially within the highly contaminated areas. In the second phase of this study,
enhanced aerobic bioremediation process was applied at site to enhance the BTEX decay rates. Air was injected into the subsurface
near the mid-plume area to biostimulate the naturally occurring microorganisms for BTEX biodegradation. Field results showed that
enhanced bioremediation process caused the change of BTEX removal mechanisms from anaerobic biodegradation inside the plume
to aerobic biodegradation. This variation could be confirmed by the following field observations inside the plume due to the enhanced
aerobic bioremediation process: (1) increased in DO, CO2, redox potential, nitrate, and sulfate, (2) decreased in dissolved ferrous iron,
sulfide, and methane, (3) increased total heterotrophs and decreased total anaerobes. Field results also showed that the percentage
of total BTEX removal increased from 92% to 99%, and the calculated total BTEX first-order natural attenuation rates increased
from 0.0092% to 0.0188% per day, respectively, after the application of enhanced bioremediation system from the spill area to the
downgradient area (located approximately 300 m from the source area). 相似文献
186.
A. Datta K. S. Rao S. C. Santra T. K. Mandal T. K. Adhya 《Mitigation and Adaptation Strategies for Global Change》2011,16(5):597-615
Recent market slump in rice, less rainfall during monsoon, high temperature and scarcity of water during dry season leads
to lower grain yield and less profit from rice cultivation in India. Farmers’ grow upland crops like chickpea (Cicer arietinum), greengram (Vigna radiate), mustard (Brassica nigra), corn (Zea maize), pigeonpea (Cajanus cajan), potato (Solanum tuberosum), sunflower (Helianthus annuus) etc. along with rice (Oryza sativa) during the dry season. However, knowledge of greenhouse gas (GHG) emission from these rice based cropping systems is very
limited. In the present study four rice based cropping systems was studied along with rice-rice rotation system as control
in respect of GHG emission, yield potential and economic feasibility. Conventional plantation and fertilizer application methodology
was followed for each crop. Methane (CH4) and nitrous oxide (N2O) flux from field plots were studied with conventional closed chamber method using gas chromatograph. CH4 flux was recorded highest from rice-rice rotation plots (304.25 kg ha−1). N2O flux was recorded 1.02 kg ha−1 from rice-rice rotation system during wet season. However, during wet season, higher N2O flux (1.93 kg ha−1) was recorded from rice-potato-sesame rotation plots. Annual N2O flux was also recorded significantly low (3.42 kg ha−1) from rice-rice rotation plots and high (6.19 kg ha−1) from rice-chickpea-greengram rotation plots. Significantly lower annual grain yield was recorded from rice-rice rotation
plots (9.25 Mg ha−1) whereas it was 18.84 Mg rice eq ha−1 from rice-potato-sesame rotation system. The global warming potential (GWP) of rice-rice rotation system was recorded significantly
high (8.62 Mg CO2 ha−1) compare to plots with different rice based cropping systems. Computing all C-emission from cradle-to-grave, highest total
C-cost was recorded from the rice-rice rotation system ($62.00 ha−1). We have made an attempt to calculate the C-credit of different rice based cropping systems by considering the difference
of C-cost with control. The study suggests that the rice-potato-sesame is most sustainable among different cropping system
studied in terms of economic profit ($62.00 ha−1). We have made an attempt to calculate the C-credit of different rice based cropping systems by considering the difference
of C-cost with control. The study suggests that the rice-potato-sesame is most sustainable among different cropping system
studied in terms of economic profit (1248.21 ha−1) and C-credit ($38.60 ha−1). The result of the study may be limited to the study region; however, the study has potential use in respect to the development
of agriculture practice for adaptation to climate change. 相似文献
187.
执行《环境空气质量标准》应注意的问题 总被引:2,自引:0,他引:2
饶未欣 《石油化工环境保护》2000,(2):34-37
随着《环境空气质量标准》GB30 95- 1 996(简称新标准 )取代 GB30 95- 82 (简称旧标准 ) ,大气环境质量现状监测和影响评价工作需要作出相应的修正以适应新标准的要求 ,从实际工作出发 ,总结出了执行新标准应注意的一些问题及其解决方法。 相似文献
188.
确定卫生防护距离应注意的问题 总被引:10,自引:0,他引:10
饶示欣 《石油化工环境保护》1999,(4):42-43
本文总结了石化行业卫生防护距离标准编制和环境影响评价工作中的经验,对确定卫生防护距离时应注意的一些问题进行了探讨,并提出了一种新的确定石化装置废气无组织排放量的方法。 相似文献
189.
基于非本地物种的毒性数据推导出的水质基准一直存在争议,质疑者提出应有针对不同生物区系的水质基准。而这个问题在中国尤为突出。本文作者搜集了38种污染物对本地物种和非本地物种的毒性数据,比较了这些生物的HC5和物种敏感度分布,结果显示,基于非本地物种推导的水质基准有74%的确定性可以有效保护中国的水生态系统。如果采用评价因子(AF=5)来校正基准,那么可以获得90%的确定性。
精选自Xiaowei Jin, Zijian Wang, Yeyao Wang, Yibing Lv, Kaifeng Rao, Wei Jin, John P. Giesy and Kenneth M. Y. Leung. Do water quality criteria based on nonnative species provide appropriate protection for native species? Environmental Toxicology and Chemistry: Volume 34, Issue 8, pages 1744–1750, August 2015. DOI: 10.1002/etc.2985
详情请见http://onlinelibrary.wiley.com/doi/10.1002/etc.2985/full 相似文献
190.
The effect of sub-lethal concentrations of chlorpyrifos on protein metabolism in physiological important tissues, namely gills, kidney, liver, and muscle of the freshwater fish, Clarias batrachus, was studied. Fish were exposed to 1/20th and 1/10th of 96?h LC50 concentrations for 7, 14, 21, and 28 days. After 28 days of exposure, fish were released into fresh water and kept in the same for 21 days in order to study the recovery. Fish were sacrificed at the stipulated periods and gills, kidney, liver, and muscle tissues were used for the estimation of total protein, amino acids, ammonia, urea, glutamine, protease, transaminases, and phosphatases. Total protein, amino acid, and ammonia contents were decreased in all tissues for 28 days and recovery was observed during the recovery period. Urea and glutamine levels were elevated, except in kidneys, and recovered at the end of the recovery period. The activities of protease, alanine, and aspartate aminotransferases, and acid and alkaline phosphatases were elevated in the tissues for 28 days exposure at both concentrations. Recovery of these enzymes activities was noticed during depuration. 相似文献