全文获取类型
收费全文 | 512篇 |
免费 | 9篇 |
国内免费 | 57篇 |
专业分类
安全科学 | 7篇 |
废物处理 | 22篇 |
环保管理 | 51篇 |
综合类 | 123篇 |
基础理论 | 113篇 |
污染及防治 | 172篇 |
评价与监测 | 69篇 |
社会与环境 | 18篇 |
灾害及防治 | 3篇 |
出版年
2023年 | 4篇 |
2022年 | 10篇 |
2021年 | 13篇 |
2020年 | 14篇 |
2019年 | 9篇 |
2018年 | 9篇 |
2017年 | 19篇 |
2016年 | 23篇 |
2015年 | 14篇 |
2014年 | 23篇 |
2013年 | 62篇 |
2012年 | 11篇 |
2011年 | 20篇 |
2010年 | 25篇 |
2009年 | 23篇 |
2008年 | 23篇 |
2007年 | 25篇 |
2006年 | 23篇 |
2005年 | 23篇 |
2004年 | 18篇 |
2003年 | 13篇 |
2002年 | 19篇 |
2001年 | 21篇 |
2000年 | 11篇 |
1999年 | 9篇 |
1998年 | 3篇 |
1996年 | 5篇 |
1995年 | 9篇 |
1994年 | 6篇 |
1993年 | 7篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1979年 | 2篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1971年 | 4篇 |
1966年 | 4篇 |
1965年 | 5篇 |
1964年 | 4篇 |
1963年 | 5篇 |
1961年 | 6篇 |
1960年 | 2篇 |
1958年 | 2篇 |
1955年 | 2篇 |
排序方式: 共有578条查询结果,搜索用时 31 毫秒
71.
72.
Assessing impacts of partial mass depletion in DNAPL source zones: II. Coupling source strength functions to plume evolution 总被引:1,自引:0,他引:1
Analytical solutions, describing the time-dependent DNAPL source-zone mass and contaminant discharge rate, derived previously in Part I [Falta, R.W., Rao, P.S., Basu, N., this issue. Assessing the impacts of partial mass depletion in DNAPL source zones: I. Analytical modeling of source strength functions and plume response. J. Contam. Hydrol.] are used as a flux-boundary condition in a semi-analytical contaminant transport model. These analytical solutions assume a power relationship between the flow-averaged source concentration, and the source DNAPL mass; the empirical exponent (gamma) is a function of the flow field heterogeneity, DNAPL architecture, and the correlation between them. The DNAPL source strength terms can account for partial source remediation, either at time zero, or at some later time after the DNAPL release. The transport model considers advection, retardation, three-dimensional dispersion, and sequential first-order decay/production of several species. A separate solution is used to compute the time-dependent mass of each contaminant in the plume. A series of examples using different values of gamma shows how the benefits of partial DNAPL source remediation can vary with site conditions. In general, when gamma>1, relatively large short-term reductions in the plume concentrations and mass occur, but the source longevity is not strongly affected. Conversely, when gamma<1, the short-term reductions in the plume concentrations and mass are smaller, but the source longevity can be greatly reduced. In either case, the source remediation effort is much more effective if it is undertaken at an early time, before much contaminant mass has entered the plume. If the remediation effort is significantly delayed, the leading parts of the plume are not affected by the source remediation, and additional control or remediation of the plume itself is required. 相似文献
73.
74.
Remediation schemes for contaminated sites are often evaluated to assess their potential for source zone reduction of mass, or treatment of the contaminant between the source and a control plane (CP) to achieve regulatory limits. In this study, we utilize a stochastic stream tube model to explain the behavior of breakthrough curves (BTCs) across a CP. At the local scale, mass dissolution at the source is combined with an advection model with first-order decay for the dissolved plume. Field-scale averaging is then employed to account for spatial variation in mass within the source zone, and variation in the velocity field. Under the assumption of instantaneous mass transfer from the source to the moving liquid, semi-analytical expressions for the BTC and temporal moments are developed, followed by derivation of expressions for effective velocity, dispersion, and degradation coefficients using the method of moments. It is found that degradation strongly influences the behavior of moments and the effective parameters. While increased heterogeneity in the velocity field results in increased dispersion, degradation causes the center of mass of the plume to shift to earlier times, and reduces the dispersion of the BTC by lowering the concentrations in the tail. Modified definitions of effective parameters are presented for degrading solutes to account for the normalization constant (zeroth moment) that keeps changing with time or distance to the CP. It is shown that anomalous dispersion can result for high degradation rates combined with wide variation in velocity fluctuations. Implications of model results on estimating cleanup times and fulfillment of regulatory limits are discussed. Relating mass removal at the source to flux reductions past a control plane is confounded by many factors. Increased heterogeneity in velocity fields causes mass fluxes past a control plane to persist, however, aggressive remediation between the source and CP can reduce these fluxes. 相似文献
75.
应用重组孕激素基因酵母测定饮用水中内分泌干扰物的方法 总被引:6,自引:0,他引:6
研究了用重组孕激素受体基因酵母测定饮用水中内分泌干扰物的方法,并利用该种方法检测了南方某水厂不同处理工艺过程水样对孕激素受体活性的抑制水平.结果表明,重组孕激素受体基因酵母能够与孕激素专一性的结合,诱导产生明显的剂量-效应关系,EC50值为0.5 nmol/L,具有较高灵敏度;环境内分泌干扰物五氯酚和壬基酚具有孕激素受体抑制活性,其IC50值分别为2.4μmol/L和3.7μmol/L;重组孕激素受体基因/报道基因的酵母技术是一种筛选和定量分析具有孕激素受体抑制活性的内分泌干扰物的快速、有效方法.结合固相萃取的前处理技术,重组孕激素受体基因酵母对水厂不同处理工艺水样检测出明显的孕激素受体抑制活性,抑制率均大于58%,表明重组孕激素受体基因酵母检测技术能够快速监测和鉴别水样中具有抑制孕激素受体活性的物质. 相似文献
76.
Wang Shulian Jiao Yiying Rao Zhi 《Environmental science and pollution research international》2021,28(23):28865-28875
Environmental Science and Pollution Research - The development of cyanobacterial blooms can have adverse effects on water bodies and may produce cyanotoxins. Several physical and chemical methods... 相似文献
77.
78.
Edith Gego Christian Hogrefe George Kallos Antigoni Voudouri John S. Irwin S. Trivikrama Rao 《Environmental Fluid Mechanics》2005,5(1-2):63-85
While fluctuations in meteorological and air quality variables occur on a continuum of spatial scales, the horizontal grid spacing of coupled meteorological and photochemical models sets a lower limit on the spatial scales that they can resolve. However, both computational costs and data requirements increase significantly with increasing grid resolution. Therefore, it is important to examine, for any given application, whether the expected benefit of increased grid resolution justifies the extra costs. In this study, we examine temperature and ozone observations and model predictions for three high ozone episodes that occurred over the northeastern United States during the summer of 1995. In the first set of simulations, the meteorological model RAMS4a was run with three two-way nested grids of 108/36/12 km grid spacing covering the United States and the photochemical model UAM-V was run with two grids of 36/12 km grid spacing covering the eastern United States. In the second set of simulations, RAMS4a was run with four two-way nested grids of 108/36/12/4 km grid spacing and UAM-V was run with three grids of 36/12/4 km grid spacing with the finest resolution covering the northeastern United States. Our analysis focuses on the comparison of model predictions for the finest grid domain of the simulations, namely, the region overlapping the 12 km and 4 km domains. A comparison of 12 km versus 4 km fields shows that the increased grid resolution leads to finer texture in the model predictions; however, comparisons of model predictions with observations do not reveal the expected improvement in the predictions. While high-resolution modeling has scientific merit and potential uses, the currently available monitoring networks, in conjunction with the scarceness of highly resolved spatial input data and the limitations of model formulation, do not allow confirmation of the expected superiority of the high-resolution model predictions.The U.S. Governments right to retain a non-exclusive royalty-free licence in and to any copyright is acknowledged. 相似文献
79.
G. Madan Mohan Rao 《Marine Biology》1971,9(3):205-212
Two types of secretory cell have been found in the cement glands of the cypris larva of Balanus balanoides (L.). Histochemical tests show the presence of proteins, phenols and the enzyme polyphenol oxidase in both the glands and secreted cement. It is proposed that cyprid cement is composed of tanned protein, all the components of which are derived from the cement glands. 相似文献
80.
Tilak KS Veeraiah K Sastry LV Rao JV 《Journal of environmental biology / Academy of Environmental Biology, India》2003,24(4):445-448
Indian bullfrog Haplobatrachus tigerinus (Daudin) was exposed to sublethal dose (1/3 of LC50 I.E. 1.166 mg/kg) of fenvalerate technical grade and the effect was studied on the specific activity of acetyl cholinesterase in the different tissues of frog viz., brain, muscle, liver, kidney and testis at different time periods viz., 3,6, 12, 24, 48 and 72 hours. The inhibition of specific activity of acetyl cholinesterase was in the order of kidney > brain > muscle > liver > testis. A significant inhibition was noticed in kidney at 12 hours (-64.33%) and no effect was noticed at 3 hours in testis (+0.67%). The AChE activity was inhibited in first three hours of administration of fenvalerate in all the tissue tested. The inhibition continued upto 6 hours or 2 hours in different tissue but the recovery was started by 24 hours and almost completed by 72 hours. 相似文献