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21.
22.
Aim of the present study was to synthesize titanium dioxide nanoparticles (YiO2 NPs) from marine actinobacteria and to develop an eco-friendly azo-dye degradation method. A total of five actinobacterial isolates were isolated from Chennai marine sediments, Tamilnadu, India and analyzed for the synthesis of TiO2 NPs using titanium hydroxide. Among these, the isolate PSV 3 showed positive results for the synthesis of TiO2 NPs, which was confirmed by UV analysis. Further characterization of the synthesized TiO2 NPs was done using XRD, AFM and FI'-IR analysis. Actinobacterial crude extract and synthesized TiO2 NPs was found efficient in degrading azo dye such as Acid Red 79 (AR-79) and Acid Red 80 (AR-80). Degradation percentage was found to be 81% for AR-79, 83% for AR-80 using actinobacterial crude extract and 84% for AR-79, 85% for AR-80 using TiO2 NPs. Immobilized actinobacterial ceils showed 88% for AR-79 and 81% for AR- 80, dye degrading capacity. Degraded components were characterized by FT-IR and GC-MS analysis. The phytotoxicity test with 500 μg/mL of untreated dye showed remarkable phenotypic as well as cellular damage to Tagetes erecta plant. Comparatively no such damage was observed on plants by degraded dye components. In biotoxicity assay, treated dyes showed less toxic effect as compared to the untreated dyes. 相似文献
23.
Rao PS Ansari MF Gavane AG Pandit VI Nema P Devotta S 《Environmental monitoring and assessment》2007,128(1-3):323-328
Petroleum refineries are largest chemical industries that are responsible for the emission of several pollutants into the
atmosphere. Benzene is among the most important air pollutants that are emitted by petroleum refineries, since they are involved
in almost every refinery process. Volatile organic compounds (VOCs) are a major group of air pollutants, which play a critical
role in atmospheric chemistry. These contribute to toxic oxidants, which are harmful to ecosystem, human health and atmosphere.
The variability of pollutants is an important factor in determining human exposure to these chemicals. The ambient air concentrations
of benzene were measured in several sites around the Digboi petroleum refinery, near the city of Gowahati in northeast India,
during winter and summer 2004. The seasonal and spatial variations of the ambient air concentrations of this benzene were
investigated and analyzed. An estimation of the contribution of the refinery to the measured atmospheric levels of benzene
was also performed. The ambient air mixing ratios of benzene in a large area outside the refinery was generally low, in ppbv
range, much lower than the ambient air quality standards. This article presents the temporal and spatial variation of air
pollution in and around petroleum refinery and showed that no health risk due to benzene is present in the areas adjacent
to the refinery. 相似文献
24.
Real time remote monitoring of air pollutants and their online transmission to the web using internet protocol 总被引:1,自引:0,他引:1
Anjaneyulu Y Jayakumar I Bindu VH Rao PV Sagareswar G Ramani KV Rao TH 《Environmental monitoring and assessment》2007,124(1-3):371-381
Recent advances in both information and sensor technologies have enabled the development of Real Time Remote Monitoring (RTRM)
capabilities for environmental management. An online and real time remote monitoring system for air pollution has been designed
and installed at a traffic police station at Punjagutta in Hyderabad, India. The system is optimized using electrochemical
sensors and a real time particulate matter analyzer. The system also monitors meteorological parameters such as temperature,
humidity, rainfall, barometric pressure, wind speed and wind direction. The system periodically monitors both pollution and
meteorological parameters at pre- programmed intervals of hr during peak periods and 1 hr during non peak periods of the day and continuously uploads to a predestinated web site (www.appcb.org/home.htm)
using File Transfer Protocol. The web site renders a quick, simple and graphical display of air pollution levels and meteorological
parameters and their significance to humans. The present paper highlights design considerations of a pollution monitoring
system, system hardware and software requirements and practical limitations and future directions for real time remote monitoring
of air pollution. 相似文献
25.
Serum profiles of PCDDs and PCDFs, in individuals near the Escambia Wood Treating Company Superfund site in Pensacola, FL 总被引:3,自引:0,他引:3
The Escambia Wood Treating Company (ETC) Superfund site, Pensacola, FL, is contaminated with polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/F), benzo(a)pyrene, lead and arsenic from pentachlorophenol (PCP), creosote, and other compounds used to treat utility poles and foundation pilings. Although ETC's operations ceased in 1982, soils in the areas surrounding the facility continue to exhibit elevated levels of contaminants attributable to ETC operations. In July 2000, individuals who may have been affected by contamination from the ETC site, including current and former residents and former workers and their household members were invited to participate in a study, which included a health and exposure history and routine blood analysis. We also conducted a toxicological health evaluation of a subset of these eligible workers/residents by analyzing serum levels of 17 PCDD/F congeners. Members of the ETC cohort exhibited elevated serum PCDD/F relative to the general population, and congener profiles in members of the cohort reflected patterns commonly observed in persons exposed to PCP. Hypertension prevalence in the cohort was found to correlate with PCDD/F levels, although no other significant relationships were identified with monitored health indices. 相似文献
26.
Based on the data of 30 Chinese provinces for the period from 2004 to 2015, this paper expounds the carbon emissions effect of two-way foreign direct investment (FDI) from the perspective of scale effect and factor market distortions. This study uses Kaya identity to decompose carbon emission and construct simultaneous equations model to empirically examine the factor market distortion and the carbon emission scale effect of two-way FDI. The results show that the inward foreign direct investment (IFDI) increase regional carbon emission through scale effect and also exacerbates factor market distortion in China, whereas the outward FDI trends reduce carbon emission and reduces factor market distortions in China. The study also shows that human capital, research and development (R&D), trade openness, and capital accumulation are important determinants of two-way FDI. Therefore, the study proposes that IFDI policies should focus on acquiring green technologies. In addition, the domestic enterprises should be encouraged to participate in global business. 相似文献
27.
印染RO浓水深度处理及回用 总被引:2,自引:0,他引:2
采用Fenton-石灰苏打法耦合工艺对某印染厂印染反渗透(RO)浓水进行深度处理。通过实验研究了不同H2O2和Fe2+投加量、p H和反应时间对废水COD去除率的影响,以及不同石灰和碳酸钠投加量对废水硬度的脱除效果,出水回用于染色工段进行染色实验。结果表明,在p H=3.0,Fe2+投加量为1.5 mmol/L,H2O2投加量为3.75 mmol/L,反应时间为45 min,石灰和碳酸钠投加量分别为450 mg/L和1 000 mg/L的条件下,出水COD和硬度的去除率可分别达到73.9%和85.0%,耦合工艺出水水质符合该厂回用染色水标准,且减少了盐的使用,可实现印染RO浓水回用。 相似文献
28.
本研究利用红外光谱(FTIR)、扫描电镜(SEM)和X射线粉末衍射(XRD)观察了共沉淀法合成羟基磷灰石(HAP)的形貌及其晶型结构,并探讨了Ca/P摩尔比、反应时间及反应温度等因素对羟基磷灰石吸附水中氟离子性能的影响。结果表明,n(Ca/P)=1.5/1、反应时间1 h、反应温度40℃、陈化时间48 h、煅烧温度200℃、煅烧时间2 h时,HAP除氟效果最佳,吸附效率和吸附容量分别达到68.8%和6.88 mg/g。实验数据Langmuir等温模式拟合效果优于Freundlich模式,热力学参数计算可知,HAP对氟离子的吸附是自发(ΔG00),吸热(ΔH00),熵增(ΔS00)的过程。HAP对氟离子的吸附符合拟二级反应动力学过程。 相似文献
29.
Keith Worrall Anthony Newton Clive Robinson Ramesh Rao 《环境化学》2006,25(5):661-663
"二噁英"是指一类化学结构和生物特征均有某些相似之处的化合物.这些有毒化合物有几百种,可分为相关的三大类:氯代二苯并-对-二噁英(CDDs),氯代二苯并呋喃(CDFs)和某些多氯代联苯(PCBs).CDDs和CDFs并非与生具有,而是由于人类活动不注意而生成的.天然过程也会产生CDDs和CDFs. 相似文献
30.
Khan Fahad Saleem Ahmed Mubarak Nabisab Mujawar Tan Yie Hua Karri Rama Rao Khalid Mohammad Walvekar Rashmi Abdullah Ezzat Chan Mazari Shaukat Ali Nizamuddin Sabzoi 《Environmental science and pollution research international》2020,27(35):43526-43541
Environmental Science and Pollution Research - Substantial discharge of hazardous substances, especially dyes and heavy metal ions to the environment, has become a global concern due to... 相似文献