Nitro-PAH formation studied by interacting artificially PAH-coated soot aerosol with NO2 in the temperature range of 295–523 K

Diesel particulate matter poses a threat to human health, and in particular nitrated polycyclic aromatic hydrocarbons (NPAHs) found within and on the surface of these particles. Although diesel particulate filters (DPFs) have been designed and implemented to reduce these and other harmful diesel emissions, the particle loaded filters may act as a reaction chamber for the enhanced production of NPAHs from the nitration of PAHs with NO₂.Focus is on the investigation of the heterogeneous reactions that occur on soot particles by exposing laboratory produced pyrene- or benzo(a)pyrene-coated spark discharge soot particles to varying concentrations of NO₂ and temperatures while following the formation of products over time. The sole nitration product that was observed throughout the experiments with pyrene-coated soot was 1-nitropyrene (1-NPYR), which increased linearly with reaction time for all NO₂ concentrations chosen (0.11, 1.0, 2.0, 4.0 ppm, m m^?1). Resulting 1-NPYR formation rate increased exponentially with [NO₂]. Throughout the 3-h experiments less than 10% of pyrene has been converted to 1-NPYR and the partial reaction order with regard to [NO₂] was estimated to 1.52. Benzo(a)pyrene (BaP) was more reactive than pyrene. After 3 h reaction time almost 80% of the BaP has been converted to 6-NBaP.Highest 1-NPYR concentrations on particles were detected at 373 K, and at higher temperatures a considerable decrease in particulate 1-NPYR was observed. A similar trend was observed in a DPF simulation system (PM-Kat^®-like) with BaP-coated soot. In this case, highest 6-NBaP concentration on particles was detected at 423 K. Backed by corroborating results from separate gas/solid-phase partition experiments with 1-NPYR and 6-NBaP, it is likely that the newly formed 1-NPYR and 6-NBaP became transferred from particle to gas phase at higher temperatures. Results from this study confirm the presence of 1-NPYR and 6-NBaP in particulate and gas phase under conditions encountered in DPFs, especially when operated at low temperature situations of the aftertreatment system.     

Assessing inter-laboratory comparability and limits of determination for the analysis of cyclic volatile methyl siloxanes in whole Rainbow Trout (Oncorhynchus mykiss)

Cyclic volatile methyl siloxanes (cVMS) are high volume production chemicals used in a wide range of industrial and consumer products. Three cVMS compounds (D4, D5, and D6) have and are undergoing environmental risk evaluations in several countries and have been proposed for legal regulation in Canada. As interest in monitoring concentrations of these chemicals in the environment increase, there is a need to evaluate the analytical procedures for cVMS in biological matrices in order to assess the quality of data produced. The purpose of this study was to determine laboratory testing performance for measuring residues of D4, D5, and D6 in a standard set of fish homogenate samples and to estimate limits of determination for each substance. The samples sent to each laboratory consisted of homogenized whole body tissues of hatchery raised rainbow trout which were fed food fortified with D4, D5, and D6 (dosed) and trout that were fed standard food rations (control). The participants analyzed each sample using their analytical method of choice using their own standards and procedures for quantification and quality control. With a few exceptions, participating laboratories generated comparable results for D4, D5, and D6 in both the dosed and control samples having z-scores between 2 and −2. Method detection limits for the whole fish matrix were on average 2.4 ng g⁻¹ ww for D4, 2.3 ng g⁻¹ ww for D5, and 1.8 ng g⁻¹ ww for D6.     

DETECTION OF FRESH WATER AQUIFERS IN THE GLACIAL DEPOSITS OF NORTHWESTERN MISSOURI BY GEOELECTRICAL METHODS1

Geoelectrical investigations in Grundy County of northwestern Missouri, where the groundwater resources of the glacial deposits have already been examined through an extensive drilling program by the Missouri Geological Survey and Water Resources, indicate that water-bearing gravel deposits can be distinguished from glacial deposits containing appreciable amounts of clay and limited amounts of water. The Schlumberger method used for the geoelectric depth soundings in the vicinity of the Survey's drillholes demonstrates the exploratory usefulness of the method in that it can partly replace the more expensive procedure of drilling. The method also provides improved interpretation between drillholes. Results of the investigation show that, in the area, clay has a resistivity below 20in, that the fresh water-bearing gravel at the bottom of the buried glacial stream channels has a resisitivity of 40 to 50fim, and that the near surface glacial gravel deposits have a resistivity above lOOfim. Interpretation of the depth soundings and the conductivity of water obtained from a local well implies that its water is drawn from the saline water of the bedrock. A recommendation is made for the quality improvement of this particular well.     

Disaster safety nets for developing countries: Extending public–private partnerships

In developed countries, public–private partnerships involving insurance companies and governments often provide security against the human and economic losses of disasters. These partnerships, however, are neither available nor affordable in most highly exposed developing countries. In this paper we examine recent innovations in financial risk management that extend traditional public–private partnerships to include NGOs, international financial institutions and other donors. Importantly, these partnerships provide secure financial arrangements to low-income communities before disasters strike and thus relieve the uncertainty and anxiety of depending on ad hoc post-disaster aid for recovery and even survival. We examine three examples of extended partnerships: the Turkish Catastrophe Insurance Pool; the Andhra Pradesh microinsurance program and an index-based weather derivative for farmers facing drought in Malawi.     

THE DEPENDENCE OF THE RESIDUAL GRAVITY ON HYDRAULIC CONSTANTS IN GLACIAL DEPOSITS1

ABSTRACT: Buried glacial stream channels contain large and easily accessible groundwater resources. Gravity surveys have been frequently applied for their location. A gravity survey in the geohydrologically explored Wood River Valley Area of southern Rhode Island shows extreme lows of -2 mgals over channel depths of maximal 300 feet. Three gravity profiles were observed in east-west direction across a north-south striking stream channel. The bedrock depth increases rapidly towards the south from 130 to 300 feet. The gravity lows observed across each profile are not related to the bedrock depth but rather to the saturated thickness of the main quifer and its hydraulic transmissivity. Well logs indicate that the large change of bedrock depth is solely due to an increase of till of low permeability. The volume of the glacial outwash, which is the major groundwater resource, changes little underneath the three profiles. The gravity lows apear to be directly related to the density contrast between glacial outwash and till. The response to the hydraulically more pertinent units renews the interest in the gravity method as it may have a potential to estimate yields of hydrologically complex aquifers