Mapping the organic carbon stocks of surface soils using local spatial interpolator

The largest uncertainties are associated with estimating the soil organic carbon (SOC) stock because of natural soil variability and data scarcity. Thus, a local spatial geostatistical hybrid approach, the geographically weighted regression kriging (GWRK), was used in the present study to overcome some of these uncertainties. This study was designed to estimate the SOC stock (kg C m(-2)) for the surface 0 to 15 cm depth using the state of Pennsylvania as the study region. A total of 920 soil profiles were extracted from the National Soil Survey Center database and were divided into calibration (80%) and validation (20%) periods. Some soil parameters that include clay content, bulk density (ρ(b)), total nitrogen (TN) content, pH, Ca(2+), Na(+), extractable acidity (EXACID), and cation exchange capacity (CEC) were used as covariates for estimating the SOC stock. These covariates exhibited spatial autocorrelation (Moran's Index, I = 0.62 to 0.89). Further, residuals of geographically weighted regression were spatially autocorrelated, and hence support the use of the GWRK approach. Validation results concluded that the performance of the GWRK approach was the best with the lowest values of root mean square error, mean estimation error and mean absolute estimation error. The estimated SOC stock for the surface 0 to 15 cm depth ranged from 1.41 to 3.94 kg m(-2). Results from this study show that the GWRK captures spatial dependent relationships, and addresses spatial non-stationarity issues, hence this approach improves the estimations of SOC stock.     

Surveying drainage culvert use by carnivores: sampling design and cost�Cbenefit analyzes of track-pads vs. video-surveillance methods

Environmental assessment studies often evaluate the effectiveness of drainage culverts as habitat linkages for species, however, the efficiency of the sampling designs and the survey methods are not known. Our main goal was to estimate the most cost-effective monitoring method for sampling carnivore culvert using track-pads and video-surveillance. We estimated the most efficient (lower costs and high detection success) interval between visits (days) when using track-pads and also determined the advantages of using each method. In 2006, we selected two highways in southern Portugal and sampled 15 culverts over two 10-day sampling periods (spring and summer). Using the track-pad method, 90% of the animal tracks were detected using a 2-day interval between visits. We recorded a higher number of crossings for most species using video-surveillance (n = 129) when compared with the track-pad technique (n = 102); however, the detection ability using the video-surveillance method varied with type of structure and species. More crossings were detected in circular culverts (1 m and 1.5 m diameter) than in box culverts (2 m to 4 m width), likely because video cameras had a reduced vision coverage area. On the other hand, carnivore species with small feet such as the common genet Genetta genetta were detected less often using the track-pad surveying method. The cost-benefit analyzes shows that the track-pad technique is the most appropriate technique, but video-surveillance allows year-round surveys as well as the behavior response analyzes of species using crossing structures.     

Dietary exposure of three passerine species to PCDD/DFs from the Chippewa, Tittabawassee, and Saginaw River floodplains, Midland, Michigan, USA

Dietary exposure of house wrens (Troglodytes aedon), tree swallows (Tachycineta bicolor), and eastern bluebirds (Sialia sialis) to polychlorinated dibenzofurans (PCDFs) and polychlorinated dibenzo-p-dioxins (PCDDs) near Midland, Michigan (USA) was evaluated based on site-specific data, including concentrations of residues in bolus samples and individual invertebrate orders and dietary compositions by study species. Site-specific dietary compositions for the three species were similar to those reported in the literature, but differed in their relative proportions of some dietary items. Oligocheata (non-depurated) and Brachycera (Diptera) contained the greatest average concentrations of ??PCDD/DFs of the major site-specific dietary items collected via food web-based sampling. Average ingestion values of ??PCDD/DFs from site-specific bolus-based and food web-based dietary concentrations for nestlings at study areas (SAs) were 6- to 20-fold and 2- to 9-fold greater than at proximally located reference areas (RAs), respectively. Average ingestion values of total 2,3,7,8-tetrachlorodibenzo-p-dioxin equivalents (TEQ_WHO???Avian) from site-specific bolus-based and food web-based dietary concentrations for nestlings at SAs were 31- to 121-fold and 9- to 64-fold greater than at proximally located RAs, respectively. Estimates of ??PCDD/DFs and TEQ_WHO???Avian tissue concentrations based on nestling dietary exposures were greater than those measured. Plausible explanations include nestling metabolism of 2,3,7,8-tetrachlorodibenzofuran and assimilation rates of less than the 70% assumed to occur over the nestling growth period. Profiles of the relative concentrations of individual PCDD/DF congeners in samples of invertebrates and bolus at SAs on the Tittabawassee River downstream of the source of contamination were dominated by 1,2,3,4,6,7,8,9-octachlorodibenzo-p-dioxin (22% to 44%) and 2,3,7,8-tetrachlorodibenzofuran (18% to 50%).     

Multi-route risk assessment from trihalomethanes in drinking water supplies

The USA is entering an era of energy diversity, and increasing nuclear capacity and concerns focus on accidents, security, waste, and pollution. Physical buffers that separate outsiders from nuclear facilities often support important natural ecosystems but may contain contaminants. The US Nuclear Regulatory Commission (NRC) licenses nuclear reactors; the applicant provides environmental assessments that serve as the basis for Environmental Impact Statements developed by NRC. We provide a template for the types of information needed for safe siting of nuclear facilities with buffers in three categories: ecological, fate and transport, and human health information that can be used for risk evaluations. Each item on the lists is an indicator for evaluation, and individual indicators can be selected for specific region. Ecological information needs include biodiversity (species, populations, communities) and structure and functioning of ecosystems, habitats, and landscapes, in addition to common, abundant, and unique species and endangered and rare ones. The key variables of fate and transport are sources of release for radionuclides and other chemicals, nature of releases (atmospheric vapors, subsurface liquids), features, and properties of environmental media (wind speed, direction and atmospheric stability, hydraulic gradient, hydraulic conductivity, groundwater chemistry). Human health aspects include receptor populations (demography, density, dispersion, and distance), potential pathways (drinking water sources, gardening, fishing), and exposure opportunities (lifestyle activities). For each of the three types of information needs, we expect that only a few of the indicators will be applicable to a particular site and that stakeholders should agree on a site-specific suite.     

Potential use of Caulerpa fastigiata biomass for removal of lead: kinetics, isotherms, thermodynamic, and characterization studies

The present study attempts to analyze the biosorption trend of biosorbent Caulerpa fastigiata (macroalgae) biomass for removal of toxic heavy metal ion Pb (II) from solution as a function of initial metal ion concentration, pH, temperature, sorbent dosage, and biomass particle size. The sorption data fitted with various isotherm models and Freundlich model was the best one with correlation coefficient of 0.999. Kinetic study results revealed that the sorption data on Pb (II) with correlation coefficient of 0.999 can best be represented by pseudo-second-order. The biosorption capacity (q _e ) of Pb (II) is 16.11?±?0.32 mg g^?1 on C. fastigiata biomass. Thermodynamic studies showed that the process is exothermic (ΔH° negative). Free energy change (ΔG°) with negative sign reflected the feasibility and spontaneous nature of the process. The SEM studies showed Pb (II) biosorption on selective grains of the biosorbent. The FTIR spectra indicated bands corresponding to –OH, COO^?, –CH, C?=?C, C?=?S, and –C–C– groups were involved in the biosorption process. The XRD pattern of the C. fastigiata was found to be mostly amorphous in nature.     

Solubilization of municipal sewage waste activated sludge by novel lytic bacterial strains

Extracellular polymeric substances (EPS) are an extracellular matrix found in sludge which plays a crucial role in flocculation by interacting with the organic solids. Therefore, to enhance pretreatment of sludge, EPS have to be removed. In this study, EPS were removed with a chemical extractant, NaOH, to enhance the bacterial pretreatment. A lysozyme secreting bacterial consortium was isolated from the waste activated sludge (WAS). The result of density gradient gel electrophoresis (DGGE) analysis revealed that the isolated consortium consists of two strains. The two novel strains isolated were named as Jerish03 (NCBI accession number KC597266) and Jerish 04 (NCBI accession number KC597267) and they belong to the genus Bacillus. Pretreatment with these novel strains enhances the efficiency of the aerobic digestion of sludge. Sludge treated with the lysozyme secreting bacterial consortium produced 29 % and 28.5 % increase in suspended solids (SS) reduction and chemical oxygen demand (COD) removal compared to the raw activated sludge (without pretreatment) during aerobic digestion. It is specified that these two novel strains had a high potential to enhance WAS degradation efficiency in aerobic digestion.     

Field performance evaluation during fog-dominated wintertime of a newly developed denuder-equipped PM1 sampler

This study presents the performance evaluation of a novel denuder-equipped PM₁ (particles having aerodynamic diameter less than 1 μm) sampler, tested during fog-dominated wintertime, in the city of Kanpur, India. One PM₁ sampler and one denuder-equipped PM₁ sampler were co-located to collect ambient PM₁ for 25 days. The mean PM₁ mass concentration measured on foggy days with the PM₁ sampler and the denuder-equipped PM₁ sampler was found to be 165.95 and 135.48 μg/m³, respectively. The mean PM₁ mass concentration measured on clear days with the PM₁ sampler and the denuder-equipped PM₁ sampler was observed to be 159.66 and 125.14 μg/m³, respectively. The mass concentration with denuder-fitted PM₁ sampler for both foggy and clear days was always found less than the PM₁ sampler. The same drift was observed in the concentrations of water-soluble ions and water-soluble organic carbon (WSOC). Moreover, it was observed that the use of denuder leads to a significant reduction in the PM positive artifact. The difference in the concentration of chemical species obtained by two samplers indicates that the PM₁ sampler without denuder had overestimated the concentrations of chemical species in a worst-case scenario by almost 40 %. Denuder-fitted PM₁ sampler can serve as a useful sampling tool in estimating the true values for nitrate, ammonium, potassium, sodium and WSOC present in the ambient PM.     

The role of precursor gases and meteorology on temporal evolution of O3 at a tropical location in northeast India

South Asia, particularly the Indo-Gangetic Plains and foothills of the Himalayas, has been found to be a major source of pollutant gases and particles affecting the regional as well as the global climate. Inventories of greenhouse gases for the South Asian region, particularly the sub-Himalayan region, have been inadequate. Hence, measurements of the gases are important from effective characterization of the gases and their climate effects. The diurnal, seasonal, and annual variation of surface level O₃ measured for the first time in northeast India at Dibrugarh (27.4° N, 94.9° E, 111 m amsl), a sub-Himalayan location in the Brahmaputra basin, from November 2009 to May 2013 is presented. The effect of the precursor gases NO _x and CO measured simultaneously during January 2012–May 2013 and the prevailing meteorology on the growth and decay of O₃ has been studied. The O₃ concentration starts to increase gradually after sunrise attaining a peak level around 1500 hours LT and then decreases from evening till sunrise next day. The highest and lowest monthly maximum concentration of O₃ is observed in March (42.9?±?10.3 ppb) and July (17.3?±?7.0 ppb), respectively. The peak in O₃ concentration is preceded by the peaks in NO _x and CO concentrations which maximize during the period November to March with peak values of 25.2?±?21.0 ppb and 1.0?±?0.4 ppm, respectively, in January. Significant nonlinear correlation is observed between O₃ and NO, NO₂, and CO. National Atmospheric and Oceanic Administration Hybrid Single-Particle Lagrangian Integrated Trajectory back-trajectory and concentration weighted trajectory analysis carried out to delineate the possible airmass trajectory and to identify the potential source region of NO _x and O₃ concentrations show that in post-monsoon and winter, majority of the trajectories are confined locally while in pre-monsoon and monsoon, these are originated at the Indo-Gangetic plains, Bangladesh, and Bay of Bengal.     

Extractive Spectrofluorometric Determination of Quinalphos Using Fluorescein in Environmental Samples

A simple, sensitive, convenient and low cost spectrofluorometric technique for determination of quinalphos is described. Quinalphos is decomposed with sodium ethoxide. Resultant sodium diethyl thiophosphate (Na-DETP) is extracted with a cationic fluorescein as ion pair complex into 1-chloro-2-nitrobenzene. The fluorescence of the ion pair, fluorescein-DETP is measured at 530 nm after excitation at 490 nm. This technique is applicable for the determination of quinalphos in water, food grains and vegetable samples up to ng level with Amberlite XAD-4.     

Air Pollution and Heat Exposure Study in the Workplace in a Glass Manufacturing Unit in India

Air pollution in the workplace environment due to industrial operation have been found to cause serious occupational health hazard. Similarly, heat stress is still most neglected occupational hazard in the tropical and subtropical countries like India. The hot climate augments the heat exposure close to sources like furnaces. In this study an attempt is made to assess air pollution and heat exposure levels to workers in the workplace environment in glass manufacturing unit located in the State of Gujarat, India. Samples for workplace air quality were collected for SPM, SO₂, NO₂ and CO₂ at eight locations. Results of workplace air quality showed 8-hourly average concentrations of SPM: 165–9118 μg/m³, SO₂: 6–9 μg/m³ and NO₂: 5–42 μg/m³, which were below the threshold limit values of workplace environment. The level of CO₂ in workplace air of the plant was found to be in the range 827–2886 μg/m³, which was below TLV but much higher than the normal concentration for CO₂ in the air (585 mg/m³). Indoor heat exposure was studied near the furnace and at various locations in an industrial complex for glass manufacturing. The heat exposure parameters including the air temperature, the wet bulb temperature, and the globe parameters were measured. The Wet Bulb Globe Temperature (WBGT), an indicator of heat, exceeded ACGIH TLVs limits most of the time at all the locations in workplace areas. The recommended duration of work and rest have also been estimated.