Soil heterogeneity effects on acid flushing of lead-contaminated soil

A compact model for evaluation of acid flushing of heavy-metal-contaminated soil in a small-scale on-site treatment plant is proposed. The model assumes that the soil was re-packed in a container after excavation resulting in a soil structure with heterogeneous and random physical and chemical properties. To evaluate the effects of heterogeneity on the efficiency of contaminant removal by acid flushing, a numerical analysis of lead transport in the heterogeneous soil medium was performed. The model examines cation exchange and surface complexation reactions involving three cations (Ca, Pb, and H) and one anion (Cl) in both dissolved and exchangeable forms, two Pb surface complexes (SOPbCl and SOPbOH), and one Cl surface complex (SOH₂Cl). The transport of these species during flushing with acid in a synthetically generated two-dimensional heterogeneous soil was simulated in the model. Results indicated that the flushing fluid preferentially followed pathways with large permeability. The heterogeneous cation exchange capacity (CEC) distribution and surface complexation sites had a significant effect on the transport of dissolved species. Because the CEC was set to a relatively low value, Pb was adsorbed mainly as surface complexes (SOPbCl and SOPbOH). Simulation results suggest that blocks of low hydraulic conductivity located in the upper part of the model domain greatly impede solute transport. Ponding conditions did not significantly affect the efficiency of decontamination. The model and its results are useful in the design of small-scale treatment plants for acid flushing.     

Potential fresh water saving using greywater in toilet flushing in Syria

Greywater reuse is becoming an increasingly important factor for potable water saving in many countries. Syria is one of the most water scarce countries in the Middle East. However, greywater reuse is still not common in the country. Regulations and standards for greywater reuse are not available. Recently, however, several stakeholders have started to plan for greywater reuse. The main objective of this paper is to evaluate the potential for potable water saving by using greywater for toilet flushing in a typical Syrian city. The Sweida city in the southern part of Syria was chosen for this purpose. Interviews were made in order to reflect the social acceptance, water consumption, and the percentage of different indoor water uses. An artificial wetland (AW) and a commercial bio filter (CBF) were proposed to treat the greywater, and an economic analysis was performed for the treatment system. Results show that using treated greywater for toilet flushing would save about 35% of the drinking water. The economic analyses of the two proposed systems showed that, in the current water tariff, the payback period for AW and CBF in block systems is 7 and 52 years, respectively. However, this period will reduce to 3 and 21 years, respectively, if full water costs are paid by beneficiaries. Hence, introducing artificial wetlands in order to make greywater use efficient appears to be a viable alternative to save potable water.     

Saltwater intrusion in coastal aquifer ??? comparison between the CIP and MOC simulation technique

Proper management and evaluation of environmental effects for coastal groundwater aquifers require accurate estimation of salt and fresh water movement. For this we compare two numerical methods to study saltwater intrusion. The two numerical methods are the CIP (constrained interpolation profile) and the MOC (method of characteristics). The two numerical methods are used to solve the salt transport equation. The two methods are applied and compared to saltwater intrusion experiments for confined and unconfined aquifer case studies. It is found that for both cases, the CIP-method is superior in terms of calculation time while keeping an acceptable numerical accuracy.     

Cocaine and metabolites in waste and surface water across Belgium

Cocaine abuse, a growing social problem, is currently estimated from population surveys, consumer interviews and crime statistics. A new approach based on the analysis of cocaine (COC) and metabolites, benzoylecgonine (BE) and ecgonine methyl ester (EME), in water samples was applied to 28 rivers and 37 waste water treatment plants in Belgium using solid-phase extraction and liquid chromatography coupled to tandem mass spectrometry. While EME was undetectable, COC and BE were detectable with concentrations ranging from <1 to 753 ng/L and <1 to 2258 ng/L, respectively. BE concentrations were employed to calculate the local amount of abused cocaine. The highest values (up to 1.8 g/day cocaine per 1000 inhabitants) were found in large cities and during weekends. The estimation of cocaine abuse through water analysis can be executed on regular basis without cooperation of patients. It also gives clear geographical information, while prevention campaigns can easily be implemented and evaluated.     

Plant-mediated effects of heavy metal pollution on host choice of a grass miner

We studied the effects of heavy metal exposure on host plant choice and performance of the grass miner Chromatomyia milii (Diptera, Agromyzidae). Cadmium decreased plant growth in a dose-dependent way. C. milii preferred the control to the cadmium-exposed plants for feeding and oviposition. Moreover, preference for the control plants increased with increasing cadmium exposure of the alternative choice. Adult and offspring performance decreased with increasing plant cadmium exposure. This suggests that, at least under our laboratory conditions, host choice of C. milii is adaptive under pollution stress. Foliar cadmium concentration increased and the soluble sugar concentration decreased with increasing cadmium exposure. Regression analysis showed that both latter components might be responsible for the decrease in performance of C. milii on cadmium-exposed plants. The protein and amino acid concentration of the leaves, the amount of structural defenses, and water concentration were not affected by the cadmium treatment.     

Discrepancies in the acute versus chronic toxicity of compounds with a designated narcotic mechanism

In this study, it was illustrated that even for certain simple organic compounds with a designated mode of action (MOA) (i.e. narcotic toxicity) unexpected differences in acute and chronic toxicity can be observed. In a first part of the study, species sensitivity distributions (SSDs) based on either acute or chronic toxicity data of three narcotic test compounds (methanol, ethanol and 2-propanol) were constructed. The results of the acute SSDs were as expected for narcotic compounds: rather similar sensitivity and small differences in toxicity were observed among different species. On the contrary, the chronic SSDs of methanol and ethanol indicated larger interspecies variation in sensitivity. Furthermore, the chronic toxicity trend (ethanol > methanol > 2-propanol) was unexpectedly different from the acute toxicity trend (2-propanol > ethanol > methanol) and acute versus chronic extrapolation could not be successfully described for methanol and ethanol using an ACR of 10 (as suggested for narcotic compounds). In contrast to the interspecies approach in the first part of this study, the second part of the study was focused on the assessment of acute and chronic toxicity of the three test compounds in Daphnia magna, which was identified as one of the most sensitive organisms to methanol and ethanol. Here, the differences in acute and chronic toxicity trend were in accordance to the results of the SSDs. The enhancement of membrane penetration due to the small molecular size of methanol and ethanol, in combination with the higher toxicity of their respective biotransformation products were suggested as potential causes of the increased chronic toxicity. Furthermore, it was stressed that larger awareness of these irregularities in acute to chronic extrapolations of narcotic compounds is required and should receive additional attention in further environmental risk assessment procedure.     

Determination of diazepam in aquatic samples by capillary liquid chromatography-electrospray tandem mass spectrometry

In recent years growing attention has been paid toward the discharge, presence and potential adverse effects of pharmaceuticals in the environment. Using different existing analytical methods several studies have already identified a variety of drugs in waste-, surface- and drinking water. The monitoring of surface waters for drugs is of great importance because drugs are designed to be biological very active substances. A capillary LC/ES-MS-MS method has been developed that enables the sensitive and specific detection of diazepam in water samples up to 0.1 ng/ml (LOD). It requires neither multiple extraction steps, nor the use of large volumes of organic solvent. Applying this assay we have detected diazepam in 'in/effluent samples' collected in Belgium and demonstrated the applicability for water analysis without off-line pre-concentration of the analyte.     

Metal concentrations in water,sediment and gudgeon (Gobio gobio) from a pollution gradient: relationship with fish condition factor

This study assesses the applicability of a sentinel fish species as a biomonitor of metal pollution. Gudgeon (Gobio gobio) were collected from 14 sites in metal polluted lowland rivers in Flanders, including a clear Cd and Zn pollution gradient. Fish tissues were analysed for Cd, Cr, Cu, Ni, Pb and Zn. Metal levels in organs were related to levels in water and sediment. At some sites Cd and Zn levels were up to 50 times higher compared to reference values and literature. Significant relationships between Cd and Zn in fish tissue and environmental levels were found, especially in the pollution gradient where up to 70% of the observed variation could be described. Condition factor differed significantly among the sampling sites but could not be directly related to the environmental metal levels. Nevertheless, in the pollution gradient, threshold tissue concentrations could be defined above which the condition factor was always low.     

Anthropogenic and naturally-produced organobrominated compounds in bluefin tuna from the Mediterranean Sea

In the present study, bioaccumulation potential of two pyrethroid insecticides, bifenthrin and permethrin, was measured using a Lumbriculus variegatus sediment bioaccumulation test. Two sediments differing in their physical characteristics and two different aging periods were tested. Desorption rates measured by Tenax extraction suggested that pyrethroids were bioavailable to L. variegatus, however bioavailability varied among chemicals, sediments and aging time, and was greater for permethrin than bifenthrin. The relatively low biota-sediment accumulation factor (BSAF) values resulted from the extensive biotransformation of pyrethroids by L. variegatus. Biotransformation capacity of L. variegatus to permethrin was further studied with a water-only exposure, and the percentage parent compound dropped to 36.0% after 14 d. These results indicated sediment-associated pyrethroids were bioavailable to L. variegatus, however bioaccumulation was limited because L. variegatus was capable of biotransforming the pyrethroids.     

The influence of body size, condition index and tidal exposure on the variability in metal bioaccumulation in Mytilus edulis

Mussels are commonly used to monitor metal pollution despite high inter-individual variability in tissue concentrations. In this study, influences of body size, condition index and tidal height on concentrations of As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn were investigated. Body weight was inversely related to metal concentrations and for Cd, Mn, Pb and Zn the regression was affected by tidal height. Except for As, Fe and Mn metal concentrations were inversely related to physiological status though no differences between essential and non-essential metals were obvious. After correcting for body size, tidal height was related positively to As, Cd and Zn, negatively related to Cu, Fe and Mn while Co, Cr, Ni and Pb were independent of tidal height. The study recommends stringent measures during sampling for biomonitoring or metal concentrations at each location must be normalized to a common body size, CI and tidal height.