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941.
López A de Marco I Caballero BM Adrados A Laresgoiti MF 《Waste management (New York, N.Y.)》2011,31(8):1852-1858
In this work, a study of the regeneration and reuse of ZSM-5 zeolite in the pyrolysis of a plastic mixture has been carried out in a semi-batch reactor at 440 °C. The results have been compared with those obtained with fresh-catalyst and in non-catalytic experiments with the same conditions. The use of fresh catalyst produces a significant change in both the pyrolysis yields and the properties of the liquids and gases obtained. Gases more rich in C3-C4 and H2 are produced, as well as lower quantities of aromatic liquids if compared with those obtained in thermal decomposition. The authors have proved that after one pyrolysis experiment the zeolite loses quite a lot of its activity, which is reflected in both the yields and the products quality; however, this deactivation was found to be reversible since after regeneration heating at 550 °C in oxygen atmosphere, this catalyst recovered its initial activity, generating similar products and in equivalent proportions as those obtained with fresh catalyst. 相似文献
942.
Callaghan TV Tweedie CE Akerman J Andrews C Bergstedt J Butler MG Christensen TR Cooley D Dahlberg U Danby RK Daniëls FJ de Molenaar JG Dick J Mortensen CE Ebert-May D Emanuelsson U Eriksson H Hedenås H Henry H R G Hik DS Hobbie JE Jantze EJ Jaspers C Johansson C Johansson M Johnson DR Johnstone JF Jonasson C Kennedy C Kenney AJ Keuper F Koh S Krebs CJ Lantuit H Lara MJ Lin D Lougheed VL Madsen J Matveyeva N Mcewen DC Myers-Smith IH Narozhniy YK Olsson H Pohjola VA Price LW Rigét F Rundqvist S 《Ambio》2011,40(6):705-716
Understanding the responses of tundra systems to global change has global implications. Most tundra regions lack sustained environmental monitoring and one of the only ways to document multi-decadal change is to resample historic research sites. The International Polar Year (IPY) provided a unique opportunity for such research through the Back to the Future (BTF) project (IPY project #512). This article synthesizes the results from 13 papers within this Ambio Special Issue. Abiotic changes include glacial recession in the Altai Mountains, Russia; increased snow depth and hardness, permafrost warming, and increased growing season length in sub-arctic Sweden; drying of ponds in Greenland; increased nutrient availability in Alaskan tundra ponds, and warming at most locations studied. Biotic changes ranged from relatively minor plant community change at two sites in Greenland to moderate change in the Yukon, and to dramatic increases in shrub and tree density on Herschel Island, and in subarctic Sweden. The population of geese tripled at one site in northeast Greenland where biomass in non-grazed plots doubled. A model parameterized using results from a BTF study forecasts substantial declines in all snowbeds and increases in shrub tundra on Niwot Ridge, Colorado over the next century. In general, results support and provide improved capacities for validating experimental manipulation, remote sensing, and modeling studies. 相似文献
943.
The changes in the vascular plant flora of Tasiilaq, low arctic Southeast Greenland, between around 1900 and 2007 were studied
by comparing the data from historical literature with those of the field observations performed between the late 1960s and
2007. Since 1900, the percentage of widely distributed arctic species distinctly decreased, whereas that of the low arctic
species somewhat increased, and boreal species hardly increased. Vegetation monitoring revealed minor changes and showed that
several thermophilous and xerophilous species increased between 1968/1969 and 2007, whereas some hygrophilous species decreased.
Repeated vegetation mapping of a shallow pond revealed conspicuous changes suggesting increased evaporation/precipitation
ratios associated with environmental warming up and decreasing snow accumulation in winter, in line with results of previous
investigations. In spite of climate warming, expansion of the town and increasing human impact, flora and vegetation on the
whole appeared rather stable during the last 40 years without invading species or introductions. 相似文献
944.
da Costa Machado Matos Carvalho IM Cavalcante AA Dantas AF Pereira DL Rocha FC Oliveira FM Da Silva J 《Chemosphere》2011,82(7):1056-1061
Sodium metabisulfite is used in marine shrimp harvesting to prevent the occurrence of black spots. Shrimps are soaked in a sodium metabisulfite solution in ice, which is disposed of in sewages that run into marine canals, creating an environmental hazard. This study evaluates the toxicity and mutagenicity caused by sodium metabisulfite in sea waters and sediments collected in a shrimp farm in Cajueiro da Praia (Luis Correia), state of Piauí, Brazil, using the Allium cepa assay. Water and sediment samples were collected in the dry and in the rainy seasons, in three sites: upstream the shrimp farm (Site 1), at the point sodium metabisulfite is discharged (Site 2), and 100 m downstream the farm (Site 3). Three sample dilutions were used (50%, 25% and 10%) for all samples. A negative control (well water) and a positive control (copper sulfate 0.0006 mg mL−1) were used in each experiment. At the end of the 72-h exposure period, onion roots were measured and removed. Mutagenicity analysis included the determination of mitotic index, chromosomal aberrations and the detection of micronuclei; analysis of root size and mitotic index were used as an index of toxicity. The A. cepa assay revealed that the water and sediments samples collected in the Piauí coast contaminated with sodium metabisulfite induce toxicity. The results demonstrate that the assay may be used as a regular tool in the analysis of water parameters in shrimp farms in the coast of Piauí state, and in strategies to preserve the region’s marine ecosystem. 相似文献
945.
Concentrations and sources of Dechlorane Plus in sewage sludge 总被引:1,自引:0,他引:1
Sewage sludge from 31 urban Spanish wastewater treatment plants (WWTP) was analyzed for the emerging halogenated flame retardant Dechlorane Plus (DP). Concentrations of the two major isomers in the technical mixture, syn and anti, ranged between 0.903-19.2 and 1.55-75.1 ng g−1 dry weight, respectively. Overall, concentrations of DP were lower than those of polybrominated diphenyl ethers (PBDEs) (9.10-995 ng g−1 dry weight) and this is likely related to the higher usage of brominated flame retardants. The average ratio of the syn isomer to total DP (fsyn) was 0.28 ± 0.05, which is similar to that of the commercial mixture. Comparing different wastewater treatment methods, we found lower concentrations in those using biological nitrogen and phosphorous elimination, suggesting that DP is susceptible to microbial degradation and that anti-DP is more so, given the enrichment of syn-DP in the sewage sludge. Principal components analysis revealed significant positive correlation (r = 0.619, p < 0.05) between total DP concentrations with the contribution of industrial input to waste streams. This implies release of DP is related to industrial activity, likely stemming from the use of the technical product during manufacture of consumer goods. However, use and disposal of products containing DP could not be dismissed. According to our knowledge, this is the first report on DP in WWTP sludge. 相似文献
946.
This paper reports genotoxicity and toxicity data in water samples collected in Sinos River, an important water course in the hydrographic region of Guaíba Lake, Rio Grande do Sul State, south of Brazil. This river is exposed to intense anthropic influence by numerous shoes, leather, petrochemical, and metallurgy industries. Water samples were collected at two moments (winter 2006 and spring 2006) at five sites of Sinos River and evaluated using in vitro V79 Chinese hamster lung fibroblasts (cytotoxicity, comet assay and micronucleus test) and Allium cepa test (toxicity and micronucleus test). Comet and micronucleus tests revealed that water samples collected exerted cytotoxic, toxic, genotoxic and mutagenic effects. The results showed the toxic action of organic and inorganic agents found in the water samples in all sites of Sinos River, for both data collections. The main causes behind pollution were the domestic and industrial toxic discharges. The V79 and A. cepa tests were proved efficient to detect toxicity and genotoxicity caused by complex mixtures. This study also showed the need for constant monitoring in sites with strong environmental degradation caused by industrial discharges and urban sewages. 相似文献
947.
García-Esquinas E Pérez-Gómez B Fernández MA Pérez-Meixeira AM Gil E de Paz C Iriso A Sanz JC Astray J Cisneros M de Santos A Asensio A García-Sagredo JM García JF Vioque J Pollán M López-Abente G González MJ Martínez M Bohigas PA Pastor R Aragonés N 《Chemosphere》2011,85(2):268-276
Background
Although breastfeeding is the ideal way of nurturing infants, it can be a source of exposure to toxicants. This study reports the concentration of Hg, Pb and Cd in breast milk from a sample of women drawn from the general population of the Madrid Region, and explores the association between metal levels and socio-demographic factors, lifestyle habits, diet and environmental exposures, including tobacco smoke, exposure at home and occupational exposures.Methods
Breast milk was obtained from 100 women (20 mL) at around the third week postpartum. Pb, Cd and Hg levels were determined using Atomic Absorption Spectrometry. Metal levels were log-transformed due to non-normal distribution. Their association with the variables collected by questionnaire was assessed using linear regression models. Separate models were fitted for Hg, Pb and Cd, using univariate linear regression in a first step. Secondly, multivariate linear regression models were adjusted introducing potential confounders specific for each metal. Finally, a test for trend was performed in order to evaluate possible dose-response relationships between metal levels and changes in variables categories.Results
Geometric mean Hg, Pb and Cd content in milk were 0.53 μg L−1, 15.56 μg L−1, and 1.31 μg L−1, respectively. Decreases in Hg levels in older women and in those with a previous history of pregnancies and lactations suggested clearance of this metal over lifetime, though differences were not statistically significant, probably due to limited sample size. Lead concentrations increased with greater exposure to motor vehicle traffic and higher potato consumption. Increased Cd levels were associated with type of lactation and tended to increase with tobacco smoking.Conclusions
Surveillance for the presence of heavy metals in human milk is needed. Smoking and dietary habits are the main factors linked to heavy metal levels in breast milk. Our results reinforce the need to strengthen national food safety programs and to further promote avoidance of unhealthy behaviors such as smoking during pregnancy. 相似文献948.
Estrogens are a class of micro-pollutants found in water at low concentrations (in the ng L−1 range), but often sufficient to exert estrogenic effects due to their high estrogenic potency. Disinfection of waters containing estrogens through oxidative processes has been shown to lead to the formation of disinfection byproducts, which may also be estrogenic. The present work investigates the formation of disinfection byproducts of 17β-estradiol (E2) and estrone (E1) in the treatment of water with ozone. Experiments have been carried out at two different concentrations of the estrogens in ground water (100 ng L−1 and 100 μg L−1) and at varying ozone dosages (0-30 mg L−1). Detection of the estrogens and their disinfection byproducts in the water samples has been performed by means of ultra performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) with a triple quadrupole (QqQ) and a quadrupole-time of flight (QqTOF) instrument. Both E2 and E1 have been found to form two main byproducts, with molecular mass (MM) 288 and 278 in the case of E2, and 286 and 276 in the case of E1, following presumably the same reaction pathways. The E2 byproduct with MM 288 has been identified as 10epsilon-17beta-dihydroxy-1,4-estradieno-3-one (DEO), in agreement with previously published results. The molecular structures and the formation pathways of the other three newly identified byproducts have been suggested. These byproducts have been found to be formed at both high and low concentrations of the estrogens and to be persistent even after application of high ozone dosages. 相似文献
949.
Lucia De Stefano Javier de Pedraza Gilsanz Fermín Villarroya Gil 《Environmental management》2010,45(6):1363-1377
Periodic assessment of progress toward established policy goals is crucial to understanding whether the applied efforts are
effective. In Europe, the Water Framework Directive (WFD) adopted in year 2000 set ambitious environmental objectives to be
achieved by the end of 2015 through the implementation of Integrated Water Resources Management (IWRM) principles. While at
this stage it is premature to measure the impact of this Directive in terms of environmental outcomes, it is nonetheless important
to develop indicators in order to monitor whether water management practices throughout Europe are aligning towards IWRM.
This article presents the methodological development of the Water and Wetland Index, a comparative water policy assessment
by environmental NGOs that was carried out in 2002–2003, and highlights the interest of repeating it in 2015, when the first
WFD planning cycle will be completed. 相似文献
950.
M. Op de Beeck M. De Bock K. Vandermeiren 《Environmental pollution (Barking, Essex : 1987)》2010,158(10):3251-3260
In this study we tested and compared a multiplicative stomatal model and a coupled semi-empirical stomatal-photosynthesis model in their ability to predict stomatal conductance to ozone (gst) using leaf-level data from oilseed rape (Brassica napus L.) and broccoli (Brassica oleracea L. var. italica Plenck). For oilseed rape, the multiplicative model and the coupled model were able to explain 72% and 73% of the observed gst variance, respectively. For broccoli, the models were able to explain 53% and 51% of the observed gst variance, respectively. These results support the coupled semi-empirical stomatal-photosynthesis model as a valid alternative to the multiplicative stomatal model for O3 flux modelling, in terms of predictive performance. 相似文献