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51.
It is generally accepted that the bioavailability of metals in sediments is influenced by the presence of acid volatile sulfides (AVS). The pore water hypothesis predicts that, if the molar concentration of simultaneously extracted metals (SEM) in a sediment is smaller than the molar concentration of AVS, the free metal ion activity in the pore water is very small and that consequently no metal toxicity in short-term toxicity tests is observed. In this study we examined (1) if this concept can be extended to predict the absence of chronic Ni toxicity to the oligochaete deposit-feeding worm Lumbriculus variegatus and (2) if the organic carbon normalized excess SEM; i.e. [SEM-AVS]/f(OC) predicts the magnitude of Ni toxicity to L. variegatus. A 28-day toxicity experiment was performed in which biomass production of L. variegatus was determined in two natural sediments with different [AVS] and f(OC), spiked at different Ni concentrations. The absence of toxicity is predicted correctly by the [SEM-AVS]<0 criterion when only the 0-1 cm surface layer of the sediment is considered, but not when the whole bulk sediment is considered (0-3 cm). In both sediments, the same [SEM-AVS]/f(OC) at the surface corresponds with a similar decrease in L. variegatus biomass. Thus, [SEM-AVS]/f(OC) in the surface layer accurately predicts the magnitude of toxicity. This measure is therefore a good estimator of toxicologically available Ni. On the other hand, the free Ni(2+) ion activity in the overlying water appeared to be an equally good predictor of the magnitude of toxicity. Consequently, it was not possible to determine the relative importance of the overlying water and pore water exposure route with the semi-static laboratory experiments.  相似文献   
52.
Two field studies of interpersonal conflict in organizations and a simulated dyadic negotiation show that problem solving and forcing are frequently combined simultaneously and sequentially. As a robust finding, conglomerations of problem solving and forcing appear to enhance the parties' joint effectiveness. The best substantive and relational outcomes for the organization are reached through forcing followed by problem solving. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   
53.
The risk assessment of genetically-modified plants pursuant to Annex II B of EU Directive 94/15/EC assumes that it is possible to infer the environmental impacts of a crop plant from its characteristics, so most of Annex II should also be applicable to conventional plants. To test this, we surveyed reports on the ecological impacts of the cultivation of non-transgenic crop plants with novel or improved traits and, in three cases, investigated whether Annex II B would have been adequate to indicate the effects. Such an assessment appears to be feasible only if the time frame on which it is based is short, so that long-term effects cannot be assessed. Secondly, the plant must be genetically homogenous which is not always granted, e.g. with forest-trees. Thirdly, the cultivation area must be defined. Differences in the behaviour of foreign plants between their original and cultivation habitats may be ecologically relevant and should be assessed. In the (few) cases where direct inference of the observed effects was possible from inherent traits, these effects often correlated with poor adaptation to local environmental conditions. The ecological impacts of traits that had been introduced in order to overcome poor adaptation may differ widely according to the way in which the traits are exploited. In practice, the effects of agricultural measures are more important than the effects of gene transfer and invasiveness, although the latter currently play a major role in risk assessment. In the light of these deliberations, a modification of Annex II B of EU Directive 94/15/EC is suggested.  相似文献   
54.
Political decision-makers in the European Union (EU) are currently discussing the introduction of a mandatory uniform labelling scheme for meat and milk that provides information on husbandry systems similar to the already existent labelling scheme in the EU egg market. The objective of this paper was to assess whether such information is relevant to consumers when buying meat and milk. The paper was based on a systematic synthesis of 53 scientific journal articles on empirical consumer studies. The review revealed that consumers perceived the aspects of outdoor access, stocking density and floor type as important factors influencing animal welfare. On average, consumers not only had a positive attitude towards more animal welfare-friendly husbandry systems with outdoor access and space allowance but were also willing to pay a price premium for products from such systems. All studies on consumer segmentation identified at least one consumer segment that placed great importance on animal welfare-friendly husbandry systems. Interestingly, many studies identified one or more other segments who still had a significant preference for animal welfare-friendly products even though other product attributes were more important to them. Based on the findings, the paper presents conclusions regarding the labelling of husbandry systems for meat and milk.  相似文献   
55.
Motivated by an inconclusive debate over implications of resource scarcity for violent conflict, and common reliance on national data and linear models, we investigate the relationship between socio-ecological vulnerability and armed conflict in global drylands on a subnational level. Our study emanates from a global typology of smallholder farmers’ vulnerability to environmental and socioeconomic stresses in drylands. This typology is composed of eight typical value combinations of variables indicating environmental scarcities, resource overuse, and poverty-related factors in a widely subnational spatial resolution. We investigate the relationships between the spatial distribution of these combinations, or vulnerability profiles, and geocoded armed conflicts, and find that conflicts are heterogeneously distributed according to these profiles. Four profiles distributed across low- and middle-income countries comprise all drylands conflicts. Comparing models for conflict incidence using logit regression and receiver operator characteristic analysis based on (1) the set of all seven indicators as independent variables and (2) a single, only vulnerability profile-based variable proves that the nonlinear typology-based variable is the better explanans for conflict incidence. Inspection of the profiles’ value combinations makes this understandable: A systematic explanation of conflict incidence and absence across all degrees of natural resource endowments is only reached through varying importance of poverty and resource overuse depending on the level of endowment. These are nonlinear interactions between the explaining variables. Conflict does not generally increase with resource scarcity or overuse. Comparison with conflict case studies showed both good agreement with our results and promise in expanding the set of indicators. Based on our findings and supporting literature, we argue that part of the debate over implications of resource scarcity for violent conflict in drylands may be resolved by acknowledging and accounting for nonlinear processes.  相似文献   
56.
In ecotoxicology, derivation of a "safe" environmental concentration is usually achieved by the use of extrapolation factors or by statistical extrapolation from a set of single species toxicity data. These approaches ignore ecological interactions between species in the field. An ecology-based alternative to this pragmatic approach can be ecosystem modelling, which can account for ecological interactions. However, it is largely unexplored how well the predictions of these models quantitatively agree with large-scale experimental studies. Therefore, we evaluated the capacity of a flexible ecosystem model to predict population and ecosystem-level no observed effect concentrations (NOECs) of 7 organic toxicants. These NOECs were compared with population and ecosystem-NOECs observed in 11 micro- and mesocosm studies. For each of the latter studies, the model was customized to account for the specific ecological interactions within these systems and combined with appropriate single-species toxicity data from literature. Population-NOEC predictions were accurate, or at least protective, for 60, and 85% of all considered model populations, respectively. For all 11 studies, a protective ecosystem-NOEC could be derived, being accurate in 7 cases, and conservative in 4 cases. In general, it can be stated that this type of models can serve as an ecology-based alternative to current extrapolation techniques in EEAs and water quality standard setting.  相似文献   
57.
In this paper, some of the main processes and parameters which affect metal bioavailability and toxicity in the aquatic environment and its implications for metal risk assessment procedures will be discussed. It has become clear that, besides chemical processes (speciation, complexation), attention should also be given to physiological aspects for predicting metal toxicity. The development of biotic ligand models (BLMs), which combine speciation models with more biologically oriented models (e.g. GSIM), has offered an answer to this need. The various BLMs which have been developed and/or refined for a number of metals (e.g. Cu, Ag, Zn) and species (algae, crustaceans, fish) are discussed here. Finally, the potential of the BLM approach is illustrated through a theoretical exercise in which chronic zinc toxicity to Daphnia magna is predicted in three regions, taking the physico-chemical characteristics of these areas into account.  相似文献   
58.
59.
By integrating social network theory and leader–member exchange (LMX) theory, we explore the effects of three types of social relationships on employee innovative behavior: weak ties outside the group, LMX, and strong ties within the group. The results from a sample in a high‐tech firm showed that LMX fully mediated the positive relationship between out‐group weak ties and innovative behavior. Furthermore, within‐group strong ties negatively moderated the second stage of this indirect relationship, such that LMX was positively and significantly related to innovative behavior only when the number of within‐group strong ties was low. The theoretical and practical implications of these findings are discussed. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
60.
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