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951.
Organic pollutants in compost and digestate. Part 1. Polychlorinated biphenyls, polycyclic aromatic hydrocarbons and molecular markers 总被引:1,自引:0,他引:1
Brändli RC Bucheli TD Kupper T Furrer R Stahel WA Stadelmann FX Tarradellas J 《Journal of environmental monitoring : JEM》2007,9(5):456-464
In Europe, 9.3 x 10(6) t(dry weight (dw)) of compost and digestate are produced per year. Most of this is applied to agricultural land, which can lead to considerable inputs of organic pollutants, such as polychlorinated biphenyls (PCB) and polycyclic aromatic hydrocarbons (PAH) to soil. This paper presents an inventory of the pollutant situation in source-separated composts, digestates and presswater in Switzerland by a detailed analysis of over 70 samples. PCB concentrations ( summation PCB 28, 52, 101, 118, 138, 153, 180) were significantly higher in urban (median: 30 microg kg(-1)dw, n = 52) than in rural samples (median: 14 microg kg(-1)dw, n = 16). Together with low concentrations in general, this points to aerial deposition on compost input material as the major contamination pathway. Enantiomeric fractions of atropisometric PCB were close to racemic. Median PAH concentration was 3010 microg kg(-1)dw( summation 15PAH, n = 69), and one quarter of the samples exhibited concentrations above the relevant Swiss guide value for compost (4000 microg kg(-1)dw). The levels were influenced by the treatment process (digestate > compost), the season of input material collection (spring-summer > winter > autumn), the particle size (coarse-grained > fine-grained), and maturity (mature > less mature). The main source of PAH in compost was pyrogenic, probably influenced mainly by liquid fossil fuel combustion and some asphalt abrasion, as suggested by multiple linear regression. This study, together with a companion paper reporting on other organic contaminates including emerging compound classes, provides a starting point for a better risk-benefit estimation of the application of compost and digestate to agricultural soil in Switzerland. 相似文献
952.
Trott D Dawson JJ Killham KS Miah MR Wilson MJ Paton GI 《Journal of environmental monitoring : JEM》2007,9(1):44-50
Despite the widespread and successful use of luminescence-based bioassays in water testing, their applications to soils and sediments is less proven. In part this is because such bioassays have mainly been carried out in an aqueous-based medium and, as such, favour contaminants that are readily water-soluble. In this study, aqueous solutions and soils contaminated with heavy metals (HM), polar organic contaminants and hydrophobic organic contaminants (HOCs) were tested using a range of luminescence-based bioassays (Vibrio fischeri, Escherichia coli HB101 pUCD607 and Pseudomonas fluorescens 10586r pUCD607). For the first two chemical groups, the assays were highly reproducible when optimised extraction procedures were employed but for HOCs the bioassay response was poor. Quantitative structure-activity relationships (QSARs) obtained from aqueous solutions had a linear response although correlation for the chemicals tested using bacterial bioassays was significantly less sensitive than that of sublethal tests for Tetrahymena pyriformis. Bacterial and Dendrobaena veneta bioassay responses to extracts from HM amended soils showed that a clear relationship between trophic levels could be obtained. There is no doubt that the wide range of bioluminescent-based bioassays offers complementary applications to traditional testing techniques but there is a significant need to justify and optimise the extraction protocol prior to application. 相似文献
953.
Harrad S Robson M Hazrati S Baxter-Plant VS Deplanche K Redwood MD Macaskie LE 《Journal of environmental monitoring : JEM》2007,9(4):314-318
The environmentally prevalent polybrominated diphenyl ether (PBDE) #47 and polychlorinated biphenyls (PCBs) #28 and #118 were challenged for 24 hours with a novel biomass-supported Pd catalyst (Bio-Pd(0)). Analysis of the products via GC-MS revealed the Bio-Pd(0) to cause the challenged compounds to undergo stepwise dehalogenation with preferential loss of the least sterically hindered halogen atom. A mass balance for PCB #28 showed that it is degraded to three dichlorobiphenyls (33.9%), two monochlorobiphenyls (12%), and biphenyl (30.7%). The remaining mass was starting material. In contrast, while PCB #118 underwent degradation to yield five tetra- and five trichlorinated biphenyls, no less chlorinated products or biphenyl were detected, and the total mass of degraded products was 0.3%. Although the Bio-Pd(0) material was developed for treatment of PCBs, a mass balance for PBDE #47 showed that the biocatalyst could prove a potentially useful method for treatment of PBDEs. Specifically, 10% of PBDE #47 was converted to identifiable lower brominated congeners, predominantly the tribrominated PBDE #17 and the dibrominated PBDE #4, 75% remained intact, while 15% of the starting mass was unaccounted for. 相似文献
954.
A recently favored hypothesis is that duetting in birds has a mate-guarding function: a male responds vocally to his partner’s
song, thereby forming a duet that repels males who are attracted to her song. Previous studies have not provided unambiguous
tests of the mate-guarding hypothesis because: (1) the probability of a male answering his partner’s song has not been shown
to increase specifically when the female is fertile, and (2) the probability of a male answering his partner’s song has not
been assessed separately from simply a higher song initiation rate. We investigated extra-pair paternity, mate-guarding, and
duetting in the socially monogamous Australian magpie-lark (Grallina cyanoleuca). DNA fingerprinting revealed that 3% of young were the result of extra-pair paternity, and we found that males guarded fertile
females by staying close to them. However, males did not initiate songs at a higher rate when females were fertile and actually
reduced their probability of replying to female song during this period. We conclude that although male magpie-larks did guard
fertile females in an attempt to prevent extra-pair copulations, they did not use duetting for this purpose.
Received: 10 May 1999 / Received in revised form: 27 September 1999 / Accepted: 2 October 1999 相似文献
955.
Recent models of choosiness in mate choice have identified two particularly important factors: the potential reproductive
rate (PRR) of the choosing sex relative to that of the chosen sex, and the variation in quality of potential mates. This experimental
study tested how these factors affected choosiness in male and female sand gobies, Pomatoschistus minutus. We manipulated relative PRR by means of water temperature, and mate quality by means of body length. The choosing male or
female was offered a choice between two mates with either a small or a large difference in body length representing a small
or a large variation in mate quality. Choosiness was measured as (1) preference for the larger mate, and (2) as whether or
not spawning occurred with the smaller mate, while the larger mate was visible but screened off. We found that females preferred
large males, and that their level of choosiness was affected by variation in male quality, but not by their own relative PRR.
Males, on the other hand, seemed unselective in all treatments and were in general more likely than females to spawn with
their provided partner. This suggests that in the sand goby, variation in male mate quality has a greater influence than relative
PRR on facultative changes in female choosiness. However, a general difference in PRR between males and females may be one
important factor explaining the observed sex difference in choosiness.
Received: 17 April 2000 / Revised: 24 June 2000 / Accepted: 17 July 2000 相似文献
956.
Weather-mediated natural selection on arrival time in cliff swallows (Petrochelidon pyrrhonota) 总被引:2,自引:0,他引:2
An unusually long period of cold weather in May 1996 caused extensive mortality among insectivorous cliff swallows (Petrochelidon pyrrhonota) in the northern and central Great Plains. We analyzed how viability selection affected spring arrival time in a migratory
Nebraska population by comparing capture histories of survivors with those of birds known to have died and by documenting
how arrival time changed in the year following the selection event. Surviving birds had significantly later first-capture
dates (an index of arrival time) in the years prior to selection than those that died; a significant selection differential
suggested directional selection for birds that arrived later. Colony sites were occupied significantly later following the
selection event, and the distribution of first-capture dates in the season after selection was significantly shifted toward
later arrivals. Offspring of the survivors tended to arrive later than birds of the same age prior to the selection event.
While major weather-caused mortality events of this magnitude are rare in the study area, spells of cold weather severe enough
to cause limited mortality are frequent in April and early May. At least 25 probable mortality events of varying severity
were identified in the last 50 years based on climatological data. Periodic weather-mediated selection against early arrival
constrains the cliff swallow’s breeding season and may partly prevent directional selection for earlier nesting.
Received: 19 October 1999 / Received in revised form: 15 January 2000 / Accepted: 24 January 2000 相似文献
957.
Male willow warblers have song repertoires which vary in complexity along several dimensions. We examined whether female choice,
as measured by date of pairing, was based on these song characteristics in 4 different years. Pairing date was negatively
correlated with song repertoire size in 1 year, and with song versatility in another year, but there was no consistent effect
of any song characteristic on pairing throughout the years or in the pooled sample. The variable that best explained how soon
a male pairs is male arrival date (only males that had settled territories before the first female arrived were considered
in the analysis). This correlation is consistently significant in all years. This is most parsimoniously interpreted as females
choosing some habitat characteristic in the same way that males do. A small percentage of males (8.3%) attracted and paired
with a second female. The likelihood of becoming polygynous was not explained by any measured song characteristic, but it
was related to arrival date: early males were more likely to pair with two females. Males with large repertoires fledged more
young in their primary nests, and there was a trend for the offspring of these males to have a greater probability of being
recruited into the population. In conclusion, the results show that in most years there is no sexual selection by female preference
on song characteristics, although the data on reproductive success is consistent with the idea of repertoire size being an
indicator of male quality.
Received: 4 June 1999 / Received in revised form: 1 December 1999 / Accepted: 31 December 1999 相似文献
958.
Most studies of social polygyny in birds have examined male provisioning on the basis of the number of feeding visits. This
may be misleading if males compensate for infrequent visits by bringing larger prey at each visit. We investigated nestling
provisioning in the socially polygynous great reed warbler, Acrocephalus arundinaceus, in south Central Sweden in 1996–1997. We collected data on rate of feeding visits, prey size and the amount of biomass delivered
by males and females. Males had lower rates of feeding visits and provided smaller prey to nestlings in secondary than in
monogamous and primary nests. Secondary females had higher rates of feeding visits and brought larger prey than monogamous
and primary females. These results confirm that secondary females face a potential cost of polygyny through a lower rate of
male feeding, and that this cost was reinforced by the significantly lower male provisioning rate (biomass h–1) at secondary nests. Secondary females compensated for the lack of male assistance by increasing their rate of feeding and
bringing larger prey. As a result, offspring in nests of secondary females received as much food as did those in nests of
primary females. Prey load size increased with the parent’s proportion of feeding visits, suggesting that parents use different
feeding strategies depending on their amount of responsibility for nestling provisioning. We suggest that parents which take
the main responsibility for nestling feeding have to forage further away from the nest, and based on optimal-foraging theory,
they should then on average bring larger prey to their nest.
Received: 4 April 1999 / Received in revised form: 12 October 1999 / Accepted: 23 October 1999 相似文献
959.
Life history costs of olfactory status signalling in mice 总被引:4,自引:0,他引:4
L. M. Gosling S. C. Roberts E. A. Thornton M. J. Andrew 《Behavioral ecology and sociobiology》2000,48(4):328-332
Large body size confers a competitive advantage in animal contests but does not always determine the outcome. Here we explore
the trade-off between short-term achievement of high social status and longer-term life history costs in animals which vary
in competitive ability. Using laboratory mice, Mus musculus, as a model system, we show that small competitors can initially maintain dominance over larger males by increasing investment
in olfactory status signalling (scent-marking), but only at the cost of reduced growth rate and body size. As a result they
become more vulnerable to dominance reversals later in life. Our results also provide the first empirical information about
life history costs of olfactory status signals.
Received: 15 December 1999 / Revised: 6 June 2000 / Accepted: 24 June 2000 相似文献
960.
Factors Affecting Population Assessments of Desert Tortoises 总被引:1,自引:0,他引:1
Jerome E. Freilich ‡ Kenneth P. Burnham † Christopher M. Collins and C. Ann Garry 《Conservation biology》2000,14(5):1479-1489
Abstract: Desert tortoises have been a subject of controversy since their listing as threatened in 1990. With a wide geographic range and more living individuals than any other listed land animal, biologists have needed to detect population trends against a "noisy" background of strong annual changes. We obtained annual population estimates of desert tortoises over 6 consecutive years at a 2.59-km2 plot in Joshua Tree National Park, California. Our estimates, based on weekly spring surveys, varied substantially, particularly between wet and dry years. Concurrently, we followed 10 radiotagged animals for 3 years to corroborate the surveys. Population density was determined separately for each year and for all years combined. Our best population estimate was an average of 67 adult tortoises, three times more than the density reported in a 1978 survey of the same site. Annual mortality was low ( <10%), and the animals showed extreme site fidelity. Apparent changes in population size were most strongly related to the animals' varying susceptibility to capture. In dry years, home ranges decreased, captures decreased, and effort required to find each tortoise nearly doubled. Our data confirm that tortoises are likely to be undercounted during dry years and call into question earlier studies conducted during droughts. 相似文献