Parametric study of MSW landfill settlement model

A newly developed and validated constitutive model that accounts for primary compression and time-dependent mechanical creep and biodegradation is used for parametric study to investigate the effects of model parameters on the predicted settlement of municipal solid waste (MSW) with time. The model enables the prediction of stress strain response and yield surfaces for three components of settlement: primary compression, mechanical creep, and biodegradation. The MSW parameters investigated include compression index, coefficient of earth pressure at-rest, overconsolidation ratio, and biodegradation parameters of MSW. A comparison of the predicted settlements for typical MSW landfill conditions showed significant differences in time-settlement response depending on the selected model input parameters. The effect of lift thickness of MSW on predicted settlement is also investigated. Overall, the study shows that the variation in the model parameters can lead to significantly different results; therefore, the model parameter values should be carefully selected to predict landfill settlements accurately. It is shown that the proposed model captures the time settlement response which is in general agreement with the results obtained from the other two reported models having similar features.     

考虑支座转角的地基不均匀沉降基础隔震结构地震响应分析∗

地基不均匀沉降可能会引起沉降范围内部分隔震支座发生转动,造成隔震层刚度发生变化,进而导致上部结构地震损伤和失效风险增大。针对地基不均匀沉降条件下基础隔震结构地震响应研究,现有成果大都通过施加平动位移进行模拟,并未考虑隔震支座转角的不利影响。为了研究地基不均匀沉降条件下基础隔震结构支座可能出现的转动及其对整体结构地震响应特征影响规律,首先以隔震支座为对象,研究了支座转动变形与叠层橡胶隔震支座水平刚度变化关系,建立了叠层橡胶隔震支座转角与水平刚度变化关系函数;在此基础上系统研究了地基不均匀沉降条件下整体基础隔震结构响应特征,以及基础结构的减震系数变化规律,以期揭示地基不均匀沉降对基础隔震结构地震响应影响机理。结果表明：隔震支座转角变形会引起隔震结构体系地震响应发生显著变化,随着隔震支座转角增大,隔震层水平刚度增大的同时隔震结构体系变形能力减弱,进而造成上部结构加速度响应增大,位移响应减小,导致基础隔震结构水平减震系数增大,减震效果低于预期;当转角接近π/2 时,隔震支座将丧失降低上部结构地震响应的作用,原隔震结构将退化为抗震结构;对于存在地基不均匀沉降的基础隔震结构,应及时采取必要措施控制地震响应,以防范上部结构发生倾覆。     

Statistical evidence on the effectiveness of sewering to protect groundwater from VOC contamination

Volatile organic compounds (VOCs) are an important source of contamination of groundwater supplies in Massachusetts and many parts of the United States. One local response is to require sewering in wellhead protection areas as an easily enforceable policy designed to reduce the probability of VOC contamination of groundwater. Data were collected for 238 wellhead protection areas in Massachusetts on VOC contamination levels and the sewered and unsewered land uses in those aquifer recharge areas. Logistic regression procedures were used to see whether sewering had any statistical effect on likelihood of contamination of well water. The results provided limited, but not overpowering, support for the idea that requiring commercial and industrial land uses to use sewers would reduce the chance of VOC contamination.     

Ameliorating effect of N-acetylcysteine and curcumin on pesticide-induced oxidative DNA damage in human peripheral blood mononuclear cells

Endosulfan, malathion, and phosphamidon are widely used pesticides. Subchronic exposure to these contaminants commonly affects the central nervous system, immune, gastrointestinal, renal, and reproductive system. There effects have been attributed to increased oxidative stress. This study was conducted to examine the role of oxidative stress in genotoxicity following pesticide exposure using peripheral blood mononuclear cells (PBMC) in vitro. Further possible attenuation of genotoxicity was studied using N-acetylcysteine (NAC) and curcumin as known modulators of oxidative stress. Cultured mononuclear cells was isolated from peripheral blood of healthy volunteers, and exposed to varying concentrations of different pesticides: endosulfan, malathion, and phosphamidon for 6, 12, and 24 h. Lipid peroxidation was assessed by cellular malondialdehyde (MDA) level and DNA damage was quantified by measuring 8-hydroxy-2'-deoxyguanosine (8-OH-dG) using ELISA. Both MDA and 8-OH-dG were significantly increased in a dose-dependent manner following treatment with these pesticides. There was a significant decrease in MDA and 8-OH-dG levels in PBMC when co-treated with NAC or/and curcumin as compared to pesticide alone. These results indicate that pesticide-induced oxidative stress is probably responsible for the DNA damage, and NAC or curcumin attenuate this effect by counteracting the oxidative stress.     

Synthesis of a highly recoverable 3D MnO2/rGO hybrid aerogel for efficient adsorptive separation of pharmaceutical residue

Water contamination by non-steroidal anti-inflammatory drugs, such as acetaminophen, is an emerging ecological concern. In this study, a new three-dimensional manganese dioxide-engrafted reduced graphene oxide (3D MnO₂/rGO) hybrid aerogel was developed for acetaminophen sequestration. The synthesis involved firstly the self-assembly of GO aerogel, followed by thermal reduction and in-situ MnO₂ growth by redox-reaction. The aerogel demonstrated interlinked planes with smooth surfaces deposited with MnO₂ nanospheres and pores of 138.4 – 235.3 µm width. The influences of adsorbent dosage, initial pH, acetaminophen concentration, temperature and contact time were investigated. It was determined that the adsorption of acetaminophen occurred on uniform sorption sites in the aerogel, as suggested by the best fit of data to the Langmuir isotherm, yielding a maximum adsorption capacity of 252.87 mg/g. This highest adsorption performance of the 3D MnO₂/rGO aerogel was attained at a dosage of 0.6 g/L, initial pH of 6.2 and temperature of 40°C. The process kinetics were in-line with the pseudo-first-order and pseudo-second-order kinetics at 10 and 20 – 500 mg/L concentrations, respectively. Thermodynamic assay showed the spontaneity and endothermicity features of the 3D MnO₂/rGO-acetaminophen system. The acetaminophen adsorption mechanisms were mainly hydrogen bonding and pore entrapment. Moreover, the as-synthesised aerogel was effectively regenerated using acetone and re-utilised in four adsorption-desorption cycles. Overall, the results highly recommend the implementation of the 3D MnO₂/rGO hybrid aerogel for purification of wastewater polluted by acetaminophen residue.     

Unravelling the molecular mechanism of mutagenic factors impacting human health

Environmental Science and Pollution Research - Environmental mutagens are chemical and physical substances in the environment that has a potential to induce a wide range of mutations and generate...     

Durability analysis and optimization of a binary system of waste cement concrete and glass-based geopolymer mortar

Journal of Material Cycles and Waste Management - Enormous generation of construction and demolition (C&D) waste along with municipal solid waste (MSW) is required to managed properly for...     

FDM-based additive manufacturing of recycled thermoplastics and associated composites

Journal of Material Cycles and Waste Management - Hailed since the fourth industrial revolution, three-dimensional (3D) printing or additive manufacturing (AM) has been extensively implemented in...     

Multi-decadal groundwater variability analysis using geostatistical method for groundwater sustainability

Environment, Development and Sustainability - The general aim of the present study was to understand the groundwater level change of period 2001–2020 using geostatistical analysis at village...     

Paternal factors in recurrent pregnancy loss: an insight through analysis of non-synonymous single-nucleotide polymorphism in human testis-specific chaperone HSPA2 gene

Environmental Science and Pollution Research - Heat shock protein A2 (HSPA2) is a testis-specific molecular chaperone of the 70 kDa heat shock protein (HSP70) family and reported to play a key role...