Sustainable land application: an overview

Man has land-applied societal nonhazardous wastes for centuries as a means of disposal and to improve the soil via the recycling of nutrients and the addition of organic matter. Nonhazardous wastes include a vast array of materials, including manures, biosolids, composts, wastewater effluents, food-processing wastes, industrial by-products; these are collectively referred to herein as residuals. Because of economic restraints and environmental concerns about land-filling and incineration, interest in land application continues to grow. A major lesson that has been learned, however, is that the traditional definition of land application that emphasizes applying residuals to land in a manner that protects human and animal health, safeguards soil and water resources, and maintains long-term ecosystem quality is incomplete unless the earning of public trust in the practices is included. This overview provides an introduction to a subset of papers and posters presented at the conference, "Sustainable Land Application," held in Orlando, FL, in January 2004. The USEPA, USDA, and multiple national and state organizations with interest in, and/or responsibilities for, ensuring the sustainability of the practice sponsored the conference. The overriding conference objectives were to highlight significant developments in land treatment theory and practice, and to identify future research needs to address critical gaps in the knowledge base that must be addressed to ensure sustainable land application of residuals.     

Phosphorus leaching in sandy outwash soils following potato-processing wastewater application

Land application of wastewater presents potential for ground water pollution if not properly managed. In situ breakthrough tests were conducted using potato (Solanum tuberosum L.)-processing wastewater and a Br tracer to characterize P leaching in seasonally frozen sandy outwash soils. In the first test, P and Br breakthrough were measured in a 7-m deep well following wastewater [2.94 mg L(-1) total P (TP); 280 mg L(-1) Br] application at the site that had 13.1 mg water-extractable P (WEP) kg(-1)and 94.4 mg Bray-1 P kg(-1). Bromide was detected in the well after approximately 0.4 pore volumes, but there was no P break-through after 7 pore volumes. In the second breakthrough test, wastewater containing 3.6 mg L(-1) TP and 259 mg L(-1) Br was applied on 1.5-m deep lysimeters at low (0.8 mg WEP kg(-1); 12.1 mg Bray-1 P kg(-1)) and high soil test P sites (104 mg WEP kg(-1); 585 mg Bray-1 P kg(-1)). Leachate TP concentration during the test remained constant (0.04 mg L(-1)) at the low P sites but increased from approximately 3.5 to 5.6 mg L(-1) at the high P sites. These results indicate no P leaching in low P soils, but leaching in high P soils, thus suggesting that most of the P leached at the high P sites was mainly due to desorption and dissolution of weakly adsorbed P from prior P applications. This was consistent with P transport simulations using the convective-dispersive equation. We conclude that P concentration in land-applied wastewater should be regulated based on soil test-P level plus wastewater P loading.     

BASE FLOW TRENDS IN URBANIZING WATERSHEDS OF THE DELAWARE RIVER BASIN1

Rapid land development is raising concern regarding the ability of urbanizing watersheds to sustain adequate base flow during periods of drought. Long term streamflow records from unregulated watersheds of the lower to middle Delaware River basin are examined to evaluate the impact of urbanization and imperviousness on base flow. Trends in annual base flow volumes, seven‐day low flows, and runoff ratios are determined for six urbanizing watersheds and four reference watersheds across three distinct physiographic regions. Hydrograph separation is used to determine annual base flow and stormflow volumes, and nonparametric trend tests are conducted on the resulting time series. Of the watersheds examined, the expected effects of declining base flow volumes and seven‐day low flows and increasing stormflows are seen in only one watershed that is approximately 20 percent impervious and has been subject to a net water export over the past 15 years. Both interbasin transfers and hydrologic mechanisms are invoked to explain these results. The results show that increases in impervious area may not result in measurable reductions in base flow at the watershed scale.     

Observations on the function of the glands of the foot of the pediveliger of Ostrea edulis during settlement

The use during settlement of secretions of the 9 different types of gland in the foot of the pediveliger of Ostrea edulis L. was examined experimentally. During settlement, there is a progressive decrease in the crawling speed of the larva and a strengthening of its bond with the substratum. Both changes are related to (a) a change from ciliary to muscular pedal locomotion; (b) the increasing acidity and viscosity of the mucoid secretions used; (c) the secretion of a byssus thread by the glands of the byssus duet; (d) changes in the form and composition of this byssus. At the termination of settlement, the entire contents of 2 types of gland are discharged. Their secretions give rise to the cement which permanently fixes the larva to the substratum. The 9 types of gland are utilised sequentially in a manner closely related to the 6 phases recognised in settlement behaviour.     

Ammonia emission from grassland and livestock production systems in the UK

Emissions of ammonia were measured from livestock excreta and fertilisers applied to grass swards, from grazed paddocks, from decomposing grass herbage and from an animal house containing dairy cows. Emissions from urine, dung, slurry and fertilisers were determined using a system of wind tunnels with each tunnel covering an area of 1 m(2). Emissions from grazed swards were determined using a micrometeorological mass balance method. From the results of these measurements, together with other published information, an inventory for ammonia emissions has been calculated for grassland and livestock production systems over the UK as a whole. It is estimated that emissions from grassland and cattle and sheep production amount to about 230 kt NH(3)-N annually, while emissions from pig and poultry production amount to about 40 kt and 80 kt NH(3)-N, respectively.     

Trace metals in the hair of habitants of the Ok Tedi region, Papua New Guinea

It has long been known that mining activity can markedly change the level and distribution of certain heavy metals in the adjacent environment. This pollution can be quite widespread and long lasting and often has deleterious effects on the health of local populations. In the present study scalp hair was used as the biopsy material because of its ease of collection and long history of use in this connection. Hair was collected from all the local villages in the vicinity of the mine site, as well as from Papua New Guinean nationals from other provinces, and European expatriates who were employed by the mining company and who were resident in the area. Hair from local people showed a remarkably high iron content by comparison with previously studied populations. The extreme variations in hair iron levels were reflected in the differential distribution of levels according to location, age and sex. Hair cadmium was also high in the population studied. Hair copper, lead, zinc and mercury all appeared to be within 'normal' limits by comparison with other general populations. These results are discussed in the context of the environmental and social impact of the mining operations on the local people.     

The fate of metal contaminated sediments in Foundry Cove, New York

The distribution of heavy metal contaminated sediments in Foundry Cove, a freshwater embayment of the Hudson River, was examined twelve years after the discharging of wastes from a battery factory had ceased. Concentrations of Cd, Ni and Co were measured in surficial sediments (top 5 cm) and seven detailed depth profiles. Comparison with earlier surveys showed that metal levels of surficial sediments have been considerably reduced throughout the cove. Evidence suggests that this reduction may be largely due to burial rather than transport of metals out of the cove or a redistribution (via sediment resuspension and redeposition) within the cove. This is suggested by the presence of a peak in metal concentrations at a depth of several centimetres in depositional environments, a calculation showing the loss of waterborne cadmium to be much less than the amount of cadmium lost from the surficial sediment, and the absence of increased pollution in the cleaner parts of the cove. Despite improvement, metal levels remain extremely high, including a persistent 'hot-spot' with levels higher than 10 000 ppm Cd.     

Dissolved organic matter fractions formed during composting of winery and distillery residues: evaluation of the process by fluorescence excitation-emission matrix

The aim of the present paper is to assess the maturity degree reached by different samples of several mixtures from winery and distillery residues composted using the Rutgers composting system, by means of excitation-emission matrix (EEM) fluorescence spectroscopy. The composts were sampled once a week for about 200d. EEM spectra indicate the presence of different fluorophores. The fluorescence intensities of these peaks show trends related to the maturity of the composting samples selected. The "contour density" of EEM maps is strongly modified through time. We have used the quantitative method of fluorescence regional integration (FRI). The EEMs were delineated into five excitation-emission regions. The degree of compost maturity could be correlated with the percentage of the volumetric integration under the EEM within each region. Further refinement of these techniques should provide a relatively rapid method for assessing the suitability of the compost to soil application.     

The sensitivity of surface waters of Great Britain to acidification predicted from catchment characteristics

Using a combination of soil, land use and geological information, a map of Great Britain has been derived which indicates the sensitivity of surface waters to acidification. For the geological information, a slightly modified version of an available map was used which indicated the sensitivity of groundwaters to acidification. For soils, 1-km databases of soil information for England and Wales and for Scotland were employed to map the soil sensitivity as determined by buffering capacity. The derived soils map was modified to take account of agricultural liming in arable and managed grassland areas using the ITE Land Classification. The final map of surface water sensitivity was obtained by using a geographic information system overlay procedure which enabled each combination of soil and geology sensitivity to be uniquely defined. The final sensitivity classification was based upon expert knowledge and the experience of a similar sensitivity mapping exercise for Wales.