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101.
Noel JD Biswas P Giammar DE 《Journal of the Air & Waste Management Association (1995)》2007,57(7):856-867
Leaching of mercury from coal combustion byproducts is a concern because of the toxicity of mercury. Leachability of mercury can be assessed by using sequential extraction procedures. Sequential extraction procedures are commonly used to determine the speciation and mobility of trace metals in solid samples and are designed to differentiate among metals bound by different mechanisms and to different solid phases. This study evaluated the selectivity and effectiveness of a sequential extraction process used to determine mercury binding mechanisms to various materials. A six-step sequential extraction process was applied to laboratory-synthesized materials with known mercury concentrations and binding mechanisms. These materials were calcite, hematite, goethite, and titanium dioxide. Fly ash from a full-scale power plant was also investigated. The concentrations of mercury were measured using inductively coupled plasma (ICP) mass spectrometry, whereas the major elements were measured by ICP atomic emission spectrometry. The materials were characterized by X-ray powder diffraction and scanning electron microscopy with energy dispersive spectroscopy. The sequential extraction procedure provided information about the solid phases with which mercury was associated in the solid sample. The procedure effectively extracted mercury from the target phases. The procedure was generally selective in extracting mercury. However, some steps in the procedure extracted mercury from nontarget phases, and others resulted in mercury redistribution. Iron from hematite and goethite was only leached in the reducible and residual extraction steps. Some mercury associated with goethite was extracted in the ion exchangeable step, whereas mercury associated with hematite was extracted almost entirely in the residual step. Calcium in calcite and mercury associated with calcite were primarily removed in the acid-soluble extraction step. Titanium in titanium dioxide and mercury adsorbed onto titanium dioxide were extracted almost entirely in the residual step. 相似文献
102.
Scrubbers are used as particulate emission control devices with the increase in stringency of old regulations or promulgation of new regulations. Scrubbing of fly ash in a novel dual flow scrubber, i.e., one water filled bubble section and one section with water-spray, is reported in this article. The presented system included a tapered section in order to achieve the bubble regime. On the other hand, a two-phase critical flow atomizer was used for the generation of spray regime with high degree of spray uniformity. Experiments were carried out for studying the behavior of the system in terms of various pertinent variables. The fly ash removal mechanism was explained in terms of various physical interactions. Electrostatic effect was found to have an insignificant influence on the collection efficiency of fly ash. The removal efficiency was found to decrease with the increase in inlet fly ash loading in the bubble section while it was increased in the spray section. A compromise must, therefore, be struck while operating the scrubber for achieving the desired performance. The effects of other operating variables studied on the removal efficiency remained similar in the regimes under investigation. The combined effect was, however, that the spray regime was dominating. Experimentation also revealed that the bubble section collected particles down to 20 microm size. Detailed experimentation revealed that almost 100% removal efficiency (zero penetration) of fly ash could be achieved in the dual flow scrubber at a QL/QG ratio of 3.0 m3/1000 ACM (actual cubic meter). Almost zero penetration of fly ash particles, clearly demonstrated that the dual flow scrubber with its staging operations met with the stricter emission regulations for particulate matter. Selection of any particulate control device is intrinsically related to the performance as a function of various pertinent variables of the system. Correlations were, therefore, put forward for the prediction of the performances of the bubble and the spray sections in terms of various pertinent variables of the system. The overall removal efficiency achievable in the dual flow scrubber was predicted with the help of these correlations. The predicted values were in excellent agreement with the experimental values (well within +/-5.0% deviation). Comparison of the performance of the present system with the existing systems indicated that the bubble and spray sections either alone or in combination (as in a dual flow scrubber), was energy and efficiency-wise much better than the existing systems. The novelty of the system is also described. 相似文献
103.
Francis L. Smith George A. Sorial Makram T. Suidan Amit Pandit Pratim Biswas Richard C. Brenner 《Journal of the Air & Waste Management Association (1995)》2013,63(7):627-636
ABSTRACT The 1990 Amendments to the Clean Air Act have stimulated strong interest in the use of biofiltration for the economical, engineered control of volatile organic compounds (VOCs) in effluent air streams. Trickle bed air biofilters (TBABs) are especially applicable for treating VOCs at high loadings. For long-term, stable operation of highly loaded TBABs, removal of excess accumulated bio-mass is essential. Our previous research demonstrated that suitable biomass control for TBABs was achievable by periodic backwashing of the biofilter medium. Backwashing was performed by fluidizing the pelletized biological attachment medium with warm water to about a 40% bed expansion. This paper presents an evaluation of the impact of backwashing on the performance of four such TBABs highly loaded with toluene. The inlet VOC concentrations studied were 250 and 500 ppmv toluene, and the loadings were 4.1 and 6.2 kg COD/m3 day (55 and 83 g toluene/m3 hr). Loading is defined as kg of chemical oxygen demand per cubic meter of medium per day. Performance deterioration at the higher loading was apparently due to a reduction of the specific surface of the attached biofilm resulting from the accumulation of excess biomass. For a toluene loading of 4.1 kg COD/m3 day, it was demonstrated that the long-term performance of biofilters with either inlet concentration could be maintained at over 99.9% VOC removal by employing a backwashing strategy consisting of a frequency of every other day and a duration of 1 hr. 相似文献
104.
Toshiaki Hayashi Tai Gyu Lee Melynda Hazelwood Elizabeth Hedrick Pratim Biswas 《Journal of the Air & Waste Management Association (1995)》2013,63(6):922-929
ABSTRACT The use of activated carbon fiber (ACF) filters for the capture of particulate matter and elemental Hg is demonstrated. The pressure drop and particle collection efficiency characteristics of the ACF filters were established at two different face velocities and for two different aerosols: spherical NaCl and combustion-generated silica particles. The clean ACF filter specific resistance was 153 kg m-2 sec-1. The experimental specific resistance for cake filtration was 1.6 × 106 sec-1 and 2.4 × 105 sec-1 for 0.5- and 1.5-μm mass median diameter particles, respectively. The resistance factor R was approximately 2, similar to that for the high-efficiency particulate air filters. There was a discrepancy in the measured particle collection efficiencies and those predicted by theory. The use of the ACF filter for elemental Hg capture was illustrated, and the breakthrough characteristic was established. The capacity of the ACF filter for Hg capture was similar to other powdered activated carbons. 相似文献
105.
106.
Sinha J Biswas CK Ghosh A Saha A 《Journal of environmental biology / Academy of Environmental Biology, India》2010,31(3):287-292
Vermicompost is a very important biofertilizer produced through the artificial cultivation of worms i.e. Vermiculture. Vermicompost is enriched with all beneficial soil bacteria and also contain many of the essential plant nutrients like N, P, K and micronutrients. It increases soil aeration, texture and jilt. In this work, study is being carried out to find out the effect of different fertilizers such as DAF, FYM and Vermicompost on various morphological parameters and on the in vitro growth of bacterial colonies and its diversity in relation to two important leguminous plants such as Pisum sp. and Cicer sp. Results showed that plant grown in Vermicompost pretreated soil exhibited maximum increase in all morphological parameters such as root length, shoot length, number of root branches, number of stem branches, number of leaves, number of flowers, number of pods and number of root nodules in four months sampling in comparison to untreated, FYM treated and DAP treated soils. Further in Vermicompost pretreated soil, number of N2 fixing bacterial colony was maximum and showed highest diversity indices (1.6 and 0.99 and 2.0 and 0.99 for Cicer sp. and Pisum sp. respectively) than FYM, DAP and untreated control. Thus not only does the Vermicompost stimulate plant growth but also it increases the N2 fixing bacterial population in soil and also its diversity. 相似文献
107.
Bakshi Madhurima Ghosh Somdeep Ram S. S. Sudarshan M. Chakraborty Anindita Biswas Jayanta Kumar Shaheen Sabry M. Niazi Nabeel Khan Rinklebe Jörg Chaudhuri Punarbasu 《Environmental geochemistry and health》2019,41(1):275-296
Environmental Geochemistry and Health - Mangroves have wide applications in traditional medicines due to their several therapeutic properties. Potentially toxic elements (PTEs), in mangrove... 相似文献
108.
109.
Debojit Baruah Lakhi P. Hazarika Bikramaditya Bakalial Sabita Borah Ranjit Dutta S. P. Biswas 《The Environmentalist》2012,32(1):85-90
The Ganges River dolphin (Platanista gangetica Roxburgh) of Subansiri River may be in great danger of extinction due to the construction of the 2,000-MW Lower Subansiri
Hydroelectric Project, which started in 2006. A recent survey indicates that there are now 29 Ganges dolphins, up from 21
in 2006. It is feared that drastic changes would occur in the downstream hydrology and ecology of the Subansiri River after
the installation of the project, scheduled for 2012. The water discharge during a major part of the day in dry months would
come down to a meager 6 cumecs from the present average of 450 cumecs (1 cumec is shorthand for cubic meter per second; also
cms, or m3/s (m3s–1). Riverine mega fauna like the dolphin would be worst hit by this extremely low discharge. Dumping of an extra amount of
sediment from different construction phases has already increased sediment load in the Subansiri downstream and degraded some
earlier pockets of dolphin up to 20 km below the dam site. There is reason to believe that high sediment influx might have
silted up some of the deeper pools downstream, a preferred habitat of dolphins, forcing them to congregate close to the confluence
of the Subansiri. 相似文献
110.
Angsumita Pramanick Abhiram Kanneganti Jing Lin Jeslyn Wong Sarah Weiling Li Pooja Sharma Dimri Aniza Puteri Mahyuddin Sailesh Kumar Sebastian Enrique Illanes Jerry Kok Yen Chan Lin Lin Su Arijit Biswas Paul Anantharajah Tambyah Ruby Yun-Ju Huang Citra Nurfarah Zaini Mattar Mahesh Choolani 《黑龙江环境通报》2021,41(8):1018-1035
There are over 50 SARS-CoV-2 candidate vaccines undergoing Phase II and III clinical trials. Several vaccines have been approved by regulatory authorities and rolled out for use in different countries. Due to concerns of potential teratogenicity or adverse effect on maternal physiology, pregnancy has been a specific exclusion criterion for most vaccine trials with only two trials not excluding pregnant women. Thus, other than limited animal studies, gradually emerging development and reproductive toxicity data, and observational data from vaccine registries, there is a paucity of reliable information to guide recommendations for the safe vaccination of pregnant women. Pregnancy is a risk factor for severe COVID-19, especially in women with comorbidities, resulting in increased rates of preterm birth and maternal morbidity. We discuss the major SARS-CoV-2 vaccines, their mechanisms of action, efficacy, safety profile and possible benefits to the maternal-fetal dyad to create a rational approach towards maternal vaccination while anticipating and mitigating vaccine-related complications. Pregnant women with high exposure risks or co-morbidities predisposing to severe COVID-19 infection should be prioritised for vaccination. Those with risk factors for adverse effects should be counselled accordingly. It is essential to support patient autonomy by shared decision-making involving a risk-benefit discussion with the pregnant woman. 相似文献