This study aimed to investigate the removal mechanisms of pharmaceutical active compounds (PhACs) and musks in a wastewater treatment plant (WWTP). Biological removal and adsorption in the activated sludge tank as well as the effect of UV radiation used for disinfection purposes were considered when performing a mass balance on the WWTP throughout a 2-week sampling campaign.
Methods
Solid-phase extraction (SPE) was carried out to analyse the PhACs in the influent and effluent samples. Ultrasonic solvent extraction was used before SPE for PhACs analysis in sludge samples. PhAC extracts were analysed by LC-MS. Solid-phase microextraction of liquid and sludge samples was used for the analysis of musks, which were detected by GC-MS. The fluxes of the most abundant compounds (13 PhACs and 5 musks) out of 79 compounds studied were used to perform the mass balance on the WWTP.
Results
Results show that incomplete removal of diclofenac, the compound that was found in the highest abundance, was observed via biodegradation and adsorption, and that UV photolysis was the main removal mechanism for this compound. The effect of adsorption to the secondary sludge was often negligible for the PhACs, with the exceptions of diclofenac, etofenamate, hydroxyzine and indapamide. However, the musks showed a high level of adsorption to the sludge. UV radiation had an important role in reducing the concentration of some of the target compounds (e.g. diclofenac, ibuprofen, clorazepate, indapamide, enalapril and atenolol) not removed in the activated sludge tank.
Conclusions
The main removal mechanism of PhACs and musks studied in the WWTP was most often biological (45%), followed by adsorption (33%) and by UV radiation (22%). In the majority of the cases, the WWTP achieved >75% removal of the most detected PhACs and musks, with the exception of diclofenac. 相似文献
Olive oil mill wastewater (OOMW) environmental impacts minimization have been attempted by developing more effective processes,
but no chemical or biological treatments were found to be totally effective to mitigate their impact on receiving systems.
This work is the first that reports simultaneously the efficiency of three different approaches: biological treatment by two
fungal species (Trametes versicolor or Pleurotus sajor caju), enzymatic treatment by laccase, and chemical treatment by photo-Fenton oxidation on phenols removal. 相似文献
The rapid industrialization and urbanization of an area require quick preparation of actual land use/land cover (LU/LC) maps in order to detect and avoid overuse and damage of the landscape beyond sustainable development limits. Remote sensing technology fits well for long-term monitoring and assessment of such effects. The aim of this study was to analyze LU/LC changes between 1980 and 1999 in Samsun, Turkey, using satellite images. Three Landsat images from 1980, 1987 and 1999 were used to determine changes. A post classification technique was used based on a hybrid classification approach (unsupervised and supervised). Images were classified into six LU/LC types; urban, agriculture, dense forest, open forest-hazelnut, barren land and water area. It is found that significant changes in land cover occurred over the study period. The results showed an increase in urban, open forest/hazelnut, barren land and water area and a decrease in agriculture and dense forest in between 1980 and 1999. In this period, urban land increased from 0.77% to 2.47% of the total area, primarily due to conversions from agricultural land and forest to a lesser degree. While the area of dense forest decreased from 41.09% to 29.64% of the total area, the area of open forest and hazelnut increased from 6.73% to 11.88%. 相似文献
A greater understanding of gendered roles in fisheries is necessary to value the often-hidden roles that women play in fisheries and households. We examine women’s contributions to household food and income using focus group discussions, market surveys, and landings data in six communities in Timor-Leste. Women were actively fishing more days per month than men. Gleaning was the most frequent activity and 100% of trips returned with catch for food and/or income. Mollusc and crab catches were common and exploitation appeared targeted on a dynamic reappraisal of changing food values and changing estimates of group needs. With as many as 80% of households in coastal areas involved in fishing, and at least 50% of women fishing, this highlights the current lack of women’s engagement as a critical gap in fisheries management approaches. The current androcentric dialogue limits social-ecological understanding of these systems and the potential for their effective stewardship.Electronic supplementary materialThe online version of this article (10.1007/s13280-020-01335-7) contains supplementary material, which is available to authorized users. 相似文献
Annoyance caused by air pollution is a matter of public health as it can cause stress and ill-health and affect quality of life, among other burdens. The aim of this study is to apply the multiple correspondence analyses (MCA) technique as a differential tooling to explore relationships between variables that can influence peoples’ behaviour concerning annoyance caused by air pollution. Data were collected through a survey on air pollution, environmental issues and quality of life. Face-to-face survey studies were conducted in two industrialized urban areas (Vitoria in Brazil and Dunkirk in France). These two regions were chosen as their inhabitants often report feeling annoyed by air pollution, and both regions have similar industrial characteristics. The results showed a progressive correspondence between levels of annoyance and other active variables in the “air pollution” factor group: as the levels of annoyance increased, the levels of the other qualitative variables (importance of air quality, perceived exposure to industrial risk, assessment of air quality, perceived air pollution) also increased. Respondents who reported feeling annoyed by air pollution also thought that air quality was very important and were very concerned about exposure to industrial risks. Furthermore, they often assessed air quality as horrible, and they could frequently perceive air pollution by dust, odours and decreased visibility. The results also showed a statistically significant association between occurrence of allergies and high levels of annoyance.
The objective of this research is to discuss the relationship between the growth of livestock and the environmental impact it generates in Colombia. For this, data were extracted from the FAO STAT for the period of 1961 to 2017. The livestock inventory has had a significant growth during the last 50 years. This has generated environmental exposure and the release of carbon, sequestered by continuous deforestation performed in the practice of extensive livestock. Recurring to vector error correction models, we observed the existence of long-term relations between CO2 emissions from dairy cattle and emissions from slaughtered cattle, deforestation, pastures, and forest development. Changes in CO2 emissions from dairy cattle tend to be anticipated by changes in CO2 emissions from the other analyzed sources, which prove how the current investment in dairy cattle results from the accumulated debates in Colombia regarding the different sources of livestock emissions.
In spite of its outstanding ecological and touristic importance the Ria Formosa Lagoon shows signs of anthropogenic pollution. Nonetheless, until the present survey no studies had ever documented the measurement of natural and pharmaceutical estrogens (17β-estradiol, estrone, and 17α-ethynylestradiol), xenoestrogenic industrial pollutants (4-octylphenol, 4-nonylphenol, and their mono and diethoxylates and bisphenol A), phytoestrogens (formononetin, biochanin A, daidzein, genistein), and sitosterol in this area. The 17 compounds measured herein are known as endocrine disrupters (EDCs) and act over the endocrine system even in few amounts (ng L?1–μg L?1). Thus to conclude about the influx of EDCs in the lagoon, water samples were taken every 2 months, during 1 year (2010), in low tide at nine sites distributed along the coastline. Water samples (1 L) were preconcentrated in the Oasis HLB cartridges and cleaned in silica cartridges before their analysis by GC-MS. Data showed the ubiquitous presence of potentially hazardous amounts of estrogens (particularly of ethynylestradiol, up to 24.3 ng L?1), nonylphenol (up to 547 ng L?1), and sitosterol (up to 12,300 ng L?1), mainly in summer, suggesting that the increase of the local number of inhabitants (tourists), the rise of the water temperature (up to 26 °C), and the blooming of local flora may interfere with the water quality parameters. This makes the lagoon a potential model to study. Taking into account the data, it was concluded that there are conditions for the occurrence of endocrine disruption in aquatic animals, even in areas included in the natural park of the Formosa. Besides, both the high amounts of un-ionized ammonia (up to 0.3 mg L?1) and phosphates (up to 1.6 mg L?1) my pose risks for local fauna and humans. 相似文献
In the middle of the 1970s, the introduction of large industrial and agricultural projects in Brazilian Amazonia created
a situation of violence and loss of land used by farming families. In this context, the process of migration to the metropolitan
region of Belém, which is principally in the interior of the state of Pará, was intensified. Excluded by the formal labor
market, these families started to collect disposed material as scavengers. The material collected is found in landfills, streets,
and open dumping areas. The main purpose of this research is to understand the social and environmental relations inherent
in collection and recycling activities in the Amazon Region.
Received: August 19, 2001 / Accepted: November 21, 2001 相似文献
