Recent changes (1973–2014 versus 1903–1972) in the flow regime of the Lower Paraná River and current fluvial pollution warnings in its Delta Biosphere Reserve

Alterations in flow regimes of large rivers may originate or increase risks to ecosystems and humans. The Paraná River basin (South America) undergoes human pressures (e.g., heavy damming in the upper basin, deforestation, and mixed pollution) that may affect the water quantity and quality of its terminal Delta (Argentina). In this study, after applying univariate and multivariate change-point detection and trend analyses to the daily data series of flows incoming to the Delta (Paraná-Santa Fe section), flow characteristics were compared by Indicators of Hydrologic Alteration (IHA) and Environmental Flow Components (EFC). Some flood characteristics were also compared from hydrometric levels in the middle Delta (San Pedro station). Chemical and microbiological water variables in the main rivers of the “Paraná Delta” Biosphere Reserve were examined during two extreme hydrologic years (October 2008 to July 2010) to detect potential risk factors in association with hydrologic conditions. In the Lower Paraná River, a historical period (1903–1972) and two more altered periods (1973–1999 wet period and 2000–2014 dry period) were identified. Flow duration curves evidenced different changes in both altered periods, reflecting the joint effect of climatic variability and human influence. The most evident alterations in the flow regime were the lack of record of the extreme-low-flow component, the attenuation of monthly flow seasonality, and the increase in the number of reversals (dry period) and in the variability of maximum and minimum flow dates. These alterations are consistent with the monthly and daily flow regulation by upstream dams evidenced by available data from the current dry period. In the middle Delta, the marked monthly seasonality in flood days decreased only in the wet period. The proportion between the number of flood days exceeding the evacuation level and that of those exceeding the warning level doubled in the wet period but decreased only slightly in the dry period. In the Delta Reserve rivers, concentrations of Escherichia coli, cadmium, lead, iron, manganese, and ammonium exceeded guideline levels under a severe drought and a dispersal of cyanobacteria appeared under a high-flow pulse in La Niña year. The ammonium concentration exceeded the level for human drink with the overbanking flood stage in El Niño year. These occasional detections pose a potential risk to the aquatic life and, especially, to the inhabitants of the Reserve. Flow duration curves, IHA, and EFC are useful tools to evaluate trends or changes of ecological and social relevance in flow regime characteristics.     

Vulnerability of Catalan (NW Mediterranean) ports to wave overtopping due to different scenarios of sea level rise

The overtopping of port breakwaters may affect the assets located at the breakwater lee side. If adaptation measures are not taken, the sea level rise will increase the overtopping discharges putting those assets at significant risk. This study compares, at a regional scale, overtopping discharges over port breakwaters for three storm conditions (return periods of 1, 5 and 50 years) under present climate as well as for three scenarios of sea level rise based on recent projections. The results indicate that, for the worst storm and sea level rise conditions, the overtopping discharge would not be negligible (larger than 1 l/s/m) in 35 ports (84 %), in contrast to only 18 ports (42 %) being affected under present conditions. In addition, in 28 ports (65 %) the overtopping would be at least one order of magnitude larger than for present conditions. In the case of large storms, in 2 ports the overtopping discharge exceeds 200 l/s/m (the discharge that can initiate breakwater damage) under present conditions, while in the worst scenario of sea level rise the number of ports exceeding this value would be 7. On the other hand, the vulnerability of each port for which overtopping flow is greater than an acceptable discharge flux is assessed, and regional maps of vulnerability are plotted. For the worst storm conditions, 23 % of the Catalan ports have risks associated with overtopping under present climate conditions. This percentage would increase to 47 % in the worst sea level rise scenario.     

Maximum power point tracking methods for photovoltaic systems operating under partially shaded or rapidly variable insolation conditions: a review paper

To increase the efficiency of photovoltaic (PV) systems, maximum power point (MPP) tracking of the solar arrays is needed. Under partially shaded conditions (PSCs), the solar arrays power–current (P–I) characteristic has multiple MPP. This paper presents various methods and approaches of tracking the MPP from a PV generator operating under PSC. Some comparisons, advantages, drawbacks and critical analysis of each method are discussed. It was found that, indirect methods use empirical data or mathematical expressions of numerical approximations to estimate the MPP from the PV generator’s voltage, current and irradiance. Direct methods offer the advantage of obtaining the actual maximum power from the PV generator’s voltage and current. Artificial intelligence methods do not need exact mathematical models. They can perform under parameter variation, load and supply voltage disturbances. Finally, novel methods require less number of iterations to converge, independent to the initial conditions. All these algorithms can be included in some of the DC/DC converters and MPP trackers for stand-alone or grid-connected systems.     

Assessment of the mechanisms of detoxification of chemical compounds and antioxidant enzymes in the digestive gland of mussels, Mytilus galloprovincialis, from Mediterranean coastal sites

In this study the effects of the main marine pollutants (metals, PAHs, PCBs and DDTs) were assessed in native mussels from the Mediterranean coast of Spain. For this purpose several biomarkers such as benzo[a]pyrene hydroxylase (BPH), DT-diaphorase (DTD), glutathione S-transferase (GST), superoxide dismutase (SOD), catalase (CAT), glutathione peroxidases (GPs), glutathione reductase (GR), metallothionein (MT) and lipid peroxidation (LPO) were measured in the digestive gland. Results showed increased LPO levels in mussels which accumulated high loads of organic compounds and arsenic in their tissues. BPH levels correlated to the concentrations of organic compounds in mussel tissues, though the range of BPH response was low in relation to the high gradient of accumulation of organic pollutants. Increased BPH levels, concomitant to low DTD and GST activities, were detected in mussels which presented high levels of organic pollutants in their tissues. This suggests that signs of LPO present in these organisms are related to the imbalance between phase I and phase II biotransformation processes. Furthermore, the increased levels of MT and CAT detected in mussels which showed high levels of Cd in their tissues appear to reflect a coordinated response which protects against the toxicity of this metal. The application of these biomarkers in environmental assessment is discussed.     

Ecotoxicological assessment of doxycycline in soil

Doxycycline has been used in continually increasing quantities for mass treatment of food animals because of its greater bioavailability relative to older tetracyclines. The study presented in this paper was undertaken to investigate the degradation rate of the tetracycline derivative in manure-amended soil. In the present experiment, following composting, the doxycycline-contaminated manure was applied to agricultural land, and a field study was performed to investigate the degradation rate of doxycycline in soil. By the end of the 20-week sampling period, about 20 %, 33 % and 18 % of the initial doxycycline concentrations could be measured in soil samples taken at three different soil depths. The calculated half-life of doxycycline in the soil was 66.5, 76.3 and 59.4 days at depths of 0 cm, 25 cm and 50 cm, respectively. The potential effect of doxycycline on soil microbial activity was demonstrated by the nitrogen transformation test performed in compliance with the Organisation for Economic Co-operation and Development (OECD) Guideline No. 216. On day 28, the following nitrate concentrations of the control soil sample were found in the soil samples treated with different amounts of doxycycline: 76.9 %, 53.0 %, 65.6 %, 59.7 % and 77.1 %.     

Socio-economic research in support of climate policy development: Mistra's Research Program Clipore

Mistra's Climate Policy Research Program, Clipore, is one of the largest research programs directed to support international climate policy development, involving research groups in Sweden, Norway, United States and India. It has been running from 2004 to 2011 with a budget of more than 100 MSEK (15?M USD). The paper briefly describes the program and its outcomes in relation to climate policy development. Discussion focuses on how the program has been able to be in the front of and include the development of emissions trading systems in Europe and the United States and how the program has been able to follow and produce inputs to the agenda of the United Nations Framework Convention on Climate Change (UNFCCC). The paper also discusses how the program has managed to present its outcomes and maintain an active dialogue with the various stakeholders. The paper emphasises options and obstacles in the communication between science and policy.     

Effect of the pH and temperature on the biosorption of lead(II) and cadmium(II) by sodium-modified stalk sponge of Zea mays

Objective  

The present work was carried out to investigate the effects of temperature, initial pH, initial concentration, and contact time on the biosorption of lead (Pb) and cadmium (Cd) by modified stalk sponge of Zea mays using a batch technique.     

Ecological monitoring of wetlands in semi-arid region of Konya closed Basin, Turkey

Wetland ecosystems are of global significance having productive, regulatory and informative function. These wetlands are crucial for the long-term protection of water sources, as well as the survival of its unique biodiversity. Most of the wetlands of Turkey are now facing serious threat from the anthropogenic sources and now near to the verge of extinction. This study has been carried out to monitor vegetation dynamics and ecological status of wetlands of Koyna basin at spatial and temporal scale. This study has involved MODerate-resolution Imaging Spectroradiometer (MODIS) images of the year 2000, 2004 and 2008 on daily basis with spatial resolution of 1 km. The MODIS 16 days composite NDVI time series products of 250-m spatial resolution from year 2000 to 2008 has been utilized to monitor the ecological status of the wetlands. The European Nature Information System habitat classification map, meteorological data (precipitation, temperature) coupled with field data has been utilized to validate NDVI values of nine habitats in the wetlands. The time series analyses of NDVI data values have been correlated with the groundwater level depth from 1996 to 2004. The overall analysis has shown a declining trend of NDVI over the year 2000 to 2008, indicated a degraded wetland condition in span of 9 years.     

Rare earth elements in the Rhine River, Germany: first case of anthropogenic lanthanum as a dissolved microcontaminant in the hydrosphere

The distribution of dissolved rare earth elements (REE) in the Rhine River, Germany, shows the anthropogenic gadolinium (Gd) microcontamination that is commonly observed in rivers in densely populated countries with a highly evolved health care system. However, the Rhine River also carries anomalously high concentrations of lanthanum (La), which produce very large positive La anomalies in normalized REE distribution patterns. These positive La anomalies first occur north of the City of Worms and then decrease in size downstream, but are still significant approximately 400 km downstream, close to the German-Dutch border. The strong La enrichment is of anthropogenic origin and can be traced back to effluent from a production plant for fluid catalytic cracking catalysts at Rhine river-km 447.4. This effluent is characterized by extremely high dissolved total REE and La concentrations of up to 52 mg/kg and 49 mg/kg, respectively. Such La concentrations are well-above those at which ecotoxicological effects have been observed. The Rhine River is the first case observed to date, where a river's dissolved REE inventory is affected and even dominated by anthropogenic La. Our results suggest that almost 1.5t of anthropogenic dissolved La is exported via the Rhine River into the North Sea per year. This reveals that the growing industrial use of REE (and other formerly "exotic" elements) results in their increasing release into the environment, and highlights the urgent need to determine their geogenic background concentrations in terrestrial surface waters.     

Personal care product use and urinary levels of phthalate metabolites in Mexican women

Sources of phthalates other than Polyvinyl chloride (PVC) related products are scarcely documented in Mexico. The objective of our study was to explore the association between urinary levels of nine phthalate metabolites and the use of personal care products. Subjects included 108 women who participated as controls in an ongoing population-based case-control study of environmental factors and genetic susceptibility to breast cancer in northern Mexico. Direct interviews were performed to inquire about sociodemographic characteristics, reproductive history, use of personal care products, and diet. Phthalate metabolites measured in urine by high performance liquid chromatography-isotope dilution tandem mass spectrometry were monoethyl phthalate (MEP), monobenzyl phthalate (MBzP), mono-n-butyl phthalate (MBP), mono-isobutyl phthalate (MiBP), mono-3-carboxypropyl phthalate (MCPP) as well as mono-2-ethylhexyl phthalate (MEHP), mono-2-ethyl-5-oxohexyl phthalate (MEOHP), mono-2-ethyl-5-hydroxyhexyl phthalate (MEHHP), mono-2-ethyl-5-carboxypentyl phthalate (MECPP) that are metabolites of di-ethylhexyl phthalate (DEHP). Detectable urinary concentrations of phthalate metabolites varied from 75% (MEHP) to 100% (MEP, MBP, MEOHP, MEHHP and MECPP). Medians of urinary concentrations of some phthalate metabolites were significantly higher among users of the following personal care products compared to nonusers: body lotion (MEHHP, MECPP and sum of DEHP metabolites (ΣDEHP)), deodorant (MEHP and ΣDEHP), perfume (MiBP), anti-aging facial cream (MEP, MBP and MCPP) and bottled water (MCPP, MEHHP and MEOHP). Urinary concentrations of MEP showed a positive relationship with the number of personal care products used. Our results suggest that the use of some personal care products contributes to phthalate body burden that deserves attention due to its potential health impact.