危险化学品公路运输事故原因分析与对策

笔者针对危险化学品的公路运输事故 ,从管理原因、人的失误、设备设施的缺陷、路况与环境影响等四方面原因逐一进行剖析 ,进而对政府部门和运输业户提出危险化学品公路运输事故的预防措施     

典型静电放电火花点燃危险性评价方法研究

通过研究典型静电放电火花的实际点燃能力 ,对实际生产工艺工程中的静电放电火花的点燃危险性进行定量评价。静电放电火花的放电相当能量、放电火花空间分布范围和放电火花持续时间 ,决定了静电放电火花实际点燃可燃物的可能性大小 ,因此不同类型的静电放电火花点燃可燃物的差异性很大。根据数据序列理论分析 ,引入静电放电火花点火源序列和可燃物危险性序列之间存在的关联性 ,反映了静电放电火花点燃可燃物的危险程度 ,可用于对静电放电火花的实际点燃危险性进行量化评价。对聚烯烃粉体生产工艺过程中典型和频发性的静电放电火花的点燃危险性进行了定量评价。     

三峡库区滑坡稳定性评价研究

三峡水库蓄水后 ,库水位将在 14 5～ 175m范围内波动 ,动水压力和水的软化作用是滑坡失稳的主要因素。库区滑坡稳定性评价规范要求采用不平衡推力法 ,但在考虑库水位下降产生的渗透力时 ,对渗流浸润线的确定缺乏理论依据 ,更没有实测数据的支持。为此 ,笔者运用一维的布辛内斯克方程 ,研究三峡水库蓄水后库水位下降和暴雨作用下滑坡渗流浸润线的变化规律 ;建立了渗流作用下滑坡稳定性评价模型 ;分析降速、渗透系数、暴雨等对滑坡稳定性的影响。     

Air Pollution Problems of the Steel Industry

Urban air pollution has traditionally been modeled using annual, or at best, seasonal emissions inventories and climatology. These averaging techniques may introduce uncertainty into the analysis, if specific emissions (e.g. SO₂) are correlated with dispersion factors on a short-term basis. This may well be the case for space heating emissions. An analysis of this problem, using hourly climatological and residential emission estimates for six U.S. cities, indicates that the errors introduced using such averages are modest (~ ± 12%) for annual average concentrations. Maximum hourly concentrations vary considerably more, since maximum heat demand and worst case dispersion are in general not coincident. The paper thus provides a basis for estimating more realistic air pollution Impacts due to residential space heating.     

Oxidation of mercury across selective catalytic reduction catalysts in coal-fired power plants

A kinetic model for predicting the amount of mercury (Hg) oxidation across selective catalytic reduction (SCR) systems in coal-fired power plants was developed and tested. The model incorporated the effects of diffusion within the porous SCR catalyst and the competition between ammonia and Hg for active sites on the catalyst. Laboratory data on Hg oxidation in simulated flue gas and slipstream data on Hg oxidation in flue gas from power plants were modeled. The model provided good fits to the data for eight different catalysts, both plate and monolith, across a temperature range of 280-420 degrees C, with space velocities varying from 1900 to 5000 hr(-1). Space velocity, temperature, hydrochloric acid content of the flue gas, ratio of ammonia to nitric oxide, and catalyst design all affected Hg oxidation across the SCR catalyst. The model can be used to predict the impact of coal properties, catalyst design, and operating conditions on Hg oxidation across SCRs.