Development and operation of immobilized cell plug flow bioreactor (PFR) for treatment of textile industry effluent and evaluation of its working efficiency

Environmental Science and Pollution Research - The release of untreated/partially treated effluent and solid waste from textile dyeing industries, having un-reacted dyes, their hydrolysed products...     

Contamination of rice crop with potentially toxic elements and associated human health risks—a review

Environmental Science and Pollution Research - Production of rice, a major staple food crop, should be maintained both quantitatively and qualitatively to assure global food security. In recent...     

Assessment of heavy metals in faecal pellets of blue rock pigeon from rural and industrial environment in India

Environmental Science and Pollution Research - The study was conducted to monitor concentration of six toxic metals in faecal pellets of blue rock pigeon from six industrial areas of Jaipur, i.e....     

Distribution and correlation of radon and uranium and associated hydrogeochemical processes in alluvial aquifers of northwest India

Environmental Science and Pollution Research - The spatial and vertical distributions of radon and uranium are evaluated in relation to the hydrogeology, geomorphology, and hydrochemistry of...     

Matrix method for evaluation of existing solid waste management system in Himachal Pradesh,India

Journal of Material Cycles and Waste Management - Effective management of Municipal Solid Waste (MSW) is an essential function of the city municipal corporation. The present study reports on the...     

Fauna-associated changes in soil biochemical properties beneath isolated trees in a desert pastureland of India and their importance in soil restoration

Biodiversity conservation and management of natural resources are the best options to restore and increase productivity of degrading pastureland in dry areas. Hence, arthropod abundance, organic matter, respiration, and dehydrogenase activity were measured in canopy zone soil of Prosopis cineraria (PC), Acacia nilotica (AN), Zizyphus nummularia (ZN), Capparis decidua (CD), and Acacia senegal (AS) associated with grasses with a view to establish interrelation for productivity enhancement of pastureland. Pure grass bock outside tree canopy was control plot. Acari, Myriapoda, Coleoptera, Isoptera, Collembola, and other soil arthropods were the major soil faunal groups. Integration of tree in pastureland enhanced population of soil arthropod by 9–65-fold in May 2001 and 8–13-fold in August/September as compared with control. The trends of changes in soil organic matter (SOM), soil respiration (SR), and dehydrogenase activity (DHA) were similar to the changes in soil arthropod population, indicating the role of soil fauna in facilitating biochemical processes and soil fertility. Two, eight, and nine times greater SOM, SR, and DHA, respectively, in silvipastoral system than the values in control suggest the beneficial effects of trees on improvement in biochemical processes and thus biodiversity in pastureland, as supported by negative values of relative tree effects (RTE). Microbial activities were highest in the ZN system, which had highest abundance of soil arthropods. In the other systems, CD and AS systems showed greater soil arthropod abundance and biological activities than with the PC and AN systems. Therefore, Z. nummularia-, C. decidua-, and A. senegal-based silvipastoral systems and related soil fauna may be promoted for enhancement of biological activity and productivity of pastureland in desert. The strategy may be adopted for developing a sustainable pedoecosystem in a region of the world where agriculture is notoriously difficult.     

Desorption of arsenic from clay and humic acid-coated clay by dissolved phosphate and silicate

Arsenic (As) contaminated aquifers contain iron minerals and clays that strongly bind As at their surfaces. It was suggested that As mobilization is driven by natural organic matter (including fulvic acids (FA) and humic acids (HA)) present in the aquifers either via providing reducing equivalents for reductive dissolution of Fe(III) (hydr)oxides or via competitive desorption of As from the mineral surfaces. In the present study we quantified sorption of As(III) and As(V) to Ca(2+)-homoionized illite (IL) and to kaolinite (Kao) as well as to HA-coated clays, i.e., illite-HA (IL-HA) and kaolinite-HA (Kao-HA) at neutral pH. Clay-HA complexes sorbed 28-50% more As than clay-only systems upon addition of 100μM As(III)/As(V) to 0.5g of clay or HA-clay with Ca(2+) probably playing an important role for HA binding to the clay surface and As binding to the HA. When comparing sorption of As(V) and As(III) to clay and HA-clay complexes, As(V) sorption was generally higher by 15-32% than sorption of As(III) to the same complexes. IL and IL-HA sorbed 11-28% and 6-11% more As compared to Kao and Kao-HA, respectively. In a second step, we then followed desorption of As from Kao, Kao-HA, IL and IL-HA by 100 and 500μM phosphate or silicate both at high (0.41-0.77μmol As/g clay), and low (0.04 to 0.05μmol As/g clay) As loadings. Phosphate desorbed As to a larger extent than silicate regardless of the amount of As loaded to clay minerals, both in the presence and absence of HA, and both for illite and kaolinite. At high loadings of As, the desorption of both redox species of As from clay-HA complexes by phosphate/silicate ranged from 32 to 72% compared to 2-54% in clay only systems meaning that As was desorbed to a larger extent from HA-coated clays compared to clay only systems. When comparing As(III) desorption by phosphate/silicate to As(V) desorption in high As-loading systems, there was no clear trend for which As species is desorbed to a higher extent in the four clay systems meaning that both As species behave similarly regarding desorption from clay surfaces by phosphate/silicate. Similarly, no significant differences were found in high As-loading systems in the amount of As desorbed by phosphate/silicate when comparing Kao vs. IL and Kao-HA vs IL-HA systems meaning that both clay types behave similarly regarding desorption of As by phosphate/silicate. At low As loadings, up to 80% of As was desorbed by phosphate and silicate with no noticeable differences being observed between different As species, different types of clay, clay vs clay-HA or the type of desorbant (phosphate and silicate). The results of this study showed that HA sorption to Ca(2+)-homoionized clay minerals can increase As binding to the clay although the As sorbed to the clay-HA is also released to a greater extent by competing ions such as phosphate and silicate. Desorption of As depended on the initial loadings of As onto the clay/clay-HA. Based on our results, the effect of humic substances on sorption of As and on desorption of As by phosphate and silicate has to be considered in order to fully understand and evaluate the environmental behavior of As in natural environments.