summary of the California aerosol characterization experiment

This report gives a brief summary of the experimental plan and the early results of field observations from the California Aerosol Characterization Experiment (ACHEX). The objectives of the program center on questions of the sources and evolution of aerosols in urban air, as they are superimposed on a natural background, particularly as they relate to visibilitydegradation. The project initially nvolved the use of an elaborately instrumented mobile laboratory combined with a fixed station in San Jose, in Pasadena, and in Riverside, and later incorporated several satellite monitoring stations in the Los Angeles Basin. Intensive field observationswere taken from July 1972 to November 1972 in several urban and nonurban locations between the San Francisco Bay area and the South Coast Basin, covering the Los Angeles area. In a second phase of the ACHEX, aerosols accompanying photochemical smog were studied intensively in the Los Angeles Basin during the period between July and October of 1973. The observations cover a wide variety of parameters including physical and chemical properties of aerosols, pollutant gas concentrations, and meteorological variables. The initial results show the great importance of sulfate, nitrate, noncarbonate carbon, and liquid water to the mass concentration of airborne particles and their relation to reduction in visibility. The anthropogenic contribution to atmospheric aerosols is consistently found to be allocated primarily to the submicron or fine particle size range.     

Heavy Metals in Urban Soils of East St. Louis,IL, Part I: Total Concentration of Heavy Metals in Soils

ABSTRACT

The city of East St. Louis, IL, has a history of abundant industrial activities including smelters of ferrous and non-ferrous metals, a coal-fired power plant, companies that produce organic and inorganic chemicals, and petroleum refineries. A protocol for soil analysis was developed to produce sufficient information on the extent of heavy metal contamination in East St. Louis soils. Soil cores representing every borough of East St. Louis were analyzed for heavy metals—As, Cd, Cu, Cr, Hg, Ni, Pb, Sb, Sn, and Zn. The topsoil contained heavy metal concentrations as high as 12.5 ppm Cd, 14,400 ppm Cu, ppm quantities of Hg, 1860 ppm Pb, 40 ppm Sb, 1130 ppm Sn, and 10,360 ppm Zn. Concentrations of Sb, Cu, and Cd were well correlated with Zn concentrations, suggesting a similar primary industrial source. In a sandy loam soil from a vacated rail depot near the bank of the Mississippi River, the metals were evenly distributed down to a 38-cm depth. The clay soils within a half-mile downwind of the Zn smelter and Cu products company contained elevated Cd (81 ppm), Cu (340 ppm), Pb (700 ppm), and Zn (6000 ppm) and displayed a systematic drop in concentration of these metals with depth. This study demonstrates the often high concentration of heavy metals heterogeneously distributed in the soil and provides baseline data for continuing studies of heavy metal soil leachability.     

Predicting aoueous solubility of organic nonelectrolytes from molar volume

Correlation equations relating aqueous solubility to molar volume and aqueous solubility to total molecular surface area were derived by regression analysis for several chemical classes which included both liquids and solids. These were similar to equations relating solubility with total molecular surface area and had similar correlation coefficients. The physical significance of the regression parameters obtained is discussed.     

Regulatory Oversight of Genetically Engineered Microorganisms: Has Regulation Inhibited Innovation?

/ Using detailed interviews with company representatives and researchers in the field, this paper examines the factors that might account for the slow pace of development of genetically engineered microorganisms (GEMs) intended for environmental release. We specifically analyzed the role of the regulatory system in shaping innovation. We identified at least two cases where industry decided to discontinue the development of a genetically engineered microbial product because of concerns over regulatory oversight. However, most often industry decisions to continue or halt development of GEMs were based on an evaluation of the particular product's efficacy and potential for profitability. Thus the inability of GEMs to perform up to expectations in the field, rather than the regulatory constraints, appears to be the factor responsible for the slow pace of development. KEY WORDS: Genetically engineered microorganisms; Biotechnology; Regulation of biotechnology; Innovation; Environmental release     

Risk communication in the internet age: The rise of disorganized skepticism

Communicating risks has become a core ingredient in the regulatory functions of government, interest group advocacy, public health, and corporate relations. The channels of risk communication have grown in complexity along with the development and expansion of the Internet and the birth of personalized blogging. This paper discusses three stages in the development of risk communication as an area of study and research. It examines the way risk is framed in three channels of communication, newsprint, the Expanded Academic Index, and Google using the example of the controversial chemical perfluorooctanoic acid (PFOA). The paper concludes that the Internet, as illustrated by the Google search engine, has created more opportunities for citizen learning and expanded the breadth and channels of risk communication, while also providing new opportunities for stakeholders to influence the message. Democritization of information does not necessarily create greater concordance between the cultural and technical assessment of risk.     

Sexual selection in a socially monogamous bird: male color predicts paternity success in the mountain bluebird, <Emphasis Type="Italic">Sialia currucoides</Emphasis>

Ornamental traits are thought to evolve because they give individuals an advantage in securing multiple mates. Thus, the presence of ornamentation among males in many monogamous bird species presents something of a conundrum. Under certain conditions, extra-pair paternity can increase the variance in reproductive success among males, thus increasing the potential for sexual selection to act. We addressed this possibility in the mountain bluebird (Sialia currucoides), a socially monogamous songbird in which males possess brilliant ultraviolet (UV)-blue plumage. Specifically, we asked whether a male’s success at siring offspring within his own nest and within the nests of other males was related to his coloration. In pairwise comparisons, males that sired extra-pair offspring were not more colorful than the males that they cuckolded. However, males that sired at least one extra-pair offspring were, on average, brighter and more UV-blue than males that did not sire extra-pair offspring. Brighter, more UV-blue males sired more offspring both with their own mate and tended to sire more offspring with extra-pair mates and thus sired more offspring overall. Our results support the hypothesis that the brilliant UV-blue ornamental plumage of male mountain bluebirds evolved at least in part because it provides males with an advantage in fertilizing the eggs of multiple females.     

ASSESSMENT OF GULLY-CONTROL STRUCTURES IN THE RIO NUTRIA WATERSHED,ZUNI RESERVATION,NEW MEXICO1

ABSTRACT: During the latter part of the 19th century and the early part of the 20th century, a major cycle of erosion, arroyo cutting, and gullying occurred in the southwestern United States. Since this erosion cycle began, many projects to control erosion, such as the Civilian Conservation Corps projects in the 1930s, were initiated. However, in the Southwestern United States few studies have documented the effect of these structures in reducing erosion or their effect on gully systems. As part of a watershed rehabilitation project on the Zuni Reservation, New Mexico, 47 structures made either of earth or rocks and 23 rock and brush structures were assessed. Sixty percent of the 47 earth or rock structures have breached and relative to dam height, 65 percent of 47 structures are more than 50 percent silted. Of the 23 rock and brush structures, 22 percent have breached or are close to breaching. Reasons for breaching of all structural types may be piping, scour immediately below the structures, large runoff and large drainage area, poor maintenance, headcutting, and active arroyo deepening and widening. In most cases, documentation does not exist on structure design, the specific purpose for a structure, or when these structures were built.