The catalysts of iron-doped Mn-Ce/TiO 2(Fe-Mn-Ce/TiO 2) prepared by sol-gel method were investigated for low temperature selective catalytic reduction(SCR) of NO with NH 3.It was found that the NO conversion over Fe-Mn-Ce/TiO 2 was obviously improved after iron doping compared with that over Mn-Ce/TiO 2.Fe-Mn-Ce/TiO 2 with the molar ratio of Fe/Ti = 0.1 exhibited the highest activity.The results showed that 96.8% NO conversion was obtained over Fe(0.1)-Mn-Ce/TiO 2 at 180°C at a space velocity of 50,000 hr 1.Fe-Mn-Ce/TiO 2 exhibited much higher resistance to H 2 O and SO 2 than that of Mn-Ce/TiO 2.The properties of the catalysts were characterized using X-ray diffraction(XRD),N 2 adsorption,temperature programmed desorption(NH 3-TPD and NOx-TPD),and Xray photoelectron spectroscopy(XPS) techniques.BET,NH3-TPD and NOx-TPD results showed that the specific surface area and NH3 and NOx adsorption capacity of the catalysts increased with iron doping.It was known from XPS analysis that iron valence state on the surface of the catalysts were in Fe3+ state.The doping of iron enhanced the dispersion and oxidation state of Mn and Ce on the surface of the catalysts.The oxygen concentrations on the surface of the catalysts were found to increase after iron doping.Fe-Mn-Ce/TiO2 represented a promising catalyst for low temperature SCR of NO with NH3 in the presence of H2 O and SO2. 相似文献
Activated carbon (AC) was considered to be an effective sorbent to control mercury in combustion systems. However, its capture
capacity was low and it required a high carbon-to-mercury mass ratio. AC loaded with catalyst showed a high elemental mercury (Hg0)
capture capacity due to large surface area of AC and high oxidization ability of catalyst. In this study, several metal chlorides and metal
oxides were used to promote the sorption capacity of AC. As a result, metal chlorides were better than metal oxides loaded on AC
to remove gaseous mercury. X-ray diffractometer (XRD), thermogravimetric analyzer (TGA) and specific surface area by Brunauer-
Emmett-Teller method (BET) analysis showed the main mechanisms: first, AC had an enormous surface area for loading enough
MClx; second, Cl and MxOy were generated during pyrogenation of MClx; finally, there were lots of active elements such as Cl and
MxOy which could react with elemental mercury and convert it to mercury oxide and mercury chloride. The HgO and HgCl2 might be
released from AC’s porous structure by thermo regeneration. A catalytic chemisorption mechanism predominates the sorption process
of elemental mercury. As Co and Mn were valence variable metal elements, their catalytic effect on Hg0 oxidization may accelerate
both oxidation and halogenation of Hg0. The sorbents loaded with metal chlorides possessed a synergistic function of catalytic effect
of valence variable metal and chlorine oxidation. 相似文献
Objective: Pedestrian injuries are a leading cause of child death and may be reduced by training children to cross streets more safely. Such training is most effective when children receive repeated practice at the complex cognitive–perceptual task of judging moving traffic and selecting safe crossing gaps, but there is limited data on how much practice is required for children to reach adult levels of functioning. Using existing data, we examined how children's pedestrian skills changed over the course of 6 pedestrian safety training sessions, each composed of 45 crossings within a virtual pedestrian environment.
Methods: As part of a randomized controlled trial on pedestrian safety training, 59 children ages 7–8 crossed the street within a semi-immersive virtual pedestrian environment 270 times over a 3-week period (6 sessions of 45 crossings each). Feedback was provided after each crossing, and traffic speed and density were advanced as children's skill improved. Postintervention pedestrian behavior was assessed a week later in the virtual environment and compared to adult behavior with identical traffic patterns.
Results: Over the course of training, children entered traffic gaps more quickly and chose tighter gaps to cross within; their crossing efficiency appeared to increase. By the end of training, some aspects of children's pedestrian behavior was comparable to adult behavior but other aspects were not, indicating that the training was worthwhile but insufficient for most children to achieve adult levels of functioning.
Conclusions: Repeated practice in a simulated pedestrian environment helps children learn aspects of safe and efficient pedestrian behavior. Six twice-weekly training sessions of 45 crossings each were insufficient for children to reach adult pedestrian functioning, however, and future research should continue to study the trajectory and quantity of child pedestrian safety training needed for children to become competent pedestrians. 相似文献
To improve the efficiency of nitrogen removal with lower energy consumption, the study of feedforward control was carried
out on a pilot-scale anaerobic-anoxicoxic (AAO) plant for the treatment of municipal wastewater. The effluent qualities of
the pilot plant under different control strategies were investigated. The results indicated that the change of external recycle
was not a suitable approach to regulate the sludge concentration of plug-flow reactors; adjusting the aeration valve and dissolved
oxygen set-point according to ammonia load could overcome the impact of influent fluctuation; and the denitrification potential
could be estimated based on the transit time of anoxic zone and the relative content of carbon resource entering the anoxic
zone. Simple feedforward control strategies for aeration and internal recycle were subsequently proposed and validated. The
nitrogen removal was successfully improved in the pilot plant. The effluent total nitrogen had decreased by 29.9% and was
steadily controlled below 15 mg·L−1. Furthermore, approximately 38% of the energy for aeration had been saved. 相似文献
Emission trading is one of the most effective alternatives to controlling water pollution. Water environmental functional
zone (WEFZ) is used to determine the water quality standard and identify the zone boundary for each river or reach. In this
study, a new emission trading scheme was addressed based on WEFZ, accounting for both the temporal dimension and water quality
control. A temporal factor of emission trading was proposed based on variations in the environmental capacity within a year
by dividing the year into three periods, including high, normal, and low periods of environmental capacity. During each period,
emission trading was implemented exclusively. A water quality-control scheme was suggested based on the water quality requirement
in the water functional zone, in which the water quality at the downstream boundary of the zone was required to meet the water
standard following auto-purification in the stream. Two methods of calculating water quality control are addressed for point-source
pollution and non-point-source pollution. The calculated temporal dimension and water quality control were located in Dongxi
River of the Daning Watershed in the Three Gorges Watershed. The high period was during June, July, and August, the normal
period was during April, May, September, and October, and the low period was during January, February, March, November, and
December. The results from the water quality calculation demonstrated that the discharge of point-source and non-point-source
pollutions led to an excess of common contaminants at the downstream boundary of WEFZ. The temporal and spatial factors above
should be incorporated into the emission trading scheme based on WEFZ. 相似文献