Differential accumulation of mercury and other trace metals in the food web components of a reservoir impacted by a chlor-alkali plant (Flix, Ebro River, Spain): Implications for biomonitoring

Comparative studies of biomonitors of trace metal contamination are relatively scarce. We took advantage of a point source pollution in a reservoir (Flix, Spain) to compare trace metal (Hg, Pb, Cd, Se, As, Zn, Cu, Cr) bioaccumulation patterns among 16 food web components. Our results indicate that most organisms are suitable for Hg biomonitoring, whereas other metals are better monitored by only some of them. Biofilms and zebra mussel were the organisms with larger and more diverse biomonitoring capacity. However, we show that using groups of biomonitors increase the scope and strengths of the conclusions and specific goals can be better addressed. We conclude providing an overview of the strengths and weaknesses of the main organisms considered for biomonitoring trace metals in rivers and reservoirs.     

Wasteful waste-reducing policies? The impact of waste reduction policy instruments on collection and processing costs of municipal solid waste

We study the impact of some local policies aimed at municipal solid waste (MSW) reduction on the cost efficiency of MSW collection and disposal. We explicitly account for differences between municipalities in background conditions by using a bootstrapped version of the Data Envelopment Analysis methodology in combination with a matching technique. Using data on 299 municipalities in Flanders, Belgium, for the year 2003, our results indicate that municipalities that are member of a waste collection joint venture, or that subscribe to a voluntary agreement to reduce MSW at the highest ambition level, collect and process MSW more efficiently than other municipalities. Weekly instead of two-weekly waste collection, or using a weight-based pricing system appears to have no impact on efficiency. Our results show that aiming at MSW reduction does not lead to lower efficiency of public service provision, even on the contrary.     

Internal distribution of uranium and associated genotoxic damages in the chronically exposed bivalve Corbicula fluminea

Uranium (U) internal distribution and involved effects in the bivalve Corbicula fluminea have been studied after direct chronic exposure (90 d, 10 μg.L-1). U distribution was assessed at the subcellular level (Metal Rich Granules -MRG-, pellets and cytosol fractions) in two main organs of the bivalve (gills and visceral mass). Micro-localisation was investigated by TEM-EDX analysis in the gills epithelium. DNA damage in gill and hemolymph samples was measured by the Comet assay. The 90-d exposure period led to a significant increase of U concentration in gills over time (×5) and a large U quantity in subcellular granules in gills. Finally, a significant increase (×2) in DNA damage was noted in exposed gills and haemocytes. This study shows that the accumulation levels and consequently the potential toxicity cannot be successfully predicted only on the basis of concentration in water or in tissues and subcellular fractions after chronic exposure.     

Treatment of polychlorinated biphenyls in two surface soils using catalyzed H₂O₂ propagations

Two surface soils contaminated with polychlorinated biphenyls (PCBs) collected from Superfund sites in the New England region of the United States, Fletcher Paints and Merrimack Industrial Metals, were evaluated for field treatment at the bench level using catalyzed H₂O₂ propagations (CHP—modified Fenton’s reagent). The two soils were first evaluated for the potential for in situ treatment based on two criteria: (1) temperature (<40 °C after CHP reagent addition), and (2) hydrogen peroxide longevity (>24 h). In situ CHP remediation was more applicable to the Fletcher soil, while the Merrimack soil was better suited to ex situ treatment based on temperature increases and hydrogen peroxide lifetimes. Using the highest hydrogen peroxide concentrations appropriate for in situ treatment in each soil, PCB destruction was 94% in the Fletcher soil but only 48% in the Merrimack soil. However, 98% PCB destruction was achieved in the Merrimack soil using conditions more applicable to ex situ treatment (higher hydrogen peroxide concentrations with temperatures >40 °C). Analysis of degradation products by gas chromatography/mass spectroscopy showed no detectable chlorinated degradation products, suggesting that the products of PCB oxidation were rapidly dechlorinated and degraded. The results of this research document that the two PCB-contaminated soils studied can be effectively treated using aggressive CHP conditions, and that such a detailed bench study provides important information before implementing field treatment.     

Mineralisation of target hydrocarbons in three contaminated soils from former refinery facilities

This study investigated the microbial degradation of ¹⁴C-labelled hexadecane, octacosane, phenanthrene and pyrene and considered how degradation might be optimised in three genuinely hydrocarbon-contaminated soils from former petroleum refinery sites. Hydrocarbon mineralisation by the indigenous microbial community was monitored over 23 d. Hydrocarbon mineralisation enhancement by nutrient amendment (biostimulation), hydrocarbon degrader addition (bioaugmentation) and combined nutrient and degrader amendment, was also explored. The ability of indigenous soil microflora to mineralise ¹⁴C-target hydrocarbons was appreciable; ≥16% mineralised in all soils. Generally, addition of nutrients or degraders increased the rates and extents of mineralisation of ¹⁴C-hydrocarbons. However, the addition of nutrients and degraders in combination had a negative effect upon ¹⁴C-octacosane mineralisation and resulted in lower extents of mineralisation in the three soils. In general, the rates and extents of mineralisation will be dependent upon treatment type, nature of the contamination and adaptation of the ingenious microbial community.     

Effects of canopy-deposition interaction on H+ supply to soils in Pinus banksiana and Populus tremuloides ecosystems in the Athabasca oil sands region in Alberta, Canada

Soil acidification has been of concern in the oil sands region in Alberta due to increased acid deposition. Using the canopy budget model, and accounting for H⁺ canopy leaching by organic acids, we determined sources and sinks of H⁺ in throughfall in jack pine (Pinus banksiana) and trembling aspen (Populus tremuloides) stands in two watersheds from 2006 to 2009. In pine stands, H⁺ deposition was greater in throughfall than in bulk precipitation while the opposite was true in aspen stands. The annual H⁺ interception deposition was 148.8-193.8 and 49.7-70.0 mol_c ha⁻¹ in pine and aspen stands, respectively; while the annual H⁺ canopy leaching was 127.1-128.7 and 0.0-6.0 mol_c ha⁻¹, respectively. The greater H⁺ supply in pine stands was caused by greater interception deposition of SO₄²⁻ and organic acids released from the pine canopy. Such findings have significant implications for establishing critical loads for various ecosystems in the oil sands region.     

Effects of livestock wastewater variety and disinfectants on the performance of constructed wetlands in organic matters and nitrogen removal

Background, aim and scope  

Treatment performance of constructed wetlands (CWs) is largely dependent on the characteristics of the wastewater. Although livestock wastewater is readily biodegradable in general, its variety in biodegradability can still be significant in practice. In addition, it is a common practice to periodically use disinfectants in livestock activities for health concerns. Obviously, the residual of the disinfectants in livestock wastewater may have serious inhibitory effect on the microbial activities during wastewater treatment. Thus, the main objective of this study was to examine the variety of livestock wastewater in biodegradability and its effect on the performance of a pilot scale tidal flow CWs (TFCWs) in organic matter and nitrogen removal. Furthermore, investigation of the potential inhibition of the chosen disinfectants on organic matter biodegradation and nitrification was another aim of this study.     

Diversity in Current Ecological Thinking: Implications for Environmental Management

Current ecological thinking emphasizes that systems are complex, dynamic, and unpredictable across space and time. What is the diversity in interpretation of these ideas among today’s ecologists, and what does this mean for environmental management? This study used a Policy Delphi survey of ecologists to explore their perspectives on a number of current topics in ecology. The results showed general concurrence with nonequilibrium views. There was agreement that disturbance is a widespread, normal feature of ecosystems with historically contingent responses. The importance of recognizing multiple levels of organization and the role of functional diversity in environmental change were also widely acknowledged. Views differed regarding the predictability of successional development, whether “patchiness” is a useful concept, and the benefits of shifting the focus from species to ecosystem processes. Because of their centrality to environmental management, these different views warrant special attention from both managers and ecologists. Such divergence is particularly problematic given widespread concerns regarding the poor linkages between science (here, ecology) and environmental policy and management, which have been attributed to scientific uncertainty and a lack of consensus among scientists, both jeopardizing the transfer of science into management. Several suggestions to help managers deal with these differences are provided, especially the need to interpret broader theory in the context of place-based assessments. The uncertainty created by these differences requires a proactive approach to environmental management, including clearly identifying environmental objectives, careful experimental design, and effective monitoring.     

Quantifying Reductions of Mass‐Failure Frequency and Sediment Loadings From Streambanks Using Toe Protection and Other Means: Lake Tahoe,United States1

Abstract: Streambank erosion by mass‐failure processes represents an important form of channel adjustment and a significant source of sediment in disturbed streams. Mass failures regularly occur by a combination of hydraulic processes that undercut bank toes and geotechnical processes that cause bank collapse by gravity. Little if any quantitative information is available on the effectiveness of bank treatments on reducing erosion. To evaluate potential reduction in sediment loadings emanating from streambanks, the hydraulic and geotechnical processes responsible for mass failure were simulated under existing and mitigated conditions using a Bank‐Stability and Toe‐Erosion Model (BSTEM). Two critical erosion sites were selected from each of the three watersheds known to contribute the greatest amounts of fine sediment by streambank processes in the Lake Tahoe Basin. A typical high‐flow annual hydrograph was selected for analysis. Bank‐material strength data were collected for each layer as were species‐specific root‐reinforcement values. The effects of the first flow event on bank‐toe erosion were simulated using an excess shear‐stress approach. The resulting geometry was then exported into the bank‐stability submodel to test for the relative stability of the bank under peak flow and drawdown conditions. In this way, BSTEM was used iteratively for all flow events for both existing and mitigated conditions. On average, 13.6% of the material was eroded by hydraulic shear, the remainder by mass failures, which occurred about five times over the simulation period. Simulations with 1.0 m‐high rock‐toe protection showed a dramatic reduction in streambank erosion (69‐100%). Failure frequency for the simulation period was reduced in most cases to a single episode. Thus, an almost 90% reduction in streambank loadings was achieved by virtually eliminating the erosion of only 14% of the material that was entrained by hydraulic forces. Consequently, simulations show average load reductions of about an order of magnitude. Results stress the critical importance of protecting the bank toe‐region from steepening by hydraulic forces that would otherwise entrain previously failed and in situ bank materials, thereby allowing the upper bank to flatten (by failure) to a stable slope.     

A Calibrated,High‐Resolution GOES Satellite Solar Insolation Product for a Climatology of Florida Evapotranspiration1

Paech, Simon J., John R. Mecikalski, David M. Sumner, Chandra S. Pathak, Quinlong Wu, Shafiqul Islam, and Taiye Sangoyomi, 2009. A Calibrated, High‐Resolution GOES Satellite Solar Insolation Product for a Climatology of Florida Evapotranspiration. Journal of the American Water Resources Association (JAWRA) 45(6):1328‐1342. Abstract: Estimates of incoming solar radiation (insolation) from Geostationary Operational Environmental Satellite observations have been produced for the state of Florida over a 10‐year period (1995‐2004). These insolation estimates were developed into well‐calibrated half‐hourly and daily integrated solar insolation fields over the state at 2 km resolution, in addition to a 2‐week running minimum surface albedo product. Model results of the daily integrated insolation were compared with ground‐based pyranometers, and as a result, the entire dataset was calibrated. This calibration was accomplished through a three‐step process: (1) comparison with ground‐based pyranometer measurements on clear (noncloudy) reference days, (2) correcting for a bias related to cloudiness, and (3) deriving a monthly bias correction factor. Precalibration results indicated good model performance, with a station‐averaged model error of 2.2 MJ m^?2/day (13%). Calibration reduced errors to 1.7 MJ m^?2/day (10%), and also removed temporal‐related, seasonal‐related, and satellite sensor‐related biases. The calibrated insolation dataset will subsequently be used by state of Florida Water Management Districts to produce statewide, 2‐km resolution maps of estimated daily reference and potential evapotranspiration for water management‐related activities.