Alumina-supported oxime for the degradation of sarin and diethylchlorophosphate

1-(4-Chlorophenyl))-N-hydroxymethanimine and cyclohexyl-N-hydroxymethanimine were synthesized and a well-established oxime, i.e., 2-[(hydroxyimino)methyl]-1-methylpyridinium chloride was purchased. Thereafter; all were loaded over Al₂O₃ using incipient wetness technique. The prepared systems were characterized using surface area analyzer, scanning electron microscope, energy dispersive X-ray spectrophotometer, Fourier transform infrared spectrophotometer and thermogravimetric analyzer. Kinetics of the degradation of sarin (GB) and simulant, i.e. diethylchlorophosphate (DEClP) was studied over synthesized oxime impregnated Al₂O₃ and results were compared with well reported oxime impregnated Al₂O₃. Kinetics of reaction was found to be following the pseudo first order reaction kinetics. The order of reactivity of the prepared systems was found to be cyclohexyl-N-hydroxymethanimine/Al₂O₃ > 1-(4-chlorophenyl)-N-hydroxymethanimine/Al₂O₃ > 2-[(hydroxyimino)methyl]-1-methylpyridinium chloride/Al₂O₃ > Al₂O₃. From the reaction kinetics it was observed that the reaction with DEClP was faster than with GB. Cyclohexyl-N-hydroxymethanimine/Al₂O₃ was found to be the most reactive system with half-life of 0.94 and 15 h for DEClP and GB respectively.     

Performance evaluation of isoproturon-degrading indigenous bacterial isolates in soil microcosm

Isoproturon (IPU)-degrading soil bacteria were isolated from herbicide-applied wheat fields. These isolates were identified using cultural, morphological, biochemical and 16S rRNA sequencing methods. 16S rRNA sequences of both the bacterial isolates were compared with NCBI GenBank data base and identified as Bacillus pumilus and Pseudoxanthomonas sp. A soil microcosm study was carried out for 40 days in six different treatments. Experimental results revealed maximum 95.98% IPU degradation in treatment 6 where bacterial consortia were augmented in natural soil, followed by 91.53% in treatment 5 enriched with organic manure as an additional carbon source. However, only 14.03% IPU was degraded in treatment 1 (control) after 40 days. In treatments (2–4), 75.59%, 70.92% and 77.32% IPU degradation was recorded, respectively. IPU degradation in all the treatments varied significantly over the control. 4-Isopropylaniline was detected as IPU degradation by-product in the medium. The study confirmed that B. pumilus and Pseudoxanthomonas sp. performed effectively in soil microcosms and could be employed profitably for field-scale bioremediation experiments.     

Environmental and agronomic implications of water table and nitrogen fertilization management

Nitrate (NO3-) pollution of surface and subsurface waters has become a major problem in agricultural ecosystems. Field trials were conducted from 1996 to 1998 at St-Emmanuel, Quebec, Canada, to investigate the combined effects of water table management (WTM) and nitrogen (N) fertilization on soil NO3- level, denitrification rate, and corn (Zea mays L.) grain yield. Treatments consisted of a combination of two water table treatments: free drainage (FD) with open drains at a 1.0-m depth from the soil surface and subirrigation (SI) with a design water table of 0.6 m below the soil surface, and two N fertilizer (ammonium nitrate) rates: 120 kg N ha(-1) (N120) and 200 kg N ha(-1) (N200). Compared with FD, SI reduced NO3(-)-N concentrations in the soil profile by 37% in spring 1997 and 2% in spring 1998; and by 45% in fall 1997 and 19% in fall 1998 (1 mg NO3(-)-N L(-1) equals approximately 4.43 mg NO3- L(-1)). The higher rate of N fertilization resulted in greater levels of NO3(-)-N in the soil solution. Denitrification rates were higher in SI than in FD plots, but were unaffected by N rate. The N200 rate produced higher yields than N120 in 1996 and 1997, but not 1998. Corn yields in SI plots were 7% higher than FD plots in 1996 and 3% higher in 1997, but 25% lower in 1998 because the SI system was unable to drain the unusually heavy June rains, resulting in waterlogging. These findings suggest that SI can be used as an economical means of reducing NO3- pollution without compromising crop yields during normal growing seasons.     

Emissions from burning biofuels in metal cookstoves

Promoting stoves that burn wood and other biofuels more efficiently is one of the means to reduce fuel consumption, but such efficient stoves may also emit more carbon monoxide and total suspended particulates. In an earlier study, a standard chamber method was proposed to estimate emission factors from burning fuelwood (Acacia nilotica). Here that methodology is extended to measure emission factors from burning of dungcakes and crop residues (Brassica or mustard stalks)—common fuels in many developing countries. The amounts of carbon monoxide (CO) and total suspended particulates (TSP) emitted by four different models of stoves, when using each of the three biofuels, are measured.The CO emission factors range from 13–68 (g/kg) for fuelwood to 26–67 g/kg for dungcakes and 20–114 g/kg for crop residues, for particulates they range from 1.1–3.8 to 4.1–7.8 and 2.1–12.0 g/kg for the three fuels, respectively. On a per unit heat delivered basis, the emissions of CO and TSP from both dungcakes and crop residues are two to three times higher compared to those from fuelwood. While for some improved stove-fuel combinations, the increase in emission factors was offset by the increase in thermal efficiency, this was not always so and causes a dilemma. The more efficient stoves are found to have higher emission factors of both CO and TSP for all three fuels. Emissions per standard task (i.e, on a unit heat delivered basis) is proposed as a criterion to evaluate cookstoves.     

Soil application of dinitroaniline and arylphenoxy propionic herbicides influences the activities of phosphate-solubilizing microorganisms in soil

An experiment was conducted under laboratory conditions to investigate the effect of two systemic herbicides, viz. pendimethalin (a dinitroaniline) and quizalofop (an arylphenoxy propionic acid) at their recommended field application rates (1.0?kg and 50?g active ingredient per hectare, respectively), either separately or in a combination, on growth and activities of phosphate-solubilizing microorganisms in relation to their effects on biochemical transformations and availability of organic carbon, total and available phosphorus in a Typic Haplustept soil of West Bengal, India. Application of herbicides, in general, significantly stimulated the growth and activities of phosphate-solubilizing microorganisms which increased microbial biomass resulting in higher accumulation of oxidizable organic carbon, total and available phosphorus in soil as compared to untreated control. The combined application of both the herbicides highly stimulated the proliferations of phosphate-solubilizing microorganisms, while pendimethalin alone significantly accentuated phosphate-solubilizing capacities 36.4% as compared to untreated control and retained highest amount of total phosphorus due to greater microbial activities in soil. The separate application of quizalofop also manifested an induced effect on the proliferations of phosphate-solubilizing microorganisms and accounted significant amounts of organic carbon and available phosphorus in the soil system. The results of the present study thus indicated that the cited herbicides at their field application rates can be safely used to eradicate weeds in the crop fields.     

Towards more sustainable future: assessment of sustainability literacy among the future managers in India

The present study attempts to assess the literacy levels of future managers of India in social, economic, and environment sustainability issues both at national and global levels among the students from Management Education Institutions (MEIs) located in Bengaluru, Chandigarh, and New Delhi. Additionally, a comparative study between the MEIs situated in Bengaluru, Chandigarh, and New Delhi, India, is undertaken. Interestingly, participants of the study specified more professional importance and personal relevance of sustainability. The study's outcome shows a higher level of sustainability knowledge among future managers from MEIs in New Delhi and Bengaluru. Future managers based out in New Delhi and Bengaluru are more aware of social and economic sustainability and having less awareness of environmental issues. Sustainability knowledge and awareness of the future managers are the first steps to engage them in building a sustainable future. It compels them to remain fully dedicated to creating a prosperous society and encourages them to make knowledgeable and successful choices to that end. The study's findings indicate a difference found in the levels of sustainability literacy among the Postgraduate students of Business Administration based in India's three metropolitan cities, including Chandigarh: Bengaluru and Delhi. The awareness about the local, national, or global eco-system, pollution, and other problems concerned with the environment was low among students based in Chandigarh, moderate among Delhi students, and high among the Bengaluru students.

     

Legacy and emerging flame retardants in indoor and outdoor dust from Indo-Gangetic Region (Patna) of India: implication for source apportionment and health risk exposure

Environmental Science and Pollution Research - The fate of legacy and emerging flame retardants are poorly reported in developing countries, including India. Also, the positive matrix factorization...     

Assessment of potential health risk of fluoride consumption through rice,pulses, and vegetables in addition to consumption of fluoride-contaminated drinking water of West Bengal,India

A study was conducted in fluoride-affected Bankura and Purulia districts of West Bengal to assess the potential health risk from fluoride exposure among children, teenagers, and adults due to consumption of rice, pulses, and vegetables in addition to drinking water and incidental ingestion of soil by children. Higher mean fluoride contents (13–63 mg/kg dry weight) were observed in radish, carrot, onion bulb, brinjal, potato tuber, cauliflower, cabbage, coriander, and pigeon pea. The combined influence of rice, pulses, and vegetables to cumulative estimated daily intake (EDI) of fluoride for the studied population was found to be 9.5–16%. Results also showed that intake of ivy gourd, broad beans, rice, turnip, fenugreek leaves, mustard, spinach, and amaranth grown in the study area is safe at least for time being. The cumulative EDI values of fluoride (0.06–0.19 mg/kg-day) among different age group of people of the study area were evaluated to be ~10⁴ times higher than those living in the control area; the values for children (0.19 and 0.52 mg/kg-day for CTE and RME scenarios, respectively) were also greater than the “Tolerable Upper Intake Level” value of fluoride. The estimated hazard index (HI) for children (3.2 and 8.7 for CTE and RME scenarios, respectively) living in the two affected districts reveals that they are at high risk of developing dental fluorosis due to the consumption of fluoride-contaminated rice, pulses, and vegetables grown in the study area in addition to the consumption of contaminated drinking water.     

Metallic components of traffic-induced urban aerosol, their spatial variation, and source apportionment

This study proposes a practical method to estimate elemental composition and distribution in order to attribute source and quantify impacts of aerosol particles at an urban region in Kolkata, India. Twelve-hour total particulates were collected in winter (2005–2006) and analyzed by energy-dispersive X-ray fluorescence technique to determine multi-elemental composition, especially trace metals. The aerosols consist of various elements including K, Ca, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Se, and Pb which exhibit significant concentration at various sites (p?<?0.05). The concentration of different metallic elements were found in the order of Zn ?> ?Pb ?> ?Ni ?> ?Cu ?> ?Cr ?>? Co. Statistical multivariate analysis and correlation matrix analyses were performed for factor identification and consequent source apportionment. Contour profiles demonstrate spatial variation of elemental compositions indicating possible source contribution along with meteorological influences. Spatial differences were clearly most significant for Zn, Ni, Pb, and Cu reflecting the importance of anthropogenic inputs, primarily from automobile sources.