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931.
932.
933.
Ammonia inhibition on thermophilic anaerobic digestion 总被引:13,自引:0,他引:13
This study evaluated both chronic and acute toxicity of ammonia in thermophilic anaerobic digestion of synthetic wastewater over a range of acclimation concentrations. The inhibition effects of ammonia, in terms of total ammonia nitrogen (TAN), under various pH values and acclimation conditions on thermophilic aceticlastic methanogens were investigated. Completely mixed thermophilic anaerobic reactors operated at a chemical oxygen demand (COD) loading rate of 4 g/lday and a solid retention time (SRT) of 7 days were subjected to TAN concentrations of 0.40, 1.20, 3.05, 4.92, and 5.77 g/l. The reactor operations presented a case of chronic inhibition and it was observed that TAN concentrations of 4.92 and 5.77 g/l caused a drop in methane production by as much as 39% and 64%, respectively with respect to control. Batch anaerobic toxicity assays (ATA) were also performed to evaluate the acute toxicity effects of TAN and pH on methanogenesis at thermophilic condition. Modeling based on the results of ATA indicated that aceticlastic methanogens acclimated to high concentrations of TAN were less sensitive to increase in TAN and could tolerate wider pH ranges. TAN concentration causing 100% inhibition occurred in the range of 8-13 g/l, depending on acclimation condition and system pH. 相似文献
934.
超声波强化污水厌氧生物处理综述 总被引:1,自引:0,他引:1
通过对超声波辐射促进微生物活性以及超声波强化污水好氧生物处理、厌氧污泥减量化处理等作用机制的分析研究,探讨将超声波应用于强化污水厌氧生物处理的可行性.同时对超声波强化污水厌氧生物处理的应用前景进行了展望. 相似文献
935.
Aqueous solubilities of four non-ortho and eight mono-ortho substituted PCBs were determined using a generator-column technique followed by subsequent off-line GC/ECD analysis of the aqueous solutions. The method is based on pumping water through a column containing glass beads coated with the congener being studied and has been used to measure solubilities at room temperature. The method circumvents many of the experimental difficulties encountered with the traditional shake-flask system. Aqueous solubility of 3,3′,4,4′-tetrachlorobiphenyl determined by this procedure is compared with data obtained from the shake-flask method and the computational method. The precision of replicate measurements is better than ±6.5%. Aqueous solubilities determined for 12 congeners ranged from 6.07 × 10−11 to 4.47 × −9 mol/L and generally decreased with molecular weight and increased with degree of ortho-chlorine substitution within a molecular-weight class. 相似文献
936.
TiO2 photocatalytic degradation of PCBs in soil-water systems containing fluoro surfactant 总被引:4,自引:0,他引:4
Titanium dioxide-mediated photodegradation of Polychlorinated biphenyls (PCBs) in soil/aqueous systems with added fluorinated surfactant was investigated. PCBs can bind tightly to organic matter in the soil, especially in aged, contaminated soil. Experiments showed an effective PCB photocatalytic degradation in mixed systems of soil/clay with anionic fluorinated surfactant FC-143 and TiO2. The FC-143 surfactant is stable in this photochemical process. PCB degradation rates in samples followed the order: spiked clay > spiked soil > Hudson River bank soil. The results suggest that anionic fluorinated surfactant may form semimicelles and/or admicelles on the surface of positively charged TiO2. The hydrophobic surface of TiO2 can provide a nonpolar phase that acts as a partioning medium for hydrophobic PCBs. Therefore, PCBs in soil can be released to the semimicelle and/or admicelle on the TiO2 surface and are effectively photodegraded in a dispersion containing anionic fluorinated surfactant. The combination of surfactant extraction and photooxidation forms the basis for a novel two-stage process for the removal and destruction of PCBs from soil. 相似文献
937.
Shim WJ Yim UH Kim NS Hong SH Oh JR Jeon JK Okamura H 《Environmental pollution (Barking, Essex : 1987)》2005,133(3):489-499
Triphenyltin (TPT) and tributyltin (TBT) concentrations were determined in two starfish species (Asteria pectinifera and Asterias amurensis), bivalves (Crassostrea gigas or Mytilus edulis), and seawater samples from sites around the coasts of Korea. Both TPT and TBT concentrations in starfish ranged from 8 to 1560 ng/g and from <2 to 797 ng/g as Sn on a dry weight basis, respectively. TPT concentration accounted for 75.4% and 86.4% of total phenyltin concentration in A. pectinifera and A. amurensis, respectively, while monobutyltin, a degradation product of TBT, accounted for 86.3% and 57.2% of total butyltin, respectively. Triphenyltin concentrations in A. pectinifera were significantly correlated to water and bivalve TPT concentrations, which implies that dietary uptake of TPT from contaminated prey as well as direct uptake from surrounding water contribute to TPT body residues in the starfish. Starfish could be target organisms for monitoring TPT compound in the marine environment, due to their high accumulation and low degradation capacity towards TPT. 相似文献
938.
Pan B Liu WX Shi Z Cao J Shen WR Qing BP Sun R Tao S 《Journal of environmental science and health. Part. B》2004,39(3):353-365
The methods of sample purification for determinations of organochlorine pesticides (OCPs) in sediment and fish muscle were investigated in this study. A two-step procedure with preliminary cleanup and florisil column fraction was adopted. The working conditions of florisil column were firstly optimized. As to preliminary cleanup, liquid-liquid extraction by mixture of dimethyl formamide (DMF) and hexane and sulphonation by concentrated sulfuric acid were applied respectively and compared for the studied samples. The results indicated that liquid-liquid distribution could effectively separate lipids from fish muscle extracts, while failed in elimination of chlorophyll extracted from the relicts of hydrophytes in the sediment sample. In view of the sample appearance and clarity of gas chromatogram, sulphonation was more suitable to purify the sediment sample, however, the recoveries of the spiked standards were poor. The use of eluting solvent with stronger polarity could improve the corresponding recoveries significantly. Due to complete loss of Dieldrin, Endrin, and Endrin aldehyde after sulphonation, this pretreatment was improper to the three components. Sulfur, as the particular disturbing element in sediment, could be removed sufficiently by addition of activated copper powder. The relevant detection limits of the selected methods for OCPs in the studied substrates were also provided. 相似文献
939.
940.
介绍了溶胶-凝胶法制备Ce离子掺杂纳米TiO2的工艺流程.采用X射线衍射(XRD)、紫外可见分光光度法(UV-Vis)等方法表征了Ce掺杂TiO2的相组成、紫外可见漫反射率与掺杂量的关系.结果表明,掺杂的TiO2在520℃、650℃焙烧2 h呈锐钛矿结构,在520℃焙烧2 h的TiO2的晶粒尺寸大约为20 nm,而掺杂Ce后其晶粒尺寸均减小,大约为12nm.UV-Vis吸光度分析表明,掺Ce后吸收带边明显发生红移,但随着Ce掺杂浓度的增大,其对可见光的吸收影响不大.光催化降解反应表明,未掺杂Ce的TiO2反应2 h后对甲醛的没有降解作用,而Ce掺杂TiO2反应2 h后甲醛降解率达15%. 相似文献