Interlaborafory Comparison of Formaldehyde Emissions from Particleboard Underlayment in Small-Scale Environmental Chambers

Formaldehyde (CH₂O) emissions from particleboard underlayment have been measured in 0.17 and 0.2 m³ chambers at separate laboratories to test the comparability of small scale environmental chamber measurements under different ventilation and product loading conditions. Absolute CH₂O calibration was established through intermethod comparison of different monitoring techniques against a CH₂O generation apparatus. Interlaboratory precision was enhanced via co-calibration of each laboratory’s CH₂O colorimetric analyzer against the same blank and bi-level generation source at the beginning and end of the study. The results show excellent intermethod and interlaboratory agreement in both the CH₂O calibration and particleboard emissions testing. The CH₂O emission rates of the test specimens demonstrate a Fick’s Law dependence on CH₂O vapor concentration. Measured CH₂O concentrations are described by a single-compartment, single emitter model, and are inversely proportional to the ratio [N/L (m/h)] of the air exchange rate [N(h^-1)] and product loading [L(m^-1)]. Comparison tests at varying N and L, but uniform N/L were performed; similar CH2O concentrations were measured for N and L levels selected from an indoor compartment model, and for fivefold larger N and L values, which are more convenient for small-scale chamber testing.     

Idle Emissions from Heavy-Duty Diesel Vehicles: Review and Recent Data

Abstract

Heavy-duty diesel vehicle idling consumes fuel and reduces atmospheric quality, but its restriction cannot simply be proscribed, because cab heat or air-conditioning provides essential driver comfort. A comprehensive tailpipe emissions database to describe idling impacts is not yet available. This paper presents a substantial data set that incorporates results from the West Virginia University transient engine test cell, the E-55/59 Study and the Gasoline/Diesel PM Split Study. It covered 75 heavy-duty diesel engines and trucks, which were divided into two groups: vehicles with mechanical fuel injection (MFI) and vehicles with electronic fuel injection (EFI). Idle emissions of CO, hydrocarbon (HC), oxides of nitrogen (NO_x), particulate matter (PM), and carbon dioxide (CO₂) have been reported. Idle CO₂ emissions allowed the projection of fuel consumption during idling. Test-to-test variations were observed for repeat idle tests on the same vehicle because of measurement variation, accessory loads, and ambient conditions. Vehicles fitted with EFI, on average, emitted [~20 g/hr of CO, 6 g/hr of HC, 86 g/hr of NO_x, 1 g/hr of PM, and 4636 g/hr of CO₂ during idle. MFI equipped vehicles emitted ~35 g/hr of CO, 23 g/hr of HC, 48 g/hr of NO_x, 4 g/hr of PM, and 4484 g/hr of CO₂, on average, during idle. Vehicles with EFI emitted less idleCO, HC, and PM, which could be attributed to the efficient combustion and superior fuel atomization in EFI systems. Idle NO_x, however, increased with EFI, which corresponds with the advancing of timing to improve idle combustion. Fuel injection management did not have any effect on CO₂ and, hence, fuel consumption. Use of air conditioning without increasing engine speed increased idle CO₂, NO_x, PM, HC, and fuel consumption by 25% on average. When the engine speed was elevated from 600 to 1100 revolutions per minute, CO₂ and NO_x emissions and fuel consumption increased by >150%, whereas PM and HC emissions increased by ~100% and 70%, respectively. Six Detroit Diesel Corp. (DDC) Series 60 engines in engine test cell were found to emit less CO, NO_x, and PM emissions and consumed fuel at only 75%of the level found in the chassis dynamometer data. This is because fan and compressor loads were absent in the engine test cell.     

A two-step approach for relating tapered element oscillating microbalance and dichotomous air sampler PM2.5 measurements

A method for transforming continuous monitoring (CM) fine particulate matter (aerodynamic diameter <2.5 μm; PM_2.5) data (i.e., by tapered element oscillating microbalance [TEOM]) obtained from the Canadian National Air Pollution Surveillance (NAPS) program to meet the data quality objective (DQO) of R² > 0.8 against the co-located federal reference method (i.e., dichotomous air sampler) is described. By using a two-step linear regression to account for the effect of the ambient temperature, 16 out of the 23 examined sites met the common model adequacy threshold of R² > 0.8. After the transformation, 20 out of the 23 examined sites met the DQO of R² > 0.7, as recommended by the U.S. Environmental Protection Agency (EPA). A combined two-step statistical approach was also examined and revealed similar results. The methods described herein show that the CM data can be successfully transformed to meet DQOs for representative sites across Canada using year-round (both summer and winter) data.

Implications:This study provides a transformation approach to correct ambient TEOM data against the federal reference method without dividing the ambient data according to warm and cold seasons. This transformation approach will significantly improve the correlation coefficient between TEOM and dichotomous air sampler data. It is possible that TEOM data at many Canadian locations can be transformed to meet the EPA data quality objective, thus making this transformation approach useful for comparisons of ambient PM data across jurisdictions.     

Evaluation of PCR-based quantification techniques to estimate the abundance of atrazine chlorohydrolase gene atzA in rhizosphere soils

There are many challenges in the accurate quantification of bacterial genes, such as the atrazine-degrading enzyme antA from Pseudomonas sp. strain ADP, from soil samples. We compared four quantitative methods for enumeration of atrazine-degrading bacteria in rhizosphere environments and utilized the optimal probe-based real-time polymerase chain reaction (PCR)-based method in an ongoing bioremediation experiment to monitor atzA copy number over time. We compared three quantitative PCR (qPCR) based methods--quantitative competitive PCR and two real-time qPCR methods--to traditional dilution-plate counting techniques. The optimal real-time qPCR assay was then used to monitor atzA copy number over time in the robust atrazine-degrading Pseudomonas sp. strain ADP-spiked rhizosphere environment. The use of sensitive and reliable probe-based real-time qPCRs for the enumeration of bacterial catabolic genes allows for their detection from soil samples and monitoring of potential degradative populations over time. The addition of arrazine-biodegrading bacteria into arrazine-contaminated sites to remove entrapped atrazine is a promising approach for mitigating atrazine pollution and its metabolites. The methodology contained herein will allow for optimal monitoring of atzA in rhizosphere soil with or without the addition of biodegradative Pseudomonas sp. strain ADP of bacteria.     

A review of the PGM industry,deposit models and exploration practices: Implications for Australia's PGM potential

Australia is prospective for platinum group metal (PGM) mineralisation (in particular primary magmatic reef, primary magmatic by-product, late magmatic and hydrothermal, and alluvial placer type) but its known PGM endowment is negligible compared to that of South Africa, Russia, the USA and Canada. Most Australian PGM projects are operated by mid-cap or junior companies and form part of larger, more diverse project portfolios held by these explorers. Most projects were ‘hot’ while market conditions were favourable. However, as other metals became ‘fashionable’ and market conditions for PGM changed, so did the focus of these companies. Pure PGM companies are rare in Australia. The search for and development of PGM-only deposits in Australia are high risk business activities. No new primary PGM deposits have been discovered since the mid to late 1980s and none of the significant deposits that were discovered or evaluated in the 1980s have been mined. This review suggests that at least several A$10 million but more likely several A$100 million were sunk into PGM exploration and development projects but none advanced to the mining stage. The viability of Australian PGM projects is very sensitive to (1) metal prices, (2) the US$/A$ exchange rate, and (3) large capital expenditure requirements relative to the small size of Australian PGM-only deposits. Most PGM-only projects were initiated at times of high PGM prices. However, advanced exploration, feasibility studies and project development always lagged behind the price booms. South Africa, Russia and Canada contain approximately 98% of the known global PGM reserves. This situation has a very negative effect on the Australian PGM industry as the well-endowed nations continue to receive the lion's share of exploration spend and new projects.     

Characterizing the Relative Contributions of Large Vessels to Total Ocean Noise Fields: A Case Study Using the Gerry E. Studds Stellwagen Bank National Marine Sanctuary

In 2006, we used the U.S. Coast Guard’s Automatic Identification System (AIS) to describe patterns of large commercial ship traffic within a U.S. National Marine Sanctuary located off the coast of Massachusetts. We found that 541 large commercial vessels transited the greater sanctuary 3413 times during the year. Cargo ships, tankers, and tug/tows constituted 78% of the vessels and 82% of the total transits. Cargo ships, tankers, and cruise ships predominantly used the designated Boston Traffic Separation Scheme, while tug/tow traffic was concentrated in the western and northern portions of the sanctuary. We combined AIS data with low-frequency acoustic data from an array of nine autonomous recording units analyzed for 2 months in 2006. Analysis of received sound levels (10–1000 Hz, root-mean-square pressure re 1 μPa ± SE) averaged 119.5 ± 0.3 dB at high-traffic locations. High-traffic locations experienced double the acoustic power of less trafficked locations for the majority of the time period analyzed. Average source level estimates (71–141 Hz, root-mean-square pressure re 1 μPa ± SE) for individual vessels ranged from 158 ± 2 dB (research vessel) to 186 ± 2 dB (oil tanker). Tankers were estimated to contribute 2 times more acoustic power to the region than cargo ships, and more than 100 times more than research vessels. Our results indicate that noise produced by large commercial vessels was at levels and within frequencies that warrant concern among managers regarding the ability of endangered whales to maintain acoustic contact within greater sanctuary waters. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Optimal Policies for Aggregate Recycling from Decommissioned Forest Roads

To mitigate the adverse environmental impact of forest roads, especially degradation of endangered salmonid habitat, many public and private land managers in the western United States are actively decommissioning roads where practical and affordable. Road decommissioning is associated with reduced long-term environmental impact. When decommissioning a road, it may be possible to recover some aggregate (crushed rock) from the road surface. Aggregate is used on many low volume forest roads to reduce wheel stresses transferred to the subgrade, reduce erosion, reduce maintenance costs, and improve driver comfort. Previous studies have demonstrated the potential for aggregate to be recovered and used elsewhere on the road network, at a reduced cost compared to purchasing aggregate from a quarry. This article investigates the potential for aggregate recycling to provide an economic incentive to decommission additional roads by reducing transport distance and aggregate procurement costs for other actively used roads. Decommissioning additional roads may, in turn, result in improved aquatic habitat. We present real-world examples of aggregate recycling and discuss the advantages of doing so. Further, we present mixed integer formulations to determine optimal levels of aggregate recycling under economic and environmental objectives. Tested on an example road network, incorporation of aggregate recycling demonstrates substantial cost-savings relative to a baseline scenario without recycling, increasing the likelihood of road decommissioning and reduced habitat degradation. We find that aggregate recycling can result in up to 24% in cost savings (economic objective) and up to 890% in additional length of roads decommissioned (environmental objective).     

Modeling the Effect of Summertime Heating on Urban Runoff Temperature1

Abstract: The summertime heating of runoff in urban areas is recognized as a common and consistent urban climatological phenomenon. In this study, a simple thermal urban runoff model (TURM) is presented for the net energy flux at the impervious surfaces of urban areas to account for the heat transferred to runoff. The first step in developing TURM consists of calculating the various factors that control how urban impervious areas absorb heat and transfer it to moving water on the surface. The runoff temperature is determined based on the interactions of the physical characteristics of the impervious areas, the weather, and the heat transfer between the moving film of runoff and the impervious surface common in urban areas. Key surface and weather factors that affect runoff temperature predictions are type of impervious surface, air temperature, humidity, solar radiation before and during rain, rainfall intensity, and rainfall temperature. Runoff from pervious areas is considered separately and estimated using the Green‐Ampt Mein‐Larson rainfall excess method. Pervious runoff temperature is estimated as the rainfall temperature. Field measurements indicate that wet bulb temperature can be used as a surrogate for rainfall temperature and that runoff temperatures from sod average just 2°C higher than rainfall temperatures. Differences between measured and predicted impervious runoff temperature average approximately 2°C, indicating that TURM is a useful tool for determining runoff temperatures for typical urban areas.