U.S. Environmental Protection Agency’s Super-fund Innovative Technology Evaluation of Pneumatic Fracturing ExtractionSM

The U.S. Environmental Protection Agency (EPA), in cooperation with Accutech Remedial Systems (ARS) and the New Jersey Institute of Technology (NJIT), performed a field demonstration of Pneumatic Fracturing Extraction (PFE)^SM for the removal of chlorinated-volatile organic compounds (VOCs) from vadose zones of low permeability. The demonstration was conducted in the fall of 1992 at an industrial park in Somerville, New Jersey, where removal of VOC contamination in shale bedrock was required to comply with New Jersey’s Environmental Cleanup Responsibility Act (ECRA). During the demonstration, airflow and contaminant concentrations were monitored to establish a database against which the developer’s claims about the technology were evaluated. The developer contended that PFE would increase extracted airfkiw rates from the subsurface formation by at least 100 percent and would increase the mass removal rate for the key contaminant, trichloroethene (TCE), by at least 50 percent. Also, during the demonstration hot-gas injection was evaluated. Based on comparisons of four-hour test results before and after fracturing, airflow rates increased more than 600 percent, and TCE mass-removal rates increased about 675 percent. The increase in TCE mass-removal rates appeared to be a result, primarily, of the increased airflow. In addition, the extracted air contained significantly higher concentrations of other VOCs after fracturing. Using data developed in the four-hour postfracture test, the estimated cost for a hypothetical one-year clean-up is $140 per pound of TCE removed, or $140 per ton of soil contaminated with one pound of TCE. Experiments to evaluate the effects of injecting heated air, at 200 to 250°F, into the vadose zone gave inconclusive results.     

Exploratory Analysis and a Stochastic Model for Humusdisintegration

Ulrich (1981) supposes in the hypothesis of humusdisintegrationthat the balance between polymerisation and breakdown of organicmaterial may be disturbed in chemically well buffered Europeanforest soils. This new aspect of aluminium toxicity may causenitrogen exceedance in forest ecosystems and subsequent seasonalnitrate output (Eichhorn and Hütterman, 1999).In a research program the substances in the seepage water aremonitored in a small woodland in central Germany. We explorethese multivariate data for examining possible influences on theprocess of humusdisintegration and its temporal evolution. As aresult, a regression model for carbon is developed, whichincludes covariables, i.e., other substances, as well as spatialand temporal terms describing systematic variability. Especiallyiron and aluminium turn out to be very influential in the model.So far our work is a basic step for monitoring the seepage waterdata by means of stochastic modelling.     

Design and field application of an automated cartridge sampler for VOC concentration and flux measurements

One of the major limitations in advancing the understanding of tropospheric ozone and aerosol generation and developing strategies for their control is the technical ability to accurately measure volatile organic compounds (VOCs). This paper describes the design of a constant flow VOC sampler. The versatile sampler can be used for fully automated concentration and flux measurements of VOCs. The sampler incorporates a microprocessor control unit and provides highly accurate mass flow control and significant ease of operation. Sampling sequences can be programmed directly or by remote control through a PC. All important operational parameters necessary for a complete sampling audit trail are logged. Compact weatherproof housings and low power consumption allow operation at remote sites and locations which are sensitive to disturbances or have restricted access. Inner wetted surfaces of the sampler are constructed from non-contaminating materials that do not sorb or emit VOC, and thus permit the collection of representative samples even in environments with very low VOC concentrations. The cartridge magazine provides a maximum of 20 sequential cartridge samples, which allows for long-term air quality assessments. In the dual channel mode, two samples can be collected simultaneously through two independent sample loops, providing ten sequential sample pairs. This design allows the parallel collection of (a) quality assurance backup samples, (b) samples on two different types of cartridges/sorbents to allow a variety of analyses, or (c) differential samples for flux measurements using enclosure, aerodynamic profile, or relaxed eddy accumulation (REA) methods. Field applications including airplane profile measurements above a tropical rainforest area, as well as gradient and REA measurements over a mid-latitude mixed forest stand are described, and demonstrate the validity and flexibility of the system. In particular, the application of the VOC sampler as an integrated part of a REA system is emphasized.     

Investigation of the behavior and metabolism of pharmaceutical residues during purification of contaminated ground water used for drinking water supply

Residues of phenazone-type pharmaceuticals originating from spills of a former pharmaceutical production plant have recently been detected in ground water in Berlin, Germany. The degradation pathways of phenazone, propyphenazone, and dimethylaminophenazone (DMAA) during water purification were enlightened in batch experiments with groundwater and filter material obtained from operating waterworks. For phenazone and propyphenazone a complete biological transformation into their respective metabolites 1,5-dimethyl-1,2-dehydro-3-pyrazolone (DP) and 4-(2-methylethyl)-1,5-dimethyl-1,2-dehydro-3-pyrazolone (PDP) was observed. Generally, removal of phenazone-type pharmaceutical residues during rapid sand filtration was almost exclusively caused by microorganisms only present in polluted raw water. DMAA applied to fresh filter materials was rapidly degraded into its metabolites 1-acetyl-1-methyl-2-phenylhydrazide (AMPH), acetoaminoantipyrine (AAA), formylaminoantipyrine (FAA), and 1-acetyl-1-methyl-2-dimethyloxamoyl-2-phenylhydrazide (AMDOPH). DMAA, AAA, and FAA were, however, only detected at low levels in a few samples of purified water from an operating water works. Whereas, the metabolites AMDOPH and DP were detected up to 1 microg l(-1). Propyphenazone was rapidly removed and AMPH, phenazone, and PDP were only measured with concentrations in the low ng l(-1) range. The concentrations of the metabolites DP and PDP are even higher in the purified water than in the raw water caused by their formation during degradation of phenazone and propyphenazone. Reduction of filtration velocity on an experimental filter from 5 m h(-1) down to 2 m h(-1) resulted in improved removal of phenazone, propyphenazone and their metabolites DP and PDP, respectively. AMDOPH, however, was highly persistent in all experiments independent from filtration velocities and contact times.     

Six years' experience with rapid karyotyping in prenatal diagnosis: Correlations between phenotype detected by ultrasound and fetal karyotype

From September 1985 to March 1992, 804 amniotic fluid samples from 64 different diagnostic centres of the Federal Republic of Germany were sent to our laboratory exclusively for rapid karyotyping. The average time needed for notification of the analysed karyotype was 4·65 days when the ‘pipette method’ was used for chromosome harvesting and 5·97 days when the ‘in situ’ technique was used. The overall incidence of chromosome aberrations was 15·3 per cent. Data are presented about the likelihood of abnormal ultrasound findings being caused by chromosome aberrations. These findings include polyhydramnios, oligohydramnios, growth retardation, fetal effusions, neural tube defects, craniofacial defects, heart defects, gastroschisis and omphalocele, gastrointestinal tract defects, urinogenital defects, and limb defects. In future, such data need to contain larger numbers of cases for each week of gestation. This will improve the risk evaluation for each case with abnormal ultrasound findings, which should lead to better management during pregnancy, delivery, and postnatal care for those who require rapid karyotyping.     

A pipette method for rapid karyotyping in prenatal diagnosis

The 'pipette method' is introduced as a method of prenatal diagnosis which is in competition with the 'in situ' and the 'trypsinization' technique. It is sufficiently standardized for routine diagnosis and the banding techniques currently used in prenatal diagnosis (G, Q, C-banding and NOR) have been adapted for it. In 180 cases from 27 different centres, the 'pipette method' was employed for chromosomal harvesting in order to save time. An average of 6·6 days was taken to achieve a result. There was a pathological karyotype in 28 cases (16·1 per cent) and this high proportion can be related to cases where ultrasound scan has led to a diagnosis of 'suspected chromosomal abnormality'. This technique is also of use in advanced stages of pregnancy. The early recognition of the fetal karyotype can contribute to the future management of the pregnancy. The 'pipette method' can also be used in chromosomal harvesting of tumour cells and fibroblast cultures.     

Oxy-fuel coal combustion—A review of the current state-of-the-art

Carbon dioxide emissions will continue being a major environmental concern due to the fact that coal will remain a major fossil-fuel energy resource for the next few decades. To meet future targets for the reduction of greenhouse gas (GHG) emissions, capture and storage of CO₂ is required. Carbon capture and storage technologies that are currently the focus of research centres and industry include: pre-combustion capture, post-combustion capture, and oxy-fuel combustion. This review deals with the oxy-fuel coal combustion process, primarily focusing on pulverised coal (PC) combustion, and its related research and development topics. In addition, research results related to oxy-fuel combustion in a circulating fluidised bed (CFB) will be briefly dealt with.During oxy-fuel combustion, a combination of oxygen, with a purity of more than 95 vol.%, and recycled flue gas (RFG) referred to as oxidant is used for combusting the fuel producing a gas consisting of mainly CO₂ and water vapour, which after purification and compression, is ready for storage. The high oxygen demand is supplied by a cryogenic air separation process, which is the only commercially available mature technology. The separation of oxygen from air as well as the purification and liquefaction of the CO₂-enriched flue gas consumes significant auxiliary power. Therefore, the overall net efficiency is expected to be decreased by 8–12% points, corresponding to a 21–35% increase in fuel consumption. Alternatively, ion transport membranes (ITMs) are proposed for oxygen separation, which might be more energy efficient. However, since ITMs are far away from becoming a mature technology, it is widely expected that cryogenic air separation will be the selected technology in the near future. Oxygen combustion is associated with higher temperatures compared with conventional air combustion. Both fuel properties as well as limitations of steam and metal temperatures of the various heat exchanger sections of the boiler require a moderation of the temperatures in the combustion zone and in the heat-transfer sections. This moderation in temperature is accomplished by means of recycled flue gas. The interdependencies between the fuel properties, the amount and temperature of the recycled flue gas, and the resulting oxygen concentration in the combustion atmosphere are reviewed.The different gas atmosphere resulting from oxy-fuel combustion gives rise to various questions related to firing, in particular, with respect to the combustion mechanism, pollutant reduction, the risk of corrosion, and the properties of the fly ash or its resulting deposits. In this review, detailed nitrogen and sulphur chemistry was investigated in a laboratory-scale facility under oxy-fuel combustion conditions. Oxidant staging succeeded in reducing NO formation with effectiveness comparable to that typically observed in conventional air combustion. With regard to sulphur, a considerable increase in the SO₂ concentration was measured, as expected. However, the H₂S concentration in the combustion atmosphere in the near-flame zone increased as well. Further results were obtained in a pilot-scale test facility, whereby acid dew points were measured and deposition probes were exposed to the combustion environment. Slagging, fouling and corrosion issues have so far been addressed via short-term exposure and require further investigation.Modelling of PC combustion processes by computational fluid dynamics (CFD) has become state-of-the-art for conventional air combustion. Nevertheless, the application of these models for oxy-fuel combustion conditions needs adaptation since the combustion chemistry and radiative heat transfer is altered due to the different combustion gas atmosphere.CFB technology can be considered mature for conventional air combustion. In addition to its inherent advantages like good environmental performance and fuel flexibility, it offers the possibility of additional heat exchanger arrangements in the solid recirculation system, i.e. the ability to control combustion temperatures despite relatively low flue gas recycle ratios even when combusting in the presence of high oxygen concentrations.     

Assessment of the predictive quality of simple indicator approaches for nitrate leaching from agricultural fields

Diffuse N losses from agriculture are a major cause of excessive nitrate concentrations in surface and groundwaters. Leaching through the soil is the main pathway of nitrate loss. For environmental management, an anticipatory assessment and monitoring of nitrate leaching risk by indicator (index) approaches is increasingly being used. Although complex Nitrogen Loss Indicator (NLI) approaches may provide more information, relatively simple NLIs may have advantages in many practical situations, for instance, when data availability is restricted.In this study, we tested four simple NLIs to assess their predictive properties: 1. N balance (Nbal); 2. Exchange frequency of soil solution (EF); 3. Potential nitrate concentration in leachate (PNCL); 4. A composite NLI (balance exchange frequency product, BEP). Field data of nitrate leaching from two sites in northeast Germany along with published data from several sites in Germany, Scotland and the USA were utilized.Nbal proved to be a relatively poor indicator of Nloss for the time frame of one year, whereas its prediction accuracy improved for longterm-averaged data. Correlation between calculated EF and experimental data was high for single-year data, whereas it was lower for longterm-averaged data. PNCL gave no significant correlations with measured data and high deviations. The results for BEP were intermediate between those for Nbal and EF.The results suggest that the use of EF is appropriate for assessing N leaching loss for single-year data and specific sites with comparable N input and management practices, whereas for longterm-averaged data, Nbal is better suited. BEP is an appropriate NLI both for single year and longterm data which accounts for source and transport factors and thus is more flexible than source-based Nbal and transport-based EF. However, such simplified NLIs have limitations: 1. The N cycle is not covered completely; 2. Processes in the vadose zone and the aquifer are neglected, 3. Assessment of management factors is restricted.     

Environmental Indicators to Assess the Risk of Diffuse Nitrogen Losses from Agriculture

Diffuse Nitrogen (N) loss from agriculture is a major factor contributing to increased concentrations of nitrate in surface and groundwater, and of N₂O and NH₃ in the atmosphere. Different approaches to assess diffuse N losses from agriculture have been proposed, among other direct measurements of N loads in leachate and groundwater, and physically-based modelling. However, both these approaches have serious drawbacks and are awkward to use at a routine base. N loss indicators (NLIs) are environmental management tools for assessing the risk of diffuse N losses from agricultural fields. They range in complexity from simple proxy variables to elaborate systems of algebraic equations. Here we present an overview of NLIs developed in different parts of the world. NLIs can be categorized into source-based, transport-based, and composite approaches. Several issues demand more attention in future studies. (1) Is incorporation of leaching losses and gaseous losses into one single NLI warranted? (2) Is it sufficient to restrict the focus on the rooted soil zone without considering the vadose zone and aquifer? (3) Calibration and validation of NLIs using field data of N loss seems not sufficient. Comparisons of several different NLIs with each other needs more attention; however, the different scaling of NLIs impedes comparability. (4) Sensitivity of input parameters with regard to the final NLI output needs more attention in future studies. (5) For environmental management purposes, factors addressing management decision by farmers deserve more attention.