Fate of para-toluenesulfonamide (p-TSA) in groundwater under anoxic conditions: modelling results from a field site in Berlin (Germany)

This article reports on a field modelling study to investigate the processes controlling the plume evolution of para-toluenesulfonamide (p-TSA) in anoxic groundwater in Berlin, Germany. The organic contaminant p-TSA originates from the industrial production process of plasticisers, pesticides, antiseptics and drugs and is of general environmental concern for urban water management. Previous laboratory studies revealed that p-TSA is degradable under oxic conditions, whereas it appears to behave conservatively in the absence of oxygen (O₂). p-TSA is ubiquitous in the aquatic environment of Berlin and present in high concentrations (up to 38 μg L^?1) in an anoxic aquifer downgradient of a former sewage farm, where groundwater is partly used for drinking water production. To obtain refined knowledge of p-TSA transport and degradation in an aquifer at field scale, measurements of p-TSA were carried out at 11 locations (at different depths) between 2005 and 2010. Comparison of chloride (Cl^?) and p-TSA field data showed that p-TSA has been retarded in the same manner as Cl^?. To verify the transport behaviour under field conditions, a two-dimensional transport model was setup, applying the dual-domain mass transfer approach in the model sector corresponding to an area of high aquifer heterogeneity. The distribution of Cl^? and p-TSA concentrations from the site was reproduced well, confirming that both compounds behave conservatively and are subjected to retardation due to back diffusion from water stagnant zones. Predictive simulations showed that without any remediation measures, the groundwater quality near the drinking water well galleries will be affected by high p-TSA loads for about a hundred years.     

Re-evaluation of the yield response to phosphorus fertilization based on meta-analyses of long-term field experiments

Phosphorus (P) fertilizer recommendations in most European countries are based on plant-available soil P contents and long-term field experiments. Site-specific conditions are often neglected, resulting in excessive P fertilizer applications. P fertilization experiments including relevant site and soil parameters were evaluated in order to analyze the yield response. The database comprises about 2000 datasets from 30 field experiments from Germany and Austria. Statistical evaluations using a classification and regression tree approach, and multiple linear regression analysis indicate that besides plant-available soil P content, soil texture and soil organic matter content have a large influence on the effectiveness of P fertilization. This study methodology can be a basis for modification and specification of existing P fertilization recommendations and thus contribute to mitigate environmental impacts of P fertilization.     

Dynamics and origin of PM2.5 during a three-year sampling period in Beijing, China

Systematic sampling and analysis were performed to investigate the dynamics and the origin of suspended particulate matter smaller than 2.5 μm in diameter (PM(2.5)), in Beijing, China from 2005 to 2008. Identifying the source of PM(2.5) was the main goal of this project, which was funded by the German Research Foundation (DFG). The concentrations of 19 elements, black carbon (BC) and the total mass in 158 weekly PM(2.5) samples were measured. The statistical evaluation of the data from factor analysis (FA) identifies four main sources responsible for PM(2.5) in Beijing: (1) a combination of long-range transport geogenic soil particles, geogenic-like particles from construction sites and the anthropogenic emissions from steel factories; (2) road traffic, industry emissions and domestic heating; (3) local re-suspended soil particles; (4) re-suspended particles from refuse disposal/landfills and uncontrolled dumped waste. Special attention has been paid to seven high concentration "episodes", which were further analyzed by FA, enrichment factor analysis (EF), elemental signatures and backward-trajectory analysis. These results suggest that long-range transport soil particles contribute much to the high concentration of PM(2.5) during dust days. This is supported by mineral analysis which showed a clear imprint of component in PM(2.5). Furthermore, the ratios of Mg/Al have been proved to be a good signature to trace back different source areas. The Pb/Ti ratio allows the distinction between periods of predominant anthropogenic and geogenic sources during high concentration episodes. Backward-trajectory analysis clearly shows the origins of these episodes, which partly corroborate the FA and EF results. This study is only a small contribution to the understanding of the meteorological and source driven dynamics of PM(2.5) concentrations.     

Urban Geochemistry: Investigations in the Berlin Metropolitan Area

The distribution of 41 trace and 11 major elements in 4000 samples of topsoils (0–20cm) from the Berlin Megacity is interpreted. The detailed comparative analysis of the element distributions and the results of factor analysis showed that the distributions of the elements Al, K, Na, Rb, Zr, Nb and Ti are mainly natural origin, i.e. related to the composition of the parent material. Industrial and commercial areas often display considerably elevated values for Mo, Ni, As, Ag, Cr, Sb, Fe, Mn, Mg, P, TOC and especially Pb, Hg and electrical conductivity relative to the geogenic background of the area surrounding Berlin. Industrial areas tend to be characterised by contamination of the subsoil with Cu, Cd, Zn, Hg, Pb and Sn. In the area around Berlin, extensive, strong anamalies of Cd, Zn, Pb, Cu and Hg occur near iron and steel industries and construction materials industries, as well as in the vicinity of sewage farms.     

Assessment of nitrogen leaching from arable land in large river basins: Part I. Simulation experiments using a process-based model

A two-step procedure for analysing nitrogen leaching from arable land in large river basins is suggested: (1) application of a process-based dynamic model for a set of representative conditions in a large river basin to simulate water and nitrogen fluxes and (2) development of a fuzzy-rule based metamodel using the simulated nitrogen fluxes in Step 1 as a training set. After that the metamodel can be used for rapid assessment of water quality inside the considered ranges of parameters, describing natural conditions and management practices. This paper describes Step 1 of the procedure. Step 2 is described in an accompanying paper (Haberlandt et al., Ecological Modelling 150 (3) (2002) 277–294). The advantage of this approach is that it combines the ‘process-based foundation’ with the resulting simplicity of the metamodel. Simulation experiments for analysing nitrogen (N) leaching from arable land were performed using the Soil and Water Integrated Model (SWIM) for a set of representative conditions in the Saale basin (23 687 km²) in Central Europe. The Saale River is one of the main tributaries of the Elbe. In advance, hydrological validation of the model was done for the whole Saale basin and validation of nitrogen dynamics was fulfilled in two mesoscale sub-basins of the Elbe. For the simulation experiments the drainage basin area was sub-divided into five climate zones and nine representative soil classes were chosen. The basic rotation and fertilisation schemes were established using regional information obtained from literature. In addition, the effects of changing the basic rotation to more/less intensive ones and changing fertilisation rates by 50% increase/decrease were studied. The ranges of simulated nitrogen fluxes for the basic rotation and fertilisation schemes are comparable to available regional estimates and differences between sub-regions and soils are plausible. The relative importance of natural and anthropogenic factors affecting nitrogen leaching for the Saale River basin was as follows: (1) soil, (2) climate, (3) fertilisation rate and (4) crop rotation. The simulation experiments provide a basis for a fuzzy-rule based metamodel approach, which aims at rapid water quality assessment of large regions.     

Scouts behave as streakers in honeybee swarms

Harmonic radar tracking was used to record the flights of scout bees during takeoff and initial flight path of two honeybee swarms. One swarm remained intact and performed a full flight to a destination beyond the range of the harmonic radar, while a second swarm disintegrated within the range of the radar and most of the bees returned to the queen. The initial stretch of the full flight is characterized by accelerating speed, whereas the disintegrating swarm flew steadily at low speed. The two scouts in the swarm displaying full flight performed characteristic flight maneuvers. They flew at high speed when traveling in the direction of their destination and slowed down or returned over short stretches at low speed. Scouts in the disintegrating swarm did not exhibit the same kind of characteristic flight performance. Our data support the streaker bee hypothesis proposing that scout bees guide the swarm by traveling at high speed in the direction of the new nest site for short stretches of flight and slowing down when reversing flight direction.     

Impact of Sodium Chloride, Sucrose and Milk on Heat Stability of the Murine Norovirus and the MS2 Phage

Until now, little is known about the influence of food additives on heat inactivation of noroviruses. Only a few studies have shown a protective or inhibiting effect on virus infectivity caused by the food matrix. Therefore, the aim of this study was to examine the influence of sodium chloride, sucrose and milk on heat stability of the surrogates murine norovirus (MNV) and MS2 phage at 60 °C for 1–5 min in PBS for MNV and for 5–120 min in suspension medium buffer for MS2 phage. Different concentrations of sodium chloride (5, 10 %) and sucrose (5, 50 %) were added to the respective buffers. In addition, commercially available milk with different fat concentrations (0.3, 1.5, 3.5 %) was investigated in this study. In general, a linear titre reduction for MNV and MS2 phage could be observed, except for the heat treatment of MNV in PBS with 50 % sucrose. A protective effect of PBS with 50 % sucrose and of the matrix milk on MNV could be concluded. All other tested conditions did not show any influence on virus inactivation. However, MS2 phage did show a higher heat resistance throughout the experiments compared to MNV. In future investigations, it should be tested, whether the achieved data may be considered in risk assessments of heat-treated food products with high concentrations of sugar. Furthermore, it should be clarified, whether these results can also be referred to complex food matrices.