Atmospheric Deposition and Ionic Input in Adirondack Forests

Major mechanisms for input of ions to forest ecosystems in the central Adirondack Mountains of New York State were studied. Precipitation and throughfall in adjacent northern hardwood and lake margin coniferous forests were continuously sampled from May 2, 1979 to May 7, 1980. Important mechanisms for transport of ions from atmosphere to forest floor were identified using regression analyses and the assumption that deciduous and coniferous forests capture particulates and aerosols with differing efficiencies. Sodium was delivered in precipitation and dry-fall and interacted little with the forest canopies. Hydrogen, potassium, and magnesium were also deposited primarily by bulk precipitation but hydrogen was retained by foliage while additional quantities of potassium and magnesium were leached from tree canopies. Impaction of suspended particulates and/or aerosols on forest vegetation was an important source of additional sulfate and nitrate, and these ions contributed to the leaching of calcium from foliage.     

Temporal and geographical genetic variation in the amphipod Melita plumulosa (Crustacea: Melitidae): Link of a localized change in haplotype frequencies to a chemical spill

Anthropogenic effects such as contamination affect the genetic structure of populations. This study examined the temporal and geographical patterns of genetic diversity among populations of the benthic crustacean amphipod Melita plumulosa in the Parramatta River (Sydney, Australia), following an industrial chemical spill. The spill of an acrylate/methacrylate co-polymer in naphtha solvent occurred in July 2006. M. plumulosa were sampled temporally between December 2006 and November 2009 and spatially in November 2009. Genetic variation was examined at the mitochondrial cytochrome c oxidase subunit I locus. Notably, nucleotide diversity was low and Tajima’s D was significantly negative amongst amphipods collected immediately downstream from the spill for 10 months. We hypothesize that the spill had a significant localized effect on the genetic diversity of M. plumulosa. Alternate explanations include an alternate and unknown toxicant or a localized sampling bias. Future proposed studies will dissect these alternatives.     

A study on legislative and policy tools for promoting the circular economic model for waste management in China

The circular economy has been developing rapidly in recent years in China. A legislative system has been created to provide legal protection for the development of a circular economy, including a series of price and tax measures in the waste management area. These measures form the basic foundation for promoting better waste management under the circular economic model. Many challenges, however, remain. For instance, the legal system needs to incorporate more sophisticated science, and China lacks key waste treatment technology that could support the further development of a circular economy. There is also a need to educate the public about the concept of the circular economy and its benefits. Specific suggestions are made for the development and implementation of the circular economic model.     

The effect of the addition of fly ash to municipal digested sludge on its electroosmotic dewatering

Effective handling of municipal digested sludge requires that the product cake have low water content. To this end, we investigated the change in sludge dewaterability after the addition of fly ash to municipal digested sludge, dewatering of which is difficult because of its high organic content. The performance of the dewatering is compared with that of electroosmotic dewatering (EDW) and conventional mechanical dewatering (CMD). Fly ash classified by sieving to the size of 25–75 μm and >75 μm is added to the municipal digested sludge by 10, 20, and 50 wt% by wet base. When adding fly ash particles to municipal digested sludge, dewatering efficiency improved with smaller fly ash particle size and with increase in the amount. When sludge was dewatered using an electroosmotic dewatering method, the dewatering efficiency is improved about 40% by adding fly ash of 25–75 μm particle size with 20 wt% when compared with conventional mechanical dewatering method without adding the fly ash. It is concluded that fly ash particles rich in inorganic material are helpful in the dewatering process when added to municipal digested sludge and EDW is more effective than CDW.     

Archaeal Poly (3-hydroxybutyrate) Polymer Production from Glycerol: Optimization by Taguchi Methodology

In this study the possibility of poly (3-hydroxybutyrate) production from glycerol was investigated and optimized by Halorcula sp. IRU1, a novel archaea isolated from Urmia lake, Iran in batch experiments. Using Taguchi methodology, three important independent parameters (glycerol, yeast extract and KH₂PO₄) were evaluated for their individual and interactive effects on poly (3-hydroxybutyrate) production. It was shown that the glycerol concentration was the most significant factor affecting the yield of poly (3-hydroxybutyrate). The optimum factor levels were a glycerol concentration of 8% (v/v), yeast extract 0.8% (w/v) and KH₂PO₄ 0.002% (w/v). The predicted value obtained for poly (3-hydroxybutyrate) production under these conditions was about 81.87%. We can conclude that Haloarcula sp. IRU1 has a high potential for synthesis of poly (3-hydroxybutyrate) from glycerol.     

Preformed Amide-containing biopolymer for Improving the Environmental Performance of Synthesized Urea–formaldehyde in Agro-fiber Composites

Investigations have continued for production high performance agro-based composites using environmentally acceptable approaches. This study examines the role of adding amide-containing biopolymers during synthesis of urea–formaldehyde (UF) on properties of adhesive produced, especially its adhesion potential. The environmental performance of UF-resin synthesized in the presence of modified amide-containing biopolymer was evaluated by evaluating the free-HCHO of both adhesive (during processing) and of the eventual engineered composite product. Also, the benefits of this synthesis-modified adhesive in enhancing the bondability of sugar-cane fibers used in engineered composite panels was evaluated and compared to using UF-resin. The results obtained show that, static bending of the produced composites varied from 27.7 to 33.13 N/mm² of modulus of rupture (MOR) and from 2860 to 3374 N/mm² of Modulus of Elasticity (MOE); while for internal bond (IB) it’s varied from 0.64 to 0.866 N/mm². Based on the ANSI and EN Standards modified UF-based agro composites produced meet the performance requirements for high grade particleboards with respect to static bending strength. These agro-based composite also tested out as having free-HCHO values of ~13 mg/100 g board.     

Effects of Filler Content and Compatibilizing Agents on Mechanical Behavior of the Particle-Reinforced Composites

The study was carried out to investigate the effects of filler content and two different compatibilizing agents (Eastman G-3003 and G-3216) on the mechanical properties of polypropylene reinforced with corn stalk and wood flour. In the sample preparation, three levels of filler loading (30, 40 and 50 wt%) and one level of compatibilizing agent content (2.5 wt%) were used. For overall trend, with addition of both grades of the compatibilizing agents, tensile and flexural properties of the composites significantly improved, as compared with the pure PP. Tensile and flexural properties reach a maximum at 40 wt% filler content and gradually decrease with a further increase in wood particle content. The composites treated with G-3003 gave better results in comparison with G-3216. This could be caused by the high melt viscosity of G-3003. In general, corn stalk flour filled composites showed superior mechanical properties.     

Preparation and Characterization of Clay Nanocomposites of Plasticized Starch and Polypropylene Polymer Blends

Plasticized starch (PLS) is a renewable, degradable, and inexpensive polymer, but it suffers from poor mechanical properties. The mechanical properties can be improved by blending PLS with polyolefins, nonetheless, at high PLS content, the mechanical properties remain poor. Here we show that addition of clay can greatly improve the mechanical properties of PLS/polypropylene blends at high starch content. Unmodified and organically modified montmorillonite clays, MMT and Cloisite 30B respectively, were added to blends of glycerol-plasticized starch and polypropylene, compatibilized using maleated polypropylene. TEM indicates that MMT is well dispersed in the PLS phase of the blends, while Cloisite 30B is located both within the PLS phase as well as at the interface between PLS and PP. At high PLS content, the addition of clay increased the tensile strength and tensile modulus by an order of magnitude, while reducing the ultimate elongation only slightly. Such improvements are attributable to both the addition of clay as a reinforcing component, as well as to the change in the two phase morphology due to addition of clay.