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41.
42.
Yuchi Lee Shanglien Lo Jeff Kuo Chinghong Hsieh 《Frontiers of Environmental Science & Engineering》2012,6(1):17-25
Microwave-hydrothermal treatment of persistent and bioaccumulative perfluorooctanoic acid (PFOA) in water with persulfate (S2O 8 2? ) has been found effective. However, applications of this process to effectively remediate PFOA pollution require a better understanding on free-radical scavenging reactions that also take place. The objectives of this study were to investigate the effects of pH (pH = 2.5, 6.6, 8.8, and 10.5), chloride concentrations (0.01?C0.15 mol·L?1), and temperature (60°C, 90°C, and 130°C) on persulfate oxidation of PFOA under microwave irradiation. Maximum PFOA degradation occurred at pH 2.5, while little or no degradation at pH 10.5. Lowering system pH resulted in an increase in PFOA degradation rate. Both high pH and chloride concentrations would result in more scavenging of sulfate free radicals and slow down PFOA degradation. When chloride concentrations were less than 0.04 mol·L?1 at 90°C and 0.06 mol·L?1 at 60°C, presence of chloride ions had insignificant impacts on PFOA degradation. However, beyond these concentration levels, PFOA degradation rates reduced significantly with an increase in chloride concentrations, especially under the higher temperature. 相似文献
43.
Fang Guor-Cheng Chen Yu-Cheng Lo Chaur-Tsuen Cho Meng-Hsien Zhuang Yuan-Jie Tsai Kai-Hsiang Huang Chao-Yang Xiao You-Fu 《Environmental geochemistry and health》2018,40(1):461-472
Environmental Geochemistry and Health - The concentrations of particulates and metallic elements that were bound to total suspended particulates in ambient air at Long Cyuan Elementary School... 相似文献
44.
Lin Ya-Wen Cheng Ta-Wui Lin Wei-Ting Lo Huang-Mu Lo Kang-Wei Chen Chiao-Ying Lin Kae-Long 《Journal of Material Cycles and Waste Management》2021,23(3):1081-1089
Journal of Material Cycles and Waste Management - The goal of this paper was to synthesize eco-humidity-conditioned Al-MCM-41 mesoporous molecular sieves (CHCMs) from liquid–crystal-display... 相似文献
45.
Predation is often considered as one of the most important biotic factor determining the success of exotic species. The freshwater amphipod Gammarus roeseli has widely colonized Western Europe, where it is frequently found in sympatry with the native species (Gammarus pulex). Previous laboratory experiments revealed that G. roeseli may have an advantage over G. pulex through differential predation by native fish (brown trout). Morphological anti-predator defences (spines) were found responsible for lower rates of predation on the invasive G. roeseli. Here, using both field surveys and laboratory experiments, we tested if a differential of predation exists with other fish predators naturally encountered by gammarids. The main predators present in our field site were nocturnal benthic feeders (mainly bullheads, Cottus gobio). Fish diet analysis showed that, compared to its global availability in the river, G. roeseli was less consumed than G. pulex. In the field, however, G. roeseli was found mainly in the aquatic vegetation whereas G. pulex was found in all habitat types. Laboratory experiments in microcosms revealed that G. roeseli was less prone to predation by C. gobio only when vegetation was present. Depending on the type of predator, the differential of predation could therefore be mediated by antipredator behaviour, and a better usage of refuges, rather than by morphological defences. 相似文献
46.
Fang GC Lo CT Huang WJ Wu YS Huang JH 《Environmental monitoring and assessment》2011,181(1-4):273-289
The main purpose for this study is to observe the seasonal and month variations for particulates-bound mercury Hg(p) in total suspended particulates (TSP) concentration, dry deposition at five characteristic sampling sites during years of 2009-2010 in central Taiwan. The results show that the highest and lowest monthly average particulates-bound mercury Hg(p) concentrations in TSP were occurred in Dec. and Oct. at Gao-mei (wetland), Chang-hua (downtown) and He-mei (residential) sampling site. In addition, the results show that the highest and lowest monthly average particulates-bound mercury Hg(p) dry deposition was occurred in Feb. and Oct. at Quan-xing (industrial) sampling site. This study reflected that the mean highest particulates-bound mercury Hg(p) concentrations in TSP and mean highest particulates-bound mercury Hg(p) dry deposition were occurred at Gao-mei (wetland) and Quan-xing (industrial). However, the mean lowest particulates-bound mercury Hg(p) concentrations in TSP and mean lowest particulates-bound mercury Hg(p) dry deposition were also occurred at Gao-mei (wetland). Regarding seasonal variation, the order of mean-particulates-bound mercury Hg(p) concentrations in TSP in winter and spring were Gao-mei (wetland) > Quan-xing (industrial) > Bei-shi (suburban/coastal) > Chang-hua (downtown) > He-mei (residential). Finally, the order of mean-particulates-bound mercury Hg(p) dry deposition in fall, spring and summer were Quan-xing (industrial) > Bei-shi (suburban/coastal) > Chang-hua (downtown) > He-mei (residential) > Gao-mei (wetland). 相似文献
47.
Rapid analysis of neonicotinoid insecticides in guttation drops of corn seedlings obtained from coated seeds 总被引:1,自引:0,他引:1
Tapparo A Giorio C Marzaro M Marton D Soldà L Girolami V 《Journal of environmental monitoring : JEM》2011,13(6):1564-1568
Regarding the hypothesis that neonicotinoid insecticides used for seed coating of agricultural crops - mainly corn, sunflower and seed rape - are related to the extensive death of honey bees, the phenomenon of corn seedling guttation has been recently considered as a possible route of exposure of bees to these systemic insecticides. In the present study, guttation drops of corn plants obtained from commercial seeds coated with thiamethoxam, clothianidin, imidacloprid and fipronil have been analyzed by an optimized fast UHPLC-DAD procedure showing excellent detection limits and accuracy, both adequate for the purpose. The young plants grown both in pots - in greenhouse - and in open field from coated seeds, produced guttation solutions containing high levels of the neonicotinoid insecticides (up to 346 mg L(-1) for imidacloprid, 102 mg L(-1) for clothianidin and 146 mg L(-1) for thiamethoxam). These concentration levels may represent lethal doses for bees that use guttation drops as a source of water. The neonicotinoid concentrations in guttation drops progressively decrease during the first 10-15 days after the emergence of the plant from the soil. Otherwise fipronil, which is a non-systemic phenylpyrazole insecticide, was never detected into guttation drops. Current results confirm that the physiological fluids of the corn plant can effectively transfer neonicotinoid insecticides from the seed onto the surface of the leaves, where guttation drops may expose bees and other insects to elevated doses of neurotoxic insecticides. 相似文献
48.
Effect of composting on characterization and leaching of copper, manganese, and zinc from swine manure. 总被引:23,自引:0,他引:23
This research was conducted to study the influence of composting on the concentrations, water solubility, and phase association of Cu, Mn, and Zn from swine (Sus domesticus) feces. Composting of separated swine manure was performed in two piles for 122 days. The metal concentrations increased rapidly during the first 49 days and leveled off thereafter. All metal concentrations increased approximately 2.7-fold in the final compost due to decomposition of organic matter. A sequential extraction protocol was used to evaluate the humification process and partition metals into water-soluble, exchangeable, organically complexed, organically bound, solid particulate, and residual fractions. Temporal changes in the water-soluble fractions of Cu, Mn, and Zn were reflected by water-soluble organic C concentrations, which rapidly increased to a maximum at Day 18 and declined thereafter. An increase in the humic acid/fulvic acid ratio in Na4P2O7 or NaOH extracts at various stages of composting represented the humification process. During composting, the major portions of Cu, Mn, and Zn were in the organically-bound, solid particulate, and organically complexed fractions, respectively. Metal distributions in different chemical fractions were generally independent of composting age and, thus, independent of respective total metal concentrations in the composts. 相似文献
49.
We develop a stochastic model for the time-evolution of scalar concentrations and temporal gradients in concentration experienced
by observers moving within inhomogeneous plumes that are dispersing within turbulent flows. In this model, scalar concentrations
and their gradients evolve jointly as a Markovian process. Underlying the model formulation is a natural generalisation of
Thomson’s well mixed condition [Thomson DJ (1987) J Fluid Mech 180:529–556]. As a consequence model outputs are necessarily
compatible with statistical properties of scalars observed in experiment that are used here as model input. We then use the
model to examine how insects aloft within the atmospheric boundary-layer can locate odour sources by modulating their flight
patterns in response to odour cues. Mechanisms underlying odour-mediated flights have been studied extensively at laboratory-scale
but an understanding of these flights over landscape scales is still lacking. Insect flights are simulated by combining the
stochastic model with a simple model of insect olfactory response. These simulations show the strong influence of wind speed
on the distributions of the times taken by insects to locate the source. In accordance with experimental observations [Baker
TC, Vickers NJ (1997) In: Insect pheromone research: new directions, pp 248–264; Mafra-Neto A, Cardé RT (1994) Nature 369:142–144],
flight patterns are predicted to become straighter and shorter, and source location is predicted to become more likely as
the mean wind speed increases. The most probable arrival time to the source decreases with the mean wind speed. It is shown
that scale-free movement patterns arising from olfactory-driven foraging stem directly from the power-law distribution of
concentration excursion times above/below a threshold level and are robust with respect to variations in Reynolds number.
Flight lengths are well represented by a power law distribution in agreement with the observed patterns of foraging bumblebees
[Heinrich B (1979) Oecologia 40(3):235–245]. 相似文献
50.
Shih-Yi Chang Tai-Ly Tso Jiunn-Guang Lo 《Journal of the Air & Waste Management Association (1995)》2013,63(9):1332-1338
ABSTRACT The accuracy of CO concentration determination by open-path Fourier transform infrared (FTIR) spectrometry has been re-evaluated in detail. The evaluation focuses on the correction of the calibration curve—the integrated intensity of a standard spectrum—that is used as a comparison spectrum when doing quantitative analysis of CO. Results show that the calibration curve (with 0.5 cm-1 or 1 cm-1 resolution) is apparently inclined to be nonlinear under standard conditions, and that the threshold point of nonlinearity is ~0.1 atm-cm. Two commercial FTIR field monitoring systems have been used to investigate the nonlinearity trend. The experimental method consists of using open-path FTIR systems in combination with nondispersive infrared (NDIR) monitors to establish the calibration curve in a semi-closed corridor. The results have been double-checked using closed-cell dynamic equilibrium systems. When the optical density is larger than a certain value, the curves begin to bend, and when the optical density approaches zero, the band strength is around 178 ± 3 atm-1 cm-2 and 173 ± 2 atm-1 cm-2, respectively, for 0.5 and 1 cm-1 resolution at standard temperature and pressure (STP). These values are quite different from other published data that have been acquired by the pressurized method or by high-resolution 相似文献